Sensing element and method of making the same
View Patent ↗Disclosed herein is a method of making a sensing element comprising forming an electrically conductive element, wherein the sensing element comprises a metal selected from the group consisting of Pd and alloys and combinations comprising Pd; and wherein the electrically conductive element is thermally stable at temperatures as high as 1,200° C.
1. A method of making a sensing element, comprising:
disposing a sensing electrode and a reference electrode in physical contact with an electrolyte;
disposing a precursor material on a supporting surface, the precursor material comprising a Pd powder that consists essentially of non-spherically shaped Pd particles having a surface area of about 0.5 m 2 /g to about 5.0 m 2 /g, to define an electrically conductive element; and
heating the precursor material to a temperature of greater than or equal to about 1,450° C. for a sufficient period of time to sinter the electrically conductive element and form the sensing element.
2. The method of claim 1 , wherein the precursor material comprises sufficient Pd such that the electrically conductive element comprises greater than or equal to about 50 wt% of Pd, based upon the total weight of the sintered electrically conductive element.
3. The method of claim 1 , wherein the precursor material comprises sufficient amount of a metal oxide such that the electrically conductive element comprises about 0.5 wt% to about 25 wt% of the metal oxide, based upon the total weight of the sintered electrically conductive element.
4. The method of claim 3 , wherein the metal oxide is selected from the group consisting of zirconia, yttria, alumina, lanthana, ceria, magnesia, scandia, and combinations comprising at least one of the foregoing.
5. The method of claim 1 , wherein the sintered electrically conductive element has a sheet resistivity of less than or equal to about 6×10 −3 μΩ·cm.
6. The method of claim 5 , wherein the sheet resistivity is less than or equal to about 4×10 −3 μΩ·cm.
7. The method of claim 6 , wherein the sheet resistivity is less than or equal to about 3×10 −3 μΩ·cm.
8. The method of claim 1 , wherein the sintered electrically conductive element is thermally stable at temperatures as high as 1,200° C.
9. The method of claim 1 , wherein the surface area is about 1.0 m 2 /g to about 4.0 m 2 /g.
10. The method of claim 9 , wherein the surface area is about 2.0 m 2 /g to about 3.0 m 2 /g.
11. The method of claim 1 , wherein the precursor material comprises sufficient amount of a metal selected from the group consisting of Pt, Rh, Ir, as well as combinations comprising at least one of the foregoing metals, such that the electrically conductive element further comprises about 0.25 wt% to about 20 wt% of the metal based upon the total weight of the sintered electrically conductive element.
12. The method of claim 11 , wherein the electrically conductive element comprises about 0.25 wt% to about 10 wt% of the metal based upon the total weight of the sintered electrically conductive element.
13. The method of claim 11 , wherein the metal is Rh.
14. The method of claim 11 , wherein the metal and the Pd are a solid solution in the sintered electrically conductive element.