Hidden organic optoelectronic devices with a light scattering layer
View Patent ↗Disclosed is an optoelectronic device including at least one optoelectronic active region comprising at least a rear electrode and a front electrode between which an organic optoelectronic material is sandwiched, said rear electrode being reflective, and a cover layer arranged in front of said front electrode. The cover layer is formed from a material with light-scattering particles of a first material dispersed in a transparent matrix of at an least partly hydrolyzed silica sol. Due to the highly scattering properties of the cover layer, the device is essentially concealed behind the cover layer when not in its operative state.
1. An optoelectronic device, comprising
a first and a second optoelectronic active region arranged side by side and mutually spaced apart so as to form a interstitial region therebetween, said first and second optoelectronic active region comprising
a reflective rear electrode,
a front electrode, and
an organic optoelectronic material disposed therebetween, and
a cover layer superimposed on said first and second optoelectronic active regions facing said front electrode and covering at least the combined surface of said first and second optoelectronic active regions and said interstitial region, said cover layer comprising a plurality of light-scattering particles of a first material dispersed in a transparent matrix comprising at least partly hydrolyzed silica sol, wherein the refractive index of said particles of said first material is higher than the refractive index of the transparent matrix.
2. An optoelectronic device according to claim 1 , wherein said optoelectronic material is an electroluminescent material.
3. An optoelectronic device according to claim 1 , wherein said organic optoelectronic material is an organic photovoltaic material.
4. An optoelectronic device according to claim 1 , wherein said cover layer is superimposed on said at least one optoelectronic active region and covers at least the entire surface of said at least one optoelectronic active area.
5. An optoelectronic device according to claim 1 , wherein said transparent matrix is a silica sol-gel.
6. An optoelectronic device according to claim 1 , wherein said cover layer has a reflectivity in a range of 50 to 95%.
7. An optoelectronic device according to claim 1 , wherein the refractive index of said particles of said first material is at least 2.0.
8. An optoelectronic device according to claim 7 , wherein said first material is selected from the group consisting of TiO 2 anastase, TiO 2 rutile, ZrO 2 , Ta 2 O 5 , ZnSe, ZnS, and combinations of two or more thereof.
9. An optoelectronic device according to claim 1 , wherein said particles account for about 10 to about 80% by weight of said cover layer material.
10. An optoelectronic device according to claim 1 , wherein the mean particle size of said particles of the first material lies in a range of 100 to 1000 nm.
11. An optoelectronic device according to claim 1 , wherein said transparent matrix comprises a color dye.