Ionomers modified with imidized acrylic resins
View Patent ↗Compositions comprising ionomers and imidized acrylic resins are disclosed. Articles prepared from the compositions exhibit improved heat resistance properties such as increased Vicat temperature, increased stiffness/modulus at room temperature and elevated temperatures below the ionomer's melting point, and increased upper use temperature at a given stiffness over those of ionomers alone.
1. A composition comprising, or produced by mixing, a mixture of, based on the weight of the mixture, 70 to 99 weight % of an ionomer composition and 1 to 30 weight % of an imidized acrylic resin wherein
the ionomer composition is produced from at least one ethylene acid copolymer by a process comprising neutralizing at least a portion of the acid moieties in the acid copolymer with a salt containing alkali metal cations, alkaline earth metal cations, transition metal cations, or combinations of two or more thereof;
the ethylene acid copolymer comprises copolymerized comonomers of ethylene, about 3 to about 30 weight % of copolymerized comonomers of at least one C 3 to C 8 α,β ethylenically unsaturated carboxylic acid, and 0 to about 30 weight of copolymerized comomers of at least one C 3 to C 8 α,β ethylenically unsaturated carboxylic acid ester, based on the total weight of the ethylene acid copolymer, and the reminder is ethylene; and
the imidized acrylic resin has a degree of imidization from 20% to 100%.
2. The composition of claim 1 wherein the imidized acrylic resin is obtained by treating an acrylic polymer with ammonia or a monoalkyl amine; the monoalkyl group has from one to five carbon atoms; and the acid level is from 0 to 10 weight % of the imidized acrylic resin.
3. The composition of claim 1 wherein the imidized acrylic resin is obtained by treating polymethyl methacrylate with methyl amine and the degree of imidization of the imidized acrylic resin is 60% to 100%.
4. The composition of claim 1 , 2 , or 3 wherein the imidized acrylic resin comprises cyclic imide units.
5. The composition of claim 3 wherein the degree of imidization of the imidized acrylic resin is 80% to 100%.
6. The composition of claim 5 wherein the acid level of the imidized acrylic resin is from 0 to 2 weight %.
7. The composition of claim 2 wherein the ethylene acid copolymer is a dipolymer consisting essentially of copolymerized comonomers of ethylene and from about 5 to about 30 weight % of copolymerized comonomer of a C 3 to C 8 α,β-ethylenically unsaturated carboxylic acid.
8. The composition of claim 7 wherein the copolymerized comonomer of the C 3 to C 8 α,β-ethylenically unsaturated carboxylic acid is acrylic acid or methacrylic acid and is present in the dipolymer from 10 to 20 weight %.
9. The composition of claim 8 wherein the degree of imidization of the imidized acrylic resin is 80% to 100%.
10. The composition of claim 2 wherein the ethylene acid copolymer is a terpolymer consisting essentially of copolymerized comonomers of ethylene, from about 3 to about 30 weight % of copolymerized comonomers of a C 3 to C 8 α,β-ethylenically unsaturated carboxylic acid, and from about 3 to about 30 weight % of copolymerized comonomers of a C 3 to C 8 α,β ethylenically unsaturated carboxylic acid ester.
11. The composition of claim 10 wherein the copolymerized comonomer of the C 3 to C 8 α,β-ethylenically unsaturated carboxylic acid is acrylic acid or methacrylic acid and is present in the dipolymer from 10 to 20 weight %; and the copolymerized comonomers of a C 3 to C 8 α,β ethylenically unsaturated carboxylic acid ester is alkyl acrylate or alkyl methacrylate and is present in the terpolymer from 10 to 30 weight %.
12. The composition of claim 11 wherein the degree of imidization of the imidized acrylic resin is 80% to 100%.
13. The composition of claim 12 wherein the alkyl acrylate is butyl acrylate.
14. An article comprising or produced from the composition of claim 1 .
15. A method comprising (1) melt blending a ionomer composition and an imidized acrylic resin to produce a molten composition; (2) forming the molten composition into a desired shape; and (3) cooling the molten composition to provide a shaped article wherein
the molten composition comprises, based on the weight of the molten composition, 70 to 99 weight % of the ionomer composition and 1 to 30 weight % of the imidized acrylic resin;
the ionomer composition is produced from at least one ethylene acid copolymer by a process comprising neutralizing at least a portion of the acid moieties in the acid copolymer with a salt containing alkali metal cations, alkaline earth metal cations, transition metal cations, or combinations of two or more thereof;
the ethylene acid copolymer comprises copolymerized comonomers of ethylene, about 3 to about 30 weight % of copolymerized comonomers of at least one C 3 to C 8 α,β-ethylenically unsaturated carboxylic acid, and 0 to about 30 weight % of copolymerized comonomers of at least one C 3 to C 8 α,β ethylenically unsaturated carboxylic acid ester, based on the total weight of the ethylene acid copolymer, and the remainder is ethylene;
the imidized acrylic resin has a degree of imidization from 20% to 100%;
the shaped article has a Vicat temperature, determined according to ASTM D1525, that exceeds that of a comparison standard article; and
the shaped article and the comparison standard article have the same shape and structure with the exception that the comparison standard article is produced from the ionomer composition that does not comprise the imidized acrylic resin.
16. The method of claim 15 further comprising reacting polymethyl methacrylate with methyl amine to produce the imidized acrylic resin.
17. The method of claim 15 wherein the ethylene acid copolymer is a dipolymer consisting essentially of copolymerized comonomers of ethylene and from about 5 to about 30 weight % of copolymerized comonomer of a C 3 to C 8 α,β-ethylenically unsaturated carboxylic acid.
18. The method of claim 17 wherein the copolymerized comonomer of the C 3 to C 8 α,β-ethylenically unsaturated carboxylic acid is acrylic acid or methacrylic acid and is present in the dipolymer from 10 to 20 weight %.
19. The method of claim 15 wherein the ethylene acid copolymer is a terpolymer consisting essentially of copolymerized comonomers of ethylene, from about 3 to about 30 weight % of copolymerized comonomers of a C 3 to C 8 α,β-ethylenically unsaturated carboxylic acid, and from about 3 to about 30 weight % of copolymerized comonomers of a C 3 to C 8 α,β ethylenically unsaturated carboxylic acid ester.
20. The method of claim 19 wherein the copolymerized comonomer of the C 3 to C 8 α,β-ethylenically unsaturated carboxylic acid is acrylic acid or methacrylic acid and is present in the dipolymer from 10 to 20 weight %; and the copolymerized comonomers of a C 3 to C 8 α,β ethylenically unsaturated carboxylic acid ester is alkyl acrylate or alkyl methacrylate and is present in the terpolymer from 10 to 30 weight %.