Multi-layer article comprising polyimide nanoweb
View Patent ↗This invention provides a multi-layer article comprising a first electrode material, a second electrode material, and a porous separator disposed between and in contact with the first and the second electrode materials, wherein the porous separator comprises a nanoweb consisting essentially of a plurality of nanofibers of a fully aromatic polyimide. Also provided is a method for preparing the multi-layer article, and an electrochemical cell employing the same. A multi-layer article comprising a polyimide nanoweb with enhanced properties is also provided.
1. A multi-layer article comprising a first electrode material, a second electrode material, and a porous separator disposed between and in contact with the first and the second electrode materials, wherein the porous separator comprises a nanoweb that comprises a plurality of nanofibers wherein the nanofibers consist essentially of a fully aromatic polyimide and wherein the fully aromatic polyimide is characterized by a crystallinity index of 0.2 or greater.
2. The multi-layer article of claim 1 wherein the fully aromatic polyimide comprises PMDA/ODA.
3. The multi-layer article of claim 1 wherein the first electrode material, the separator, and the second electrode material are in mutually adhering contact in the form of a laminate.
4. The multi-layer article of claim 1 further comprising at least one metallic current collector in adhering contact with at least one of the first or second electrode materials.
5. The multi-layer article of claim 4 further comprising
a first layer comprising a first metallic current collector;
a second layer comprising the first electrode material, in adhering contact with the first metallic current collector;
a third layer comprising the porous separator, in adhering contact with the first electrode material;
a fourth layer comprising the second electrode material, adheringly contacting the porous separator;
and,
a fifth layer comprising a second metallic current collector, adheringly contacting the second electrode material.
6. The multi-layer article of claim 5 wherein the first metallic current collector comprises copper foil, the first electrode material comprises carbon, the fully aromatic polyimide comprises PMDA/ODA, the second electrode material comprises lithium cobalt oxide, and the second metallic current collector comprises aluminum foil.
7. The multi-layer article of claim 1 wherein the first and second electrode materials are the same material.
8. The multi-layer article of claim 1 wherein the first and second electrode materials are different material.
9. The multi-layer article of claim 5 wherein the first and second electrode materials are the same material.
10. The multi-layer article of claim 5 wherein the first and second electrode materials are different material.
11. The multi-layer article of claim 5 wherein the first and second metallic current collectors comprise aluminum foil; the first and second electrode materials comprise carbon; and the fully aromatic polyimide comprises PMDA/ODA.