Blends of isosorbide-based copolycarbonate, method of making, and articles formed therefrom
View Patent ↗Disclosed herein is are thermoplastic compositions comprising a blend of a homopolycarbonate comprising units derived from an aromatic dihydroxy compound and a copolymer comprising isosorbide units and siloxane units. The copolymer comprising isosorbide units and siloxane units can further comprise non-isosorbide aliphatic units derived from a C 14-44 aliphatic diacid, a C 14-44 aliphatic diol or combination of these, aromatic units, aliphatic units derived from an oligomer having a weight average molecular weight of 900 to 4000 or a combination of some or all of the foregoing additional units.
1. A thermoplastic composition comprising a homopolycarbonate comprising units derived from an aromatic dihydroxy compound and a copolycarbonate comprising isosorbide units and siloxane units, wherein the homopolycarbonate is present in an amount of 10 to 80 weight percent, based on the total weight of composition, and wherein the isosorbide units in the copolycarbonate are present in an amount of 50 to 95 weight percent, based on a total weight of diol and diacid used to make the copolycarbonate, wherein the copolycarbonate is present in an amount of 20 to 90 wt %, based on the total weight of the composition.
2. The thermoplastic composition of claim 1 wherein the copolycarbonate comprising isosorbide units and siloxane units further comprises non-isosorbide aliphatic units derived from a C 14-44 aliphatic diacid, a C 14-44 aliphatic diol or combination of these.
3. The thermoplastic composition of claim 1 wherein the copolycarbonate comprising isosorbide units and siloxane units further comprises aliphatic units derived from an oligomer having a weight average molecular weight of 900 to 4000.
4. The thermoplastic composition of claim 1 wherein the copolycarbonate comprising isosorbide units and siloxane units further comprises units derived from an aromatic dihydroxy compound.
5. The thermoplastic composition of claim 1 wherein the homopolycarbonate is a bisphenol A homopolycarbonate.
6. The thermoplastic composition of claim 1 , wherein the homopolycarbonate is present in an amount of 20 to 70 weight percent, based on the total weight of composition.
7. The thermoplastic composition of claim 1 , wherein the isosorbide units in the copolycarbonate are present in an amount of 60 to 95 weight percent, based on a total weight of diol and diacid used to make the copolycarbonate.
8. The thermoplastic composition of claim 1 , wherein the siloxane units in the copolycarbonate are present in an amount of 3 to 30 weight percent, based on a total weight of diol and diacid used to make the copolycarbonate.
9. The thermoplastic composition of claim 1 , wherein the composition has a total bio-content of greater than or equal to 15 wt % based on the total weight of the composition exclusive of and prior to addition of any filler.
10. The thermoplastic composition of claim 1 , wherein the copolycarbonate is present in an amount of 30 to 80 wt %, based on the total weight of the composition.
11. A thermoplastic composition comprising a homopolycarbonate comprising units derived from an aromatic dihydroxy compound and a copolycarbonate comprising isosorbide units, siloxane units and at least one additional unit selected from the group consisting of aliphatic units derived from an oligomer having a weight average molecular weight of 900 to 4000, units derived from an aromatic dihydroxy compound, non-isosorbide aliphatic units derived from a C 14-44 aliphatic diacid, and non-isosorbide aliphatic units derived from a C 14-44 aliphatic diol, wherein the homopolycarbonate is present in an amount of 10 to 80 weight percent, based on the total weight of composition, and wherein the isosorbide units in the copolycarbonate are present in an amount of 50 to 95 weight percent, based on a total weight of diol and diacid used to make the copolycarbonate, wherein the copolycarbonate is present in an amount of 20 to 90 wt %, based on the total weight of the composition.
12. The thermoplastic composition of claim 11 , wherein the homopolycarbonate is a bisphenol A homopolycarbonate.
13. The thermoplastic composition of claim 11 , wherein the homopolycarbonate is present in an amount of 20 to 70 weight percent, based on the total weight of composition.
14. The thermoplastic composition of claim 11 , wherein the isosorbide units in the copolycarbonate are present in an amount of 60 to 95 weight percent, based on a total weight of diol and diacid used to make the copolycarbonate.
15. The thermoplastic composition of claim 11 , wherein the siloxane units in the copolycarbonate are present in an amount of 3 to 30 weight percent, based on a total weight of diol and diacid used to make the copolycarbonate.
16. The thermoplastic composition of claim 11 , wherein the composition has a total bio-content of greater than or equal to 15 wt % based on the total weight of the composition exclusive of and prior to addition of any filler.
17. The thermoplastic composition of claim 11 , wherein the copolycarbonate is present in an amount of 30 to 80 wt %, based on the total weight of the composition.
18. The thermoplastic composition of claim 11 , wherein the composition has a notched Izod impact strength at 23° C. of greater than or equal to 100 kJ/m 2 .
19. The thermoplastic composition of claim 11 , wherein the siloxane unit comprises polydimethylsiloxane.
20. The thermoplastic composition of claim 1 , wherein the siloxane unit comprises polydimethylsiloxane.
21. A thermoplastic composition comprising a homopolycarbonate comprising units derived from an aromatic dihydroxy compound and a copolycarbonate comprising isosorbide units and siloxane units, wherein the homopolycarbonate is present in an amount of 25 to 65 weight percent, based on the total weight of composition, wherein the composition has a total bio-content of greater than or equal to 15 wt % based on the total weight of the composition exclusive of and prior to addition of any filler, wherein the heat deflection temperature greater than or equal to 112° C., wherein the impact strength of the thermoplastic composition is greater than the impact strength of the homopolycarbonate and of the copolycarbonate.