IP Library Granted Patent US 8,435,322
Granted Patent B2
US 8,435,322 · App. 12/916,132 · Granted May 7, 2013

Enhanced process to produce a thermofertiliser from potassium-bearing minerals

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Quick Facts
Patent No.
US 8,435,322
App. No.
12/916,132
Granted
May 7, 2013
Kind
B2
Abstract

A simplified and enhanced process to produce thermofertiliser obtained from potassium and phosphorous-bearing minerals is provided, where these elements may or may not be in citric acid or insoluble in water. The process also includes the use of specific additives, at the beginning of the process or immediately before the beginning of the thermal treatment step, in order to increase the potassium and phosphorous contents in the product and the overall efficiency of the process and also to promote the production of a high quality thermofertiliser.

Claims (27)

1. A method of producing a thermofertiliser from potassium-bearing minerals comprising:

grinding the potassium-bearing minerals;

screening a size of the potassium-bearing minerals to determine whether the size of the potassium-bearing minerals is within a first size range;

when the size of the potassium-bearing minerals is within the first size range, mixing the potassium-bearing minerals with a first set of additives;

heating the mixed potassium-bearing minerals to a first temperature for a period of time;

cooling the mixed potassium-bearing minerals down to a second temperature after the period of time;

grinding the mixed potassium-bearing minerals;

screening the size of the mixed potassium-bearing minerals to determine whether the size of the mixed potassium-bearing minerals is within a second size range; and

when the size of the potassium-bearing minerals is within the second size range, mixing the potassium-bearing minerals with a second set of additives so as to form said thermofertiliser.

2. The method of claim 1 , wherein the first set of additives comprises at least one of limestone, sylvinite or muriate of potash.

3. The method of claim 1 , wherein the second set of additives comprises at least one of boron, manganese, copper, cobalt or molybdenum.

4. The method of claim 1 , wherein the first size range of the potassium-bearing minerals is between about 0.037 mm and about 2 mm.

5. The method of claim 1 , further comprising agglomerating the potassium-bearing minerals after the mixing with the first set of additives and before the heating.

6. The method of claim 1 , wherein heating the mixed potassium-bearing minerals comprises calcinating and sintering the mixed potassium-bearing minerals.

7. The method of claim 1 , wherein the heating results in the mixed potassium-bearing minerals undergoing micro-fusions following the heating.

8. The method of claim 1 , wherein the heating is performed in a rotary kiln.

9. The method of claim 4 , wherein the heating is performed in a rotary kiln.

10. The method of claim 6 , wherein the heating is performed in a rotary kiln.

11. The method of claim 7 , wherein the heating is performed in a rotary kiln.

12. The method of claim 5 , wherein the heating is performed in a sintering roaster.

13. The method of claim 1 , wherein the first temperature is in a range of about 300° C. to about 1,600° C.

14. The method of claim 1 , wherein the first temperature is in a range of about 850° C. to about 1,300° C.

15. The method of claim 1 , wherein the period of time is in a range of about 1 hour to about 10 hours.

16. The method of claim 1 , wherein the period of time is in a range of about 1 hour to about 4.5 hours.

17. The method of claim 1 , wherein the heating comprises using an energy source comprising one of coal, biomass, oil or gas.

18. The method of claim 1 , wherein the cooling is performed using one of air or water.

19. The method of claim 13 , wherein the period of time is in a range of about 1 hour to about 10 hours.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 26, 2017
From: VALE S.A.
To: VALE FERTILIZANTES S.A.
Reel/Frame 042998/0171 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 8, 2011
From: AILTON RODRIGUES, SEBASTIAO; GOMES DA SILVA, RUBERLAN
To: VALE S.A.
Reel/Frame 026411/0095 →