IP Library Granted Patent US 8,474,541
Granted Patent B2
US 8,474,541 · App. 12/917,343 · Granted Jul 2, 2013

Glass forming hardbanding material

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Quick Facts
Patent No.
US 8,474,541
App. No.
12/917,343
Granted
Jul 2, 2013
Kind
B2
Abstract

A drill pipe and a method of applying hardbanding thereto. A hardbanding alloy comprising iron and manganese present in the range of 67 to 87 weight percent (wt. %), niobium and chromium present in the range of 9 to 29 wt. %, and boron, carbon and silicon present in the range of 3 to 6.5 wt. % may be welded around at least a portion of a tool joint circumference. The hardbanding alloy may exhibit a hardness of 45 Rc to 70 Rc and a wear rate in the range of 0.08 grams to 1.60 grams of mass loss after 6,000 cycles as measured using ASTM G65-04, Procedure A.

Claims (61)

1. A method of applying a hardband to a drill pipe containing a tool joint circumference, comprising:

welding around at least a portion of said tool joint circumference a hardbanding alloy comprising iron and manganese present in the range of 67 to 87 weight percent (wt. %), niobium and chromium present in the range of 9 to 29, and boron, carbon and silicon present in the range of 3 to 6.5 wt. %; and

cooling said hardbanding alloy, wherein said hardbanding alloy as welded exhibits a hardness of 45 Rc to 70 Rc and a wear rate in the range of 0.08 grams to 1.60 grams of mass loss after 6,000 cycles as measured using ASTM G65-04, Procedure A;

wherein said hardbanding alloy further comprises:

iron present in the range of 67.0 to 86.0 wt. %;

manganese present in the range of 0.05 to 0.3 wt. %;

niobium present in the range of 3.5 to 6.0 wt. %;

chromium present in the range of 6.0 to 23.0 wt. %;

boron present in the range of 2.5 to 4.5 wt. %;

carbon present in the range of 0.5 to 2 wt. %; and

silicon present in the range of 0.2 to 0.5 wt. % wherein said alloy contains up to 2.0 wt. % of an elemental impurity.

2. The method of claim 1 further comprising preheating a tool joint at a temperature of 275° C. or greater for a period of 0.01 hours to 100 hours.

3. The method of claim 1 , wherein said hardbanding alloy is cooled at a rate sufficient to produce alpha-iron and/or gamma-iron phases in the range of 0.05 μm to 50 μm in size.

4. The method of claim 1 , wherein said hardbanding alloy further comprises:

iron present in the range of 67.3 to 86.0 wt. %;

manganese present in the range of 0.10 to 0.27 wt. %;

niobium present in the range of 3.6 to 5.9 wt. %;

chromium present in the range of 6.4 to 22.9 wt. %;

boron present in the range of 2.5 to 4.2 wt. %;

carbon present in the range of 0.7 to 1.2 wt. %; and

silicon present in the range of 0.25 to 0.5 wt. %

wherein said alloy contains up to 2.0 wt. % of an elemental impurity.

5. The method of claim 1 , wherein said hardbanding alloy exhibits metal boride phases (M 2 B, wherein M is a transition metal) sized in the range of 0.5 μm to 5 μm.

6. The method of claim 1 , wherein said hardbanding alloy further comprises exhibits borocarbide phases containing iron, chromium and/or molybdenum transition metals.

7. The method of claim 1 , wherein said tool joint exhibits a hardness of less than 100 R B .

8. The method of claim 1 , wherein said tool joint comprises iron present at 95 atomic percent (at %) or more, carbon present at 0.2 atomic percent to 0.5 atomic percent, and manganese present in the range of 0.5 atomic percent to 1.5 atomic percent.

9. A drill pipe, comprising:

a tool joint having a circumference; and

a hardband disposed around at least a portion of said tool joint circumference, wherein said hardband includes a hardbanding alloy comprising iron and manganese present in the range of 67 to 87 weight percent (wt. %), niobium and chromium present in the range of 9 to 29 wt. %, and boron, carbon and silicon present in the range of 3 to 6.5 wt. %, wherein said hardbanding alloy exhibits a hardness of 45 Rc to 70 Rc and a wear rate in the range of 0.08 grams to 1.60 grams of mass loss after 6,000 cycles as measured using ASTM G65-04, Procedure A;

wherein said hardbanding alloy further comprises:

iron present in the range of 67.0 to 86.0 wt. %;

manganese present in the range of 0.05 to 0.3 wt. %;

niobium present in the range of 3.5 to 6.0 wt. %;

chromium present in the range of 6.0 to 23.0 wt. %;

boron present in the range of 2.5 to 4.5 wt. %;

carbon present in the range of 0.5 to 2 wt. %; and

silicon present in the range of 0.2 to 0.5 wt. % wherein said alloy contains up to 2.0 wt. % of an elemental impurity.

10. The drill pipe of claim 9 , wherein said hardbanding alloy exhibits alpha-iron and/or gamma-iron phases in the range of 0.05 μm to 50 μm in size as applied to said tool joint.

11. The drill pipe of claim 9 , wherein said hardbanding alloy further comprises:

iron present in the range of 67.0 to 86.0 wt. %;

manganese present in the range of 0.05 to 0.3 wt. %;

niobium present in the range of 3.5 to 6.0 wt. %;

chromium present in the range of 6.0 to 23.0 wt. %;

boron present in the range of 2.5 to 4.5 wt. %;

carbon present in the range of 0.5 to 2 wt. %; and

silicon present in the range of 0.2 to 0.5 wt. %

wherein said alloy contains up to 2.0 wt. % of an elemental impurity.

12. The drill pipe of claim 9 , wherein said hardbanding alloy further comprises:

iron present in the range of 67.3 wt. % to 86.0 wt. %;

manganese present in the range of 0.10 to 0.27 wt. %;

niobium present in the range of 3.6 to 5.9 wt. %;

chromium present in the range of 6.4 to 22.9 wt. %;

boron present in the range of 2.5 to 4.2 wt. %;

carbon present in the range of 0.7 to 1.2 wt. %; and

silicon present in the range of 0.25 to 0.5 wt. %

wherein said alloy contains up to 2.0 wt. % of an elemental impurity.

13. The drill pipe of claim 9 , wherein said hardbanding alloy exhibits an onset melting temperature of 1137° C. to 1202° C. as determined by differential scanning calorimetry or differential thermal analysis measured at 10° C. per minute.

14. The drill pipe of claim 9 , wherein said tool joint exhibits a hardness of less than 100 R B .

15. The drill pipe of claim 9 , wherein said hardbanding alloy exhibits metal boride phases (M 2 B, wherein M is a transition metal) sized in the range of 0.5 μm to 5 μm.

16. The drill pipe of claim 9 , wherein said hardbanding alloy further comprises exhibits borocarbide phases containing iron, chromium and/or molybdenum transition metals.

17. The drill pipe of claim 9 , wherein said drill pipe comprises iron present at 95 atomic percent (at %) or more, carbon present at 0.2 atomic percent to 0.5 atomic percent, and manganese present in the range of 0.5 atomic percent to 1.5 atomic percent.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 7, 2021
From: HORIZON TECHNOLOGY FINANCE CORPORATION
To: LINCOLN GLOBAL, INC.
Reel/Frame 056176/0440 →
SECURITY INTEREST Recorded Dec 3, 2018
From: THE NANOSTEEL COMPANY, INC.
To: HORIZON TECHNOLOGY FINANCE CORPORATION
Reel/Frame 047713/0163 →
SECURITY INTEREST Recorded Jun 11, 2015
From: THE NANOSTEEL COMPANY, INC.
To: HORIZON TECHNOLOGY FINANCE CORPORATION
Reel/Frame 035889/0122 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 7, 2010
From: BRANAGAN, DANIEL JAMES; MEACHAM, BRIAN E.; KIILUNEN, WILLIAM D.; MILLOWAY, JAMES N.; MERKLE, BRIAN D.
To: THE NANOSTEEL COMPANY, INC.
Reel/Frame 025461/0754 →