Process for the production of metal oxide and metalloid oxide dispersions
View Patent ↗Process for the production of an aqueous dispersion of pyrogenically produced metal oxide and metalloid oxide powders with a BET surface area of between 5 and 600 m 2 /g, with a metal oxide or metalloid oxide content in the dispersion of between 5 and 25 wt. %, comprising the following steps: water, which is optionally adjusted to pH values of between 2 and 4 by adding acids, is circulated from a receiving vessel via a rotor/stator machine, and metal oxide or metalloid oxide powder is introduced, using a feed device, into the shear zone between the slots in the rotor teeth and the stator slots, continuously or discontinuously and with the rotor/stator machine running, in a quantity such that a predispersion with a solids content of between 20 and 40 wt. % results, and, after all the metal oxide powder or metalloid oxide powder has been added, the feed device closes and shearing continues in such a way that the shear rate is in the range of between 10000 and 40000 s −1 , and then, by dilution, the predispersion is adjusted to the desired solids content of the dispersion while maintaining the dispersing conditions.
1. A process for the production of an aqueous dispersion of a pyrogenically produced silica powder with a BET surface area of between about 90 to 300 m 2 /g, with a silica content in the dispersion of between 5 and 25 wt. %, comprising the steps:
water is introduced from a receiving vessel to a rotor/stator machine, wherein the water is optionally adjusted to pH values of between 2 and 4 by adding an acid, and
silica powder is introduced, using a feed device, into the shear zone between the slots in the rotor teeth and the stator slots of the rotor/stator machine, continuously or discontinuously and with the rotor/stator machine running, in a quantity such that a predispersion having a pH of between 2 and 4.5, and with a solids content of between 20 and 35 wt. % results, and, after all the silica powder has been added,
the feed device closes and shearing continues in such a way that the shear rate is in the range of between 10000 and 40000 s −1 , and
then, by dilution, the predispersion is adjusted to the desired solids content of the dispersion while maintaining dispersing conditions,
wherein the silica powder is not a doped silica powder.
2. The process according to claim 1 , wherein a base or acid is added to the dispersion and/or predispersion.
3. The process according to claim 1 , wherein a cationic polymer and/or an aluminium salt is added to the dispersion and/or predispersion.
4. The process according to claim 1 , wherein a surface active substance is added to the dispersion and/or predispersion.
5. The process according to claim 1 , wherein a preservative is added to the dispersion and/or predispersion.
6. The process according to claim 1 , wherein the pH of the predispersion is between 2 and 3.9.
7. The process according to claim 1 , wherein the pH of the predispersion is between 2 and 3.8.
8. The process according to claim 1 , wherein the pH of the predispersion is between 2 and 3.7.
9. The process according to claim 1 , wherein said adjusted to pH values of between 2 and 4 by adding an acid is carried out.