Fluorinated elastic copolymer composition and its cross-linked rubber member
View Patent ↗To provide a fluorinated elastic copolymer composition, and a cross-linked rubber member obtained by crosslinking the fluorinated elastic copolymer composition, which is excellent in hot water resistance and steam resistance under severe conditions. A fluorinated elastic copolymer composition, which comprises a fluorinated elastic copolymer and a compound represented by the following formula (1) wherein the compound represented by the following formula (1) is contained in an amount of from 0.1 to 10 parts by mass per 100 parts by mass of the fluorinated elastic copolymer: (RCOO − ) n M n+ (1) (wherein R is a C 10-30 organic group, n is an integer of 2 or 3, and M is an alkaline earth metal, Zn, Cd, Co, Sn, Cu, Pb, Ni or Al).
1. A fluorinated elastic copolymer composition, comprising:
a tetrafluoroethylene-propylene elastic copolymer; and
a compound of formula (1):
(RCOO − ) n M n+ (1)
wherein R is a C 10-30 organic group, n is an integer of 2 or 3, and M is an alkaline earth metal, Zn, Cd, Co, Sn, Cu, Pb, Ni or Al, and
an organic peroxide, and
an amount of the compound of formula (1) is from 0.1 to 10 parts by mass per 100 parts by mass of the tetrafluoroethylene-propylene elastic copolymer and
wherein a volume swell ratio in a steam resistance test at 170° C. for 70 hours according to JIS K6258 of a member obtained by press-crosslinking the fluorinated elastic copolymer composition with triallyl isocyanurate is less than 3%.
2. The fluorinated elastic copolymer composition according to claim 1 , wherein R is a C 10-25 linear saturated aliphatic hydrocarbon group.
3. The fluorinated elastic copolymer composition according to claim 1 , wherein M is Mg, Ba, Ca, Zn or Al.
4. The fluorinated elastic copolymer composition according to claim 1 , wherein the compound of formula (1) is at least one selected from the group consisting of zinc stearate, calcium stearate, barium stearate, magnesium stearate and aluminum stearate.
5. The fluorinated elastic copolymer composition according to claim 1 , wherein the organic peroxide is at least one selected from the group consisting of benzyl peroxide, dicumyl peroxide, di-tert-butyl peroxide, 2,5-dimethyl-2,5-bis(tert-butylperoxy)hexane, 2,5-dimethyl-2,5-bis(t-butylperoxy)hexyne-3,α,α′-bis(tert-butylperoxy)-p-diisopropylenebenzene and 1,1-bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane.
6. The fluorinated elastic copolymer composition according to claim 1 , wherein a content of the organic peroxide is from 0.3 to 10 parts by mass per 100 parts by mass of the fluorinated elastic copolymer.
7. The fluorinated elastic copolymer composition according to claim 1 , further comprising at least one cross-linking coagent selected from the group consisting of triallyl cyanurate, triallyl isocyanurate and trimethallyl isocyanurate.
8. The fluorinated elastic copolymer composition according to claim 7 , wherein a content of the cross-linking coagent is from 0.1 to 10 parts by mass, per 100 parts by mass of the fluorinated elastic copolymer.
9. The fluorinated elastic copolymer composition according to claim 1 , wherein a Mooney viscosity [ML 1+4 (100° C.)] of the fluorinated elastic copolymer is from 20 to 180.
10. A cross-linked rubber member obtained by cross-linking the fluorinated elastic copolymer composition as defined in claim 1 by an organic peroxide or an ionizing radiation.
11. The cross-linked rubber member according to claim 10 , wherein a volume swell ratio of the member is at most 5% in a hot water resistance test at 180° C. for 70 hours in accordance with JIS K6258.
12. The cross-linked rubber member according to claim 10 , wherein a volume swell ratio of the member is at most 10% in a steam resistance test at 170° C. for 70 hours in accordance with JIS K6258.
13. A hot water resistant apparatus, comprising the cross-linked rubber member as defined in claim 10 .
14. A steam resistant apparatus, comprising the cross-linked rubber member as defined in claim 10 .