Light-emitting device
View Patent ↗Disclosed is a light-emitting device including a light-emitting element emitting primary light, and a light converter absorbing a part of the primary light emitted from the light-emitting element and emitting secondary light having a longer wavelength than the primary light. The light converter contains a green light-emitting phosphor and a red light-emitting phosphor. The green light-emitting phosphor is composed of at least one phosphor selected from a divalent europium-activated oxynitride phosphor substantially represented by the following formula: Eu a Si b Al c O d N e and a divalent europium-activated silicate phosphor substantially represented by the following formula: 2 (Ba 1-f-g MI f Eu g )O.SiO 2 , while the red light-emitting phosphor is composed of at least one phosphor selected from tetravalent manganese-activated fluoro-tetravalent metalate phosphors substantially represented by the following formulae: MII 2 (MIII 1-h Mn h )F 6 and/or MIV(MIII 1-h Mn h )F 6 . Consequently, the light-emitting device has excellent color gamut (NTSC ratio).
1. A light-emitting device comprising a light-emitting element emitting primary light, and a light converter absorbing a part of the primary light emitted from the light-emitting element and emitting secondary light having a longer wavelength than the primary light, said light converter including a green light-emitting phosphor and a red light-emitting phosphor,
said green light-emitting phosphor including at least one selected from:
a divalent europium-activated oxynitride phosphor which is β-type SiAlON, substantially represented by a general formula (A): Eu a Si b Al c O d N e (in said general formula (A), 0.005≦a≦0.4, b+c=12, and d+e=16), and
a divalent europium-activated silicate phosphor substantially represented by a general formula (B): 2(Ba 1-f-g MI f Eu g )O.SiO 2 (in said general formula (B), MI represents at least one alkaline earth metal element selected from Mg, Ca and Sr, 0<f≦0.55, and 0.03≦g≦0.10),
said red light-emitting phosphor including at least one selected from:
a tetravalent manganese-activated fluoro-tetravalent metalate phosphor substantially represented by a general formula (C): MII 2 (MIII 1-h Mn h )F 6 (in said general formula (C), MII represents at least one alkaline metal element selected from Li, Na, K, Rb and Cs, MIII represents at least one tetravalent metal element selected from Ge, Si, Sn, Ti and Zr, and 0.001≦h≦0.1), and
a tetravalent manganese-activated fluoro-tetravalent metalate phosphor substantially represented by a general formula (D): MIV(MIII 1-h Mn h )F 6 (in said general formula (D), MIV represents at least one alkaline earth metal element selected from Mg, Ca, Sr, Ba and Zn, MIII represents at least one tetravalent metal element selected from Ge, Si, Sn, Ti and Zr, and 0.001≦h≦0.1).
2. The light-emitting device according to claim 1 , wherein MII is K and MIII is Ti.
3. The light-emitting device according to claim 1 , wherein 0.005≦h≦0.05.
4. The light-emitting device according to claim 1 , wherein MI is Sr.
5. The light-emitting device according to claim 1 , wherein the light-emitting element is a gallium nitride-based semiconductor emitting primary light having a peak wavelength of 430 to 480 nm.