IP Library Granted Patent US 9,000,157
Granted Patent B2
US 9,000,157 · App. 12/913,274 · Granted Apr 7, 2015

Metallic compound and organic electroluminescence device comprising the same

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Quick Facts
Patent No.
US 9,000,157
App. No.
12/913,274
Granted
Apr 7, 2015
Kind
B2
Abstract

The present invention relates to an organic electroluminescence device containing a light emitting metallic compound of Chemical Formula 1. In the Chemical Formula 1, M is selected from Ir, Pt, Rh, Re, and Os, and m is 2, provided that m is 1 when M is Pt.

Claims (18)

1. An organic electroluminescence device comprising the compound represented by the following Chemical Formula 1:

wherein, M is selected from Ir, Pt, Rh, Re, or Os, m is 2, provided that m is 1 when M is Pt,

 of the Chemical Formula 1 is represented by the following Chemical Formulae 2:

wherein, a portion denoted as * in the above Chemical Formulae 2 has a carboxyl substituent, and transition metal M forms a complex compound by a covalent bond with the carboxyl group and a coordination bond with an adjacent N or P atom, and

R1-R4 are the same or different, and are hydrogen, a C1 to C20 alkyl excluding an aromatic cyclic substituent, a cycloalkyl, or a halogen, and

L1 is represented by the following formula 3:

wherein, L1 in the above formula 3 is a independent ligand having a covalent bond site with a carbon denoted as * and a coordination bond with nitrogen and forming a complex compound with the transition metal M of the Formula 1,

X is a hetero atom of nitrogen, oxygen, sulfur, or phosphorus, and

Z1 and Z2 are atoms for forming a C4 to C7 aromatic hydrocarbon ring or aromatic heterocyclic ring and represented by any one of the following Chemical Formulae 5:

2. An organic electroluminescence device comprising the compound represented by the following Chemical Formula 1:

wherein, M is selected from Ir, Pt, Rh, Re, or Os, m is 2, provided that m is 1 when M is Pt,

 of the Chemical Formula 1 is represented by the following Chemical Formulae 2:

wherein, a portion denoted as * in the above Chemical Formulae 2 has a carboxyl substituent, and transition metal M forms a complex compound by a covalent bond with the carboxyl group and a coordination bond with an adjacent N or P atom, and

R 3 -R 4 are the same or different, and are hydrogen, a C1 to C20 alkyl excluding an aromatic cyclic substituent, a cycloalkyl, or a halogen, and

L 1 is represented by the following formula 3:

wherein, L 1 in the above formula 3 is a independent ligand having a covalent bond site with a carbon denoted as * and a coordination bond with nitrogen and forming a complex compound with the transition metal M of the Formula 1,

X is a hetero atom of nitrogen, oxygen, sulfur, or phosphorus, and

Z 1 and Z 2 are atoms for forming a C4 to C7 aromatic hydrocarbon ring or aromatic heterocyclic ring and represented by any one of the following Chemical Formulae 5:

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 11, 2012
From: SAMSUNG ELECTRONICS CO., LTD.
To: SAMSUNG DISPLAY CO., LTD.
Reel/Frame 029151/0055 →