IP Library Granted Patent US 8,974,589
Granted Patent B2
US 8,974,589 · App. 12/911,486 · Granted Mar 10, 2015

Silicone protectant compositions

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Quick Facts
Patent No.
US 8,974,589
App. No.
12/911,486
Granted
Mar 10, 2015
Kind
B2
Abstract

The present invention relates generally to compositions and methods of use for an automotive protectant composition and/or automotive cleaning composition. The protectant composition and/or cleaning composition includes silicone, organic solvent, rheology modifier and water. The composition also optionally includes other components. The weight ratio of the silicon to the organic solvent is at least 0.5:1 and generally no more than 3:1. The organic solvent generally is or includes mineral oil.

Claims (75)

1. A silicone based automotive protectant composition comprising:

a. at least 0.5 weight percent and up to 10 weight percent silicone;

b. at least 0.1 weight percent and up to 10 weight percent of an organic solvent comprising oil selected from the group consisting of:

a mineral oil, a natural oil, and combinations or mixtures thereof, wherein said organic solvent includes more than 60 weight percent mineral oil;

c. from 0.01 to 3 weight percent of a rheology modifier; and

d. from 60 to 98 weight percent water;

wherein a weight ratio of said silicone to said organic solvent is 0.5-3:1, wherein said protectant composition is sprayable or pumpable and has a viscosity of 1600-3100 cSt (25° C.), and wherein no surfactant is included in said protectant composition.

2. The protectant composition as defined in claim 1 , wherein said weight ratio of said silicone to said organic solvent is over 0.5:1: and up to 2:1.

3. The protectant composition as defined in claim 2 , wherein said weight ratio of said silicone to said organic solvent is 0.75-1.5:1.

4. The protectant composition as defined in claim 1 , comprising by weight percent:

Silicone

 1.1-9.9%

Organic Solvent

 1.1-9.9%

Rheology Modifier

0.04-0.6%

Rheology Modifying Agent

  0-0.5%

Buffering or

0.01-0.22%

pH Adjusting Agent

Biocide or Preservative

0.01-0.55%

Surfactant

  0-0.44%

Opacifier

0.02-0.9%

Fragrance

  0-0.44%

Water

  72-97%

and wherein a silicone to organic solvent weight ratio is 0.7-1.3:1, said organic solvent including at least 75 weight percent mineral oil.

5. The protectant composition as defined in claim 1 , comprising by weight percent:

Silicone

  1-11%

Organic Solvent

  1-11%

Rheology Modifier

 0.1-1.5%

Rheology Modifying Agent

  0-1%

Buffering and/or

0.01-0.2%

pH Adjusting Agent

Biocide or Preservative

  0-0.5%

Surfactant

  0-0.1%

Opacifier

  0-0.9%

Fragrance

  0-0.4%

Water

  72-97%

and wherein a silicone to organic solvent weight ratio is 0.7-1.4:1, said organic solvent including at least 95 weight percent mineral oil.

6. The protectant composition of claim 1 wherein the composition provides similar or higher gloss, shine, spreadability and/or protection to a substrate surface in comparison to a protectant composition having a weight percent silicone greater than 10 weight percent, and a surfactant present.

7. The protectant composition of claim 1 which protects a substrate surface from heat damage and/or fading to sun exposure.

8. The protectant composition of claim 1 which protects a substrate surface from damaging effects of UV rays, sunlight, heat and moisture.

9. The protectant composition as defined in claim 1 , wherein said organic solvent includes more than 90 weight percent mineral oil.

10. The protectant composition as defined in claim 1 , further comprising at least one ingredient selected from the group consisting of a rheology modifying agent, buffering or pH adjusting agent, biocide or preservative, opacifier, fragrance, and combinations thereof

11. The protectant composition as defined in claim 10 , wherein said at least one ingredient comprises from 0.0001 to 5 weight percent of the protectant composition.

12. A silicone based automotive protectant composition comprising:

a. over 0.5 weight percent and up to 10 weight percent silicone;

b. at least 0.1 weight percent and up to 10 weight percent of an organic solvent, said organic solvent comprising at least 80 weight percent mineral oil;

c. from 0.01 to 3 weight percent of a rheology modifier; and

d. from 70 to 98 weight percent water;

wherein a weight ratio of said silicone to said organic solvent is 0.6-2:1, wherein said protectant composition is spra able or pumpable and has a viscosity of 1600-3100 cSt (25° C.), and wherein no surfactant is included in said protectant composition.

13. The protectant composition as defined in claim 12 , wherein said weight ratio of said silicone to said organic solvent is 0.75-1.5:1.

14. The protectant composition as defined in claim 12 , wherein said organic solvent includes more than 90 weight percent mineral oil.

15. A sprayable silicone based automotive protectant composition comprising:

a. over 0.8 weight percent and up to 10 weight percent silicone;

b. at least 0.1 weight percent and up to less than 10 weight percent of an organic solvent, said organic solvent including at least 90 weight percent mineral oil, natural oil or a combination thereof;

c. from 0.01 to 3 weight percent of a rheology modifier; and

d. from 70 to 98 weight percent water;

wherein a weight ratio of said silicone to said organic solvent is 0.75-1.8:1, wherein said protectant composition is sprayable or pumpable and has a viscosity of 1600-3100 cSt (25° C.), and wherein no surfactant is included in said protectant composition.

Assignments (9)
AMENDED AND RESTATED INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Mar 19, 2025
From: ENERGIZER BRANDS, LLC; ENERGIZER AUTO, INC.,; ENERGIZER AUTO SALES, INC.
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 070565/0282 →
PATENT SECURITY AGREEMENT Recorded Dec 30, 2020
From: ENERGIZER BRANDS, LLC; ENERGIZER AUTO, INC.
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 054875/0651 →
CHANGE OF NAME Recorded Oct 25, 2019
From: THE ARMOR ALL/STP PRODUCTS COMPANY
To: ENERGIZER AUTO, INC.
Reel/Frame 050829/0790 →
RELEASE OF SECURITY INTEREST Recorded Jan 30, 2019
From: ROYAL BANK OF CANADA
To: THE ARMOR ALL/STP PRODUCTS COMPANY
Reel/Frame 048183/0811 →
SECURITY INTEREST Recorded Jan 28, 2019
From: THE ARMOR ALL/STP PRODUCTS COMPANY
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 048157/0549 →
NOTICE OF SUCCESSOR AGENT AND ASSIGNMENT OF SECURITY INTEREST (INTELLECTUAL PROPERTY) REEL/FRAME 036131/0722 Recorded Jun 5, 2018
From: DEUTSCHE BANK AG NEW YORK BRANCH
To: ROYAL BANK OF CANADA
Reel/Frame 046303/0421 →
SECURITY INTEREST Recorded Jul 20, 2015
From: THE ARMOR ALL/STP PRODUCTS COMPANY
To: DEUTSCHE BANK AG NEW YORK BRANCH, AS COLLATERAL AGENT
Reel/Frame 036131/0722 →
RELEASE OF SECURITY INTEREST Recorded Jul 14, 2015
From: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS COLLATERAL TRUSTEE
To: APPLICA CONSUMER PRODUCTS, INC.; APPLICA CONSUMER PRODUCTS, INC., A CORP. OF FLORIDA; KWIKSET CORPORATION; LIQUID HOLDING COMPANY, INC.; NATIONAL MANUFACTURING CO.; PRICE PFISTER, INC.; ROV HOLDING, INC., A CORP. OF DELAWARE; ROVCAL, INC.; ROVCAL, INC., A CORP. OF CALIFORNIA; RUSSELL HOBBS, INC., A CORP. OF DELAWARE; SALIX ANIMAL HEALTH, LLC; SEED RESOURCES, L.L.C.; SPECTRUM BRANDS, INC.; SPECTRUM BRANDS, INC. AS SUCCESSOR IN INTEREST TO ROVCAL, INC.; SPECTRUM BRANDS, INC., A CORP. OF DELAWARE; TELL MANUFACTURING, INC.; TETRA HOLDING (US), INC., A CORP. OF DELAWARE; TETRA HOLDINGS (US), INC.; UNITED INDUSTRIES CORPORATION; UNITED INDUSTRIES CORPORATION AS SUCCESSOR IN INTEREST TO LIQUID HOLDING COMPANY, INC.; UNITED PET GROUP, INC.; UNITED PET GROUP, INC., A CORP. OF DELAWARE
Reel/Frame 036102/0001 →
RELEASE OF SECURITY INTEREST Recorded May 28, 2015
From: JPMORGAN CHASE BANK, N.A.
To: THE ARMOR ALL/STP PRODUCTS COMPANY
Reel/Frame 035736/0697 →