Systems for recovering silane from heavy-ends separation operations
View Patent ↗Processes and systems for purifying silane-containing streams are disclosed with relatively less silane being lost in impurity streams by use of distillation and/or condensation operations.
1. A system for purifying a silane-containing stream comprising silane and one or more compounds having a boiling point greater than silane and being substantially free of trichlorosilane, tetrachlorosilane and tetrafluorosilane, the system comprising:
a silane-containing stream conveying apparatus for conveying the silane-containing stream to a heavy-ends distillation column, wherein the silane-containing stream conveying apparatus is operatively connected to the heavy-ends distillation column;
the heavy-ends distillation column for producing a silane-enriched overhead fraction and a silane-depleted bottoms fraction relative to the silane-containing stream, the silane-depleted bottoms fraction produced from the heavy-ends distillation column comprising silane and being enriched in one or more compounds having a boiling point greater than silane relative to the silane-containing stream; and
a silane-recovery distillation column for producing a silane-recovery column silane-enriched overhead fraction and a silane-recovery column silane-depleted bottoms fraction relative to the silane-depleted bottoms fraction produced from the heavy-ends distillation column.
2. The system as set forth in claim 1 comprising a silane-depleted bottoms fraction conveying apparatus for conveying the silane-depleted bottoms fraction produced from the heavy-ends distillation column to the silane-recovery distillation column.
3. The system as set forth in claim 1 comprising:
a silane-containing feed stream conveying apparatus for conveying a silane-containing feed stream to a light-ends distillation column, wherein the silane-containing stream conveying apparatus is operatively connected to the light-ends distillation column;
the light-ends distillation column for producing a silane-depleted overhead fraction that is enriched in compounds having a boiling point less than silane and a silane-enriched bottoms fraction that is depleted in compounds having a boiling point less than silane relative to a silane-containing feed stream introduced into the light-ends distillation column; and
a silane-enriched bottoms fraction conveying apparatus for conveying the silane-enriched bottoms fraction produced from the light-ends distillation column to the heavy-ends distillation column,
wherein the silane-depleted bottoms fraction produced from the heavy-ends distillation column comprises silane and is enriched in one or more compounds having a boiling point greater than silane relative to the silane-enriched bottoms fraction produced from the light-ends distillation column.
4. The system as set forth in claim 1 comprising:
a light-ends distillation column for producing a silane-depleted overhead fraction that is enriched in compounds having a boiling point less than silane and a silane-enriched bottoms fraction that is depleted in compounds having a boiling point less than silane relative to the silane-enriched overhead fraction produced from the heavy-ends distillation column; and
a silane-enriched overhead fraction conveying apparatus for conveying the silane-enriched overhead fraction produced from the heavy-ends distillation column to the light-ends distillation column.
5. The system as set forth in claim 3 comprising a silane-enriched overhead fraction conveying apparatus for conveying the silane-enriched overhead fraction produced from the silane-recovery distillation column to the light-ends distillation column.
6. The system as set forth in claim 3 comprising:
an adsorber for removing a portion of ethylene from the silane-enriched overhead fraction produced from the heavy-ends distillation column and form an ethylene-depleted effluent stream; and
a silane-enriched overhead fraction conveying apparatus for conveying the silane-enriched overhead fraction produced from the heavy-ends distillation column to the adsorber.
7. The system as set forth in claim 6 wherein the adsorber comprises a molecular sieve which causes a portion of the ethylene to react with silane and form ethylsilane, the system comprising:
an ethylsilane distillation column to produce an ethylsilane-depleted overhead fraction comprising purified silane product and an ethylsilane-enriched bottoms fraction relative to the ethylene-depleted effluent stream produced from the adsorber; and
an ethylene-depleted effluent stream conveying apparatus for conveying the ethylene-depleted effluent stream comprising ethylsilane to the ethylsilane distillation column.
8. The system as set forth in claim 7 comprising an ethylsilane-enriched bottoms fraction conveying apparatus for conveying the ethylsilane-enriched bottoms fraction into the light-ends distillation column.