IP Library Granted Patent US 8,188,212
Granted Patent B2
US 8,188,212 · App. 12/920,989 · Granted May 29, 2012

Method of enhancing conductivity of conductive polymer product

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Quick Facts
Patent No.
US 8,188,212
App. No.
12/920,989
Granted
May 29, 2012
Kind
B2
Abstract

A method of enhancing the conductivity of various conductive polymer products, such as a conductive polymer product obtained by polymerizing 3,4-ethylenedioxythiophene in an aqueous solution of polystyrenesulfonic acid. The method of enhancing the conductivity of a conductive polymer product includes placing a conductive polymer product, water, an organic solvent compatible with the conductive polymer product, and carbon dioxide gas in a pressure vessel; and applying heat and pressure to an interior of the pressure vessel to bring the carbon dioxide into a supercritical state.

Claims (8)

1. A method of enhancing an electrical conductivity of an electrically conductive polymer product comprising: placing an electrically conductive polymer product, water, an organic solvent compatible with the electrically conductive polymer product, and carbon dioxide gas in a pressure vessel; and applying heat and pressure to an interior of the pressure vessel to bring the carbon dioxide into a supercritical state.

2. The method of enhancing a conductivity of a conductive polymer product according to claim 1 , wherein the conductive polymer product is a product obtained by polymerizing 3,4-ethylenedioxythiophene in an aqueous solution of polystyrenesulfonic acid and/or polyaniline.

3. The method of enhancing a conductivity of a conductive polymer product according to claim 1 , wherein the organic solvent is at least one selected from the group consisting of dimethyl sulfoxide, ethylene glycol, N-methylpyrrolidone and N,N-dimethylformamide.

4. The method of enhancing a conductivity of a conductive polymer product according to claim 1 , wherein the interior of the pressure vessel is pressurized to a pressure from 7 to 25 MPa and heated to a temperature from 85 to 110° C., and the pressure and the temperature are maintained for 0.5 to 4 hours.

5. The method of enhancing a conductivity of a conductive polymer product according to claim 2 , wherein the organic solvent is at least one selected from the group consisting of dimethyl sulfoxide, ethylene glycol, N-methylpyrrolidone and N,N-dimethylformamide.

6. The method of enhancing a conductivity of a conductive polymer product according to claim 2 , wherein the interior of the pressure vessel is pressurized to a pressure from 7 to 25 MPa and heated to a temperature from 85 to 110° C., and the pressure and the temperature are maintained for 0.5 to 4 hours.

7. The method of enhancing a conductivity of a conductive polymer product according to claim 3 , wherein the interior of the pressure vessel is pressurized to a pressure from 7 to 25 MPa and heated to a temperature from 85 to 110° C., and the pressure and the temperature are maintained for 0.5 to 4 hours.

8. The method of enhancing a conductivity of a conductive polymer product according to claim 5 , wherein the interior of the pressure vessel is pressurized to a pressure from 7 to 25 MPa and heated to a temperature from 85 to 110° C., and the pressure and the temperature are maintained for 0.5 to 4 hours.

Assignments (2)
CHANGE OF ASSIGNEE ADDRESS Recorded May 8, 2013
From: NIKKISO CO., LTD.
To: NIKKISO CO., LTD.
Reel/Frame 030378/0791 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 24, 2010
From: OSADA, FUMIO; FUKUZAWA, SHINYA; NAGAI, KAZUYO
To: NIKKISO CO., LTD.
Reel/Frame 025418/0788 →