Methods and compositions for preventing or reducing frizzy appearance of hair
View Patent ↗Compositions and methods are disclosed for preventing or reducing frizzy appearance of keratin fibers, including hair, and reducing the amount of fly-away strands of hair, particularly in humid conditions, by forming a coating on hair that is resistant to water vapors from the air or surrounding environment. The compositions comprise a combination of a hydrophobic particulate material comprising a hydrophobically surface-modified oxide and one or more hydrophobic film formers in a cosmetically acceptable vehicle.
1. A method for preventing or reducing frizzy appearance of hair comprising applying to frizzy hair a composition comprising:
(a) a hydrophobic particulate material having a median particle size between about 10 nm and about 20 μm, said hydrophobic particulate material being from about 0.1% to about 2.0% by weight of said composition;
(b) a silicone-based hydrophobic film former being from about 0.5% to about 20% by weight of said composition, said silicone-based hydrophobic film former selected from the group consisting of amodimethicone, dimethiconol, silicone polyurethane, silicone acrylate, or a combination thereof; and
(c) a volatile hydrocarbon or silicone fluid having a vapor pressure above about 0.01 mmHg at 20° C.;
wherein the aggregate weight percentage of all non-volatile water-soluble or water-dispersible organic constituents in said composition is less than 5%, based on the entire weight of the composition, thereby preventing or reducing the frizzy appearance of hair as compared to otherwise identical hair that has not been treated; and wherein an emulsifier is absent from said composition.
2. The method according to claim 1 , wherein said hydrophobic particulate material comprises a hydrophobically surface-modified oxide selected from the group consisting of aluminum oxide, silicon dioxide, titanium dioxide, zirconium dioxide, tin dioxide, zinc oxide, iron oxide, and combinations thereof.
3. The method according to claim 2 , wherein said oxide is surface modified with alkylsilane groups.
4. The method according to claim 3 , wherein said alkylsilane is caprylylsilane.
5. The method according to claim 2 , wherein said oxide is alumina or silica.
6. The method according to claim 5 , wherein said alumina or silica is fumed alumina or fumed silica.
7. The method according to claim 6 , wherein the fumed alumina or fumed silica is surface modified with alkylsilane groups.
8. The method according to claim 7 , wherein said alkylsilane is caprylylsilane.
9. The method according to claim 1 , wherein said silicone-based hydrophobic film former comprises a silicone acrylate copolymer.
10. The method according to claim 9 , wherein said silicone acrylate copolymer is a copolymer comprising a poly(alkyl)acrylate backbone and a dimethicone polymer grafted to an alkyl ester side chain.
11. The method according to claim 1 , wherein in the applying step, the composition is distributed through the hair with a brush, a comb or fingers.
12. The method according to claim 1 , wherein said step of applying distributes said composition across strands of the hair to form a coating on shafts of hair fibers.
13. The method according to claim 1 , the frizzy appearance of said hair is reduced or prevented following at least one shampooing as compared to otherwise identical hair that has not been treated.
14. The method according to claim 1 , wherein the frizzy appearance of said hair is reduced or prevented following at least two shampooings as compared to otherwise identical hair that has not been treated.
15. The method according to claim 1 , wherein frizz volume of hair is reduced as compared to otherwise identical hair that has not been treated.
16. The method according to claim 1 , wherein said composition is applied daily to the hair.
17. The method according to claim 1 , wherein said composition is applied to the hair when the ambient relative humidity is 85% or above.
18. The method according to claim 1 , wherein the composition comprises said volatile silicone fluid having a vapor pressure above about 0.01 mmHg at 20° C.
19. The method according to claim 18 , wherein the volatile silicone fluid is selected from the group comprising cyclomethicone tetramer, cyclomethiconepentamer, cyclomethiconehexamer, trisiloxane, methyl trimethicone, or combinations thereof.
20. The method according to claim 1 , wherein the weight ratio of said hydrophobic particulate material to said silicone-based hydrophobic film former is from about 1:5 to about 1:100.
21. The method according to claim 1 , wherein the weight ratio of said hydrophobic particulate material to said silicone-based hydrophobic film former is from about 1:8 to about 1:20.
22. The method according to claim 15 , wherein the reduction of the frizz volume of hair as compared to otherwise identical hair that has not been treated is at least about 50%.