Method for purifying tetrafluoroethylene
View Patent ↗To provide a method for purifying tetrafluoroethylene by removing, from tetrafluoroethylene containing a polymerization inhibitor, the polymerization inhibitor by adsorption. A method of bringing tetrafluoroethylene containing a polymerization inhibitor into contact with a silica gel containing a metal salt in an amount of from 250 to 100,000 mass ppm as calculated as metal atoms to remove the polymerization inhibitor by adsorption, and the metal salt is preferably a salt of a metal of Group 3 to 13 of the Periodic Table, more preferably a salt of a metal of Group 8 to 10 of the Periodic Table. For example, as the metal salt, a salt of at least one metal selected from the group consisting of iron, cobalt, nickel, ruthenium, rhodium, palladium, osmium, iridium and platinum may be used.
1. A method for purifying tetrafluoroethylene, which comprises bringing tetrafluoroethylene comprising a polymerization inhibitor into contact with a silica gel comprising a metal salt in an amount of from 250 to 100,000 mass ppm as calculated as metal atoms to remove the polymerization inhibitor by adsorption,
wherein the metal salt is a salt of at least one metal selected from the group consisting of iron, cobalt, nickel, ruthenium, rhodium, palladium, osmium, iridium and platinum, and
wherein the polymerization inhibitor is a terpene.
2. The method for purifying tetrafluoroethylene according to claim 1 , wherein the metal salt is a salt of at least one metal selected from the group consisting of iron and cobalt.
3. The method for purifying tetrafluoroethylene according to claim 1 , wherein the silica gel is produced by immersing a starting material silica gel in an aqueous solution in which the metal salt is dissolved.
4. The method for purifying tetrafluoroethylene according to claim 1 , wherein the metal salt is an iron salt.
5. The method for purifying tetrafluoroethylene according to claim 4 , wherein the content of the iron salt in the silica gel is from 300 to 10,000 mass ppm as calculated as iron atoms.
6. The method for purifying tetrafluoroethylene according to claim 4 , wherein the silica gel further comprises cobalt chloride in an amount of from 400 to 50,000 mass ppm as calculated as cobalt atoms.
7. The method for purifying tetrafluoroethylene according to claim 1 , wherein the specific surface area of the silica gel is from 100 m 2 /g to 1,000 m 2 /g.
8. The method for purifying tetrafluoroethylene according to claim 1 , wherein the average particle size of the silica gel is from 0.1 mm to 10 mm.
9. The method for purifying tetrafluoroethylene according to claim 1 , wherein the temperature at which the tetrafluoroethylene comprising the polymerization inhibitor and the silica gel are brought into contact with each other is from −20° C. to 20° C.
10. The method for purifying tetrafluoroethylene according to claim 1 , wherein when the tetrafluoroethylene comprising the polymerization inhibitor and the silica gel are brought into contact with each other, the linear velocity of the tetrafluoroethylene is from 0.005 m/sec to 1 m/sec.
11. The method for purifying tetrafluoroethylene according to claim 1 , wherein the content of the metal salt in the silica gel is from 300 to 10,000 mass ppm as calculated as metal atoms.
12. The method for purifying tetrafluoroethylene according to claim 1 , wherein the content of the metal salt in the silica gel is from 400 to 5,000 mass ppm as calculated as metal atoms.
13. The method for purifying tetrafluoroethylene according to claim 4 , wherein the specific surface area of the silica gel is 100 m 2 /g to 1,000 m 2 /g.
14. The method for purifying tetrafluoroethylene according to claim 4 , wherein the silica gel is in the form of particles, the average particle size of the silica gel being 0.1 mm to 10 mm.
15. The method for purifying tetrafluoroethylene according to claim 1 , wherein the content of the polymerization inhibitor in said tetrafluoroethylene prior to contact with said silica gel is 10 to 1,000 mass ppm, and wherein the content of the polymerization inhibitor in said tetrafluoroethylene after contact with said silica gel is less than 1 mass ppm.
16. The method for purifying tetrafluoroethylene according to claim 4 , wherein the iron salt is ferrous sulfate, ferric sulfate, ferrous chloride, ferric chloride, ferrous nitrate or ferric nitrate.
17. The method for purifying tetrafluoroethylene according to claim 4 , wherein the content of the polymerization inhibitor in said tetrafluoroethylene prior to contact with said silica gel is 10 to 1,000 mass ppm, and wherein the content of the polymerization inhibitor in said tetrafluoroethylene after contact with said silica gel is less than 1 mass ppm.