Ceramic material composition
View Patent ↗A ceramic material composition comprising from 20 to 50 mass % of a borosilicate glass powder, from 25 to 55 mass % of an alumina filler powder and from 10 to 45 mass % of a filler powder (a high refractive index filler powder) having a refractive index higher than the alumina filler powder, wherein the borosilicate glass powder comprises, as calculated as oxides, from 30 to 70 mass % of SiO 2 , from 5 to 28 mass % of B 2 O 3 , from 5 to 30 mass % of Al 2 O 3 , from 3 to 35 mass % of CaO, from 0 to 25 mass % of SrO, from 0 to 25 mass % of BaO, from 0 to 10 mass % of Na 2 O, from 0 to 10 mass % of K 2 O, from 0.5 to 10 mass % of Na 2 O+K 2 O and from 3 to 40 mass % of CaO+SrO+BaO, and satisfies the following conditions: in the borosilicate glass powder, as represented by mass %, the value of “three times the B 2 O 3 content”+“twice (the CaO content+the SrO content+the BaO content)”+“ten times (the Na 2 O content+the K 2 O content)”, is within a range of from 105 to 165.
1. A ceramic material composition comprising from 20 to 50 mass % of a borosilicate glass powder, from 25 to 55 mass % of an alumina filler powder and from 10 to 45 mass % of a filler powder (a high refractive index filler powder) having a refractive index higher than the alumina filler powder, wherein the borosilicate glass powder comprises, as calculated as oxides, from 30 to 70 mass % of SiO 2 , from 5 to 28 mass % of B 2 O 3 , from 5 to 30 mass % of Al 2 O 3 , from 3 to 35 mass % of CaO, from 0 to 25 mass % of SrO, from 0 to 25 mass % of BaO, from 0 to 10 mass % of Na 2 O, from 0 to 10 mass % of K 2 O, from 0.5 to 10 mass % of Na 2 O+K 2 O and from 3 to 40 mass % of CaO+SrO+BaO, and satisfies the following conditions:
in the borosilicate glass powder, as represented by mass %, the value of “three times the B 2 O 3 content”+“twice (the CaO content+the SrO content+the BaO content)”+“ten times (the Na 2 O content+the K 2 O content)”, is within a range of from 105 to 165.
2. The ceramic material composition according to claim 1 , wherein the borosilicate glass powder contains, as calculated as oxides, from higher than 55 to 70 mass % of SiO 2 , from 5 to 15 mass % of B 2 O 3 , from 5 to 15 mass % of Al 2 O 3 , from 3 to 20 mass % of CaO, from 0 to 10 mass % of SrO, from 0 to 10 mass % of BaO, from 0 to 10 mass % of Na 2 O, from 0 to 10 mass % of K 2 O, from 3 to 20 mass % of CaO+SrO+BaO and from 4 to 10 mass % of Na 2 O+K 2 O, and the value of “three times the B 2 O 3 content”+“twice (the CaO content+the SrO content+the BaO content)”+“ten times (the Na 2 O content+the K 2 O content)”, as represented by mass %, is within a range of from 105 to 140.
3. The ceramic material composition according to claim 1 , wherein the borosilicate glass powder contains, as calculated as oxides, from 30 to 55 mass % of SiO 2 , from 10 to 28 mass % of B 2 O 3 , from 5 to 30 mass % of Al 2 O 3 , from 3 to 35 mass % of CaO, from 0 to 25 mass % of SrO, from 0 to 25 mass % of BaO, from 0 to 10 mass % of Na 2 O, from 0 to 10 mass % of K 2 O, from 0.5 to 10 mass % of Na 2 O+K 2 O and from 10 to 40 mass % of CaO+SrO+BaO, and the value of “three times the B 2 O 3 content”+“twice (the CaO content+the SrO content+the BaO content)”+“ten times (the Na 2 O content+K 2 O content)”, as represented by mass %, is within a range of from 105 to 165.
4. The ceramic material composition according to claim 1 , wherein the borosilicate glass powder contains substantially no Fe 2 O 3 or has its content of less than 0.05 mass %.
5. The ceramic material composition according to claim 1 , wherein in a ceramic sintered body obtainable by firing, the degree of crystallinity of a glass phase is at most 60% by the volume ratio.
6. The ceramic material composition according to claim 1 , wherein the high refractive index filler powder is a ceramic having a refractive index higher than 1.95.
7. The ceramic material composition according to claim 6 , wherein the high refractive index filler powder is a powder of zirconia, stabilized zirconia or partially stabilized zirconia.
8. A package to be mounted on a light emitting diode element, comprising a ceramic substrate obtained by molding and firing the ceramic material composition as defined in claim 1 , and a wiring conductor formed in relation to the ceramic substrate.