Nitrile rubbers
View Patent ↗Through the use of an improved iron-based redox system it is possible to prepare special new, optionally hydrogenated, nitrile rubbers which feature a more uniform monomer distribution and a lower fraction of long-chain branches and hence are distinguished by enhanced flow properties at the same time as very good properties on processing.
1. A process for producing nitrile rubbers, comprising:
performing an emulsion polymerization of
at least one α,β-unsaturated nitrile, and
at least one conjugated diene,
wherein the emulsion polymerization is carried out using a redox system, said redox system comprising
an oxidizing agent comprising at least one peroxo compound,
at least one reducing agent, and
Fe(II) chloride.
2. The process according to claim 1 , wherein the at least one peroxo compound comprises at least one of hydrogen peroxide, peroxodisulphates, peroxodiphosphates, hydroperoxides, peracids, peracid esters, peracid anhydrides, peroxides having two organic moieties, or mixtures thereof.
3. The process according to claim 1 , wherein the at least one peroxo compound comprises at least one of sodium, potassium or ammonium salts of peroxodisulphuric acid or peroxodiphosphoric acid, t-butyl hydroperoxide, cumene hydroperoxide, pinane hydroperoxide, p-menthane hydroperoxide, dibenzoyl peroxide, 2,4,-dichlorobenzoyl peroxide, di-t-butyl peroxide, dicumyl peroxide, t-butyl perbenzoate or t-butyl peracetate, or mixtures thereof.
4. The process according to claim 1 , wherein the at least one reducing agent comprises at least one of sodium formaldehyde-sulphoxylate, sodium benzaldehyde-sulphoxylate, reducing sugars, ascorbic acid, sulphenates, sulphinates, sulphoxylates, dithionite, sulphite, metabisulphite, disulphite, sugars, urea, thiourea, xanthogenates, thioxanthogenates, hydrazinium salts, amines and amine derivatives, aniline, dimethylaniline, monoethanolamine, diethanolamine,triethanolamine, and mixtures thereof.
5. The process according to claim 1 , wherein the emulsion polymerization is carried out in the presence of sodium ethylenediaminetetraacetate (EDTA), sodium silicate, sodium pyrophosphate or sodium polyphosphate or trisodium phosphate.
6. The process according to claim 1 , wherein the at least one peroxo compound comprises at least one of pinane hydroperoxide or p-menthane hydroperoxide, and
wherein the at least one reducing agent comprises sodium formaldehyde-sulphoxylate, and Fe(II) chloride in the form of FeCl 2 *4 H 2 O, and further wherein EDTA is present in the emulsion polymerization.
7. The process according to claim 1 , further comprising: after the emulsion polymerization, performing a metathesis reaction whereby the molecular weight of the rubber is reduced.
8. The process according to claim 1 , wherein the emulsion polymerization further comprises one or more copolymerizable monomers in addition to the at least one α,β-unsaturated nitrile and the at least one conjugated diene.
9. The process according to claim 7 , further comprising: after the metathesis reaction, performing a hydrogenation reaction.
10. The process according to claim 1 , further comprising: after the emulsion polymerization, performing a hydrogenation reaction.