Production of polycrystalline silicon in substantially closed-loop systems
View Patent ↗Production of polycrystalline silicon in a substantially closed-loop process is disclosed. The processes generally include decomposition of trichlorosilane produced from metallurgical grade silicon.
1. A system for producing polycrystalline silicon by decomposition of trichlorosilane, the system being substantially closed-loop with respect to trichlorosilane, the system comprising:
a chlorination reactor in which hydrogen chloride is contacted with silicon to produce trichlorosilane and silicon tetrachloride;
a fluidized bed reactor in which trichlorosilane is decomposed to produce polycrystalline silicon;
a hydrogenation reactor in which silicon tetrachloride and hydrogen are introduced to produce trichlorosilane;
a hydrogenated gas separator to which hydrogenated gas from the hydrogenation reactor is directly introduced, the hydrogenated gas comprising trichlorosilane, hydrogen chloride, unreacted hydrogen and unreacted silicon tetrachloride, wherein the hydrogenated gas separator separates trichlorosilane and unreacted silicon tetrachloride from hydrogen and unreacted hydrogen chloride; and
a purification system to which trichlorosilane and silicon tetrachloride are directly introduced from the chlorination reactor to separate trichlorosilane and silicon tetrachloride.
2. The system as set forth in claim 1 comprising:
a conveying apparatus selected from the group consisting of a recirculation fan and a blower for conveying trichlorosilane from the hydrogenation reactor to the fluidized bed reactor; and
a conveying apparatus selected from the group consisting of a recirculation fan and a blower for conveying trichlorosilane from the chlorination reactor to the fluidized bed reactor.
3. The system as set forth in claim 1 comprising:
a conveying apparatus selected from the group consisting of a recirculation fan and a blower for conveying trichlorosilane from the purification system to the fluidized bed reactor; and
a conveying apparatus selected from the group consisting of a recirculation fan and a blower for conveying silicon tetrachloride from the purification system to the hydrogenation reactor.
4. The system as set forth in claim 1 comprising an effluent gas separator to which effluent gas from the fluidized bed reactor is introduced, the effluent gas comprising silicon tetrachloride, hydrogen and unreacted trichlorosilane, wherein the effluent gas separator separates hydrogen from trichlorosilane and silicon tetrachloride.
5. The system as set forth in claim 4 comprising a conveying apparatus selected from the group consisting of a recirculation fan and a blower for conveying trichlorosilane and silicon tetrachloride from the effluent gas separator to the purification system.
6. The system as set forth in claim 1 comprising a conveying apparatus selected from the group consisting of a recirculation fan and a blower for conveying trichlorosilane and unreacted silicon tetrachloride from the hydrogenated gas separator to the purification system.
7. The system as set forth in claim 1 comprising a separation system to which hydrogen and hydrogen chloride from the hydrogenated gas separator are introduced to separate hydrogen and hydrogen chloride.
8. The system as set forth in claim 7 comprising:
a conveying apparatus selected from the group consisting of a recirculation fan and a blower for conveying hydrogen chloride from the separation system to the chlorination reactor; and
a conveying apparatus selected from the group consisting of a recirculation fan and a blower for conveying hydrogen from the separation system to at least one of the fluidized bed reactor and the hydrogenation reactor.