Tough and rigid mixtures of alpha-methylstyrene-acrylnitrile copolymers and of block copolymers
Composition comprising at least one copolymer A composed of at least one alkylated styrene, of acrylonitrile, and, if appropriate, of at least one further monomer, at least one block copolymer B which has at least one block forming a hard phase and composed of at least one vinylaromatic monomer and has at least one block forming a soft phase and composed of at least one vinylaromatic monomer and of at least one diene, and at least one further copolymer C, and, if appropriate, one polymer D, where the copolymer C is at least one triblock copolymer composed of a first block composed of at least one vinylaromatic monomer, of a second block composed of at least one diene, and of a third block composed of at least one methyl methacrylate monomer, or comprising at least 50% by weight of methyl methacrylate, and the polymer D is at least one styrene polymer selected from glass-clear and impact-resistant polystyrene. The present invention moreover relates to a process for the preparation of the inventive compositions, to the use of the inventive compositions for the production of moldings, of foils, of fibers, or of foams, to moldings, foils, fibers, or foams comprising the inventive composition, and also to the use of the inventive composition as packaging for electronic components, such as integrated circuits (microchips) (“electronic packing”), for applications in chemical engineering, in household products, in bathroom items, e.g. toothbrush tumblers, cosmetics holders, etc., as housings, as tubes, as profiles, for medical items or medical devices, and in toys.
1. A composition comprising:
A at least one copolymer A composed of
a1) at least one alkylated styrene as component A1;
a2) acrylonitrile as component A2; and
a3) optionally, at least one further monomer as component A3;
B at least one block copolymer B composed of
b1) at least one block B1 forming a hard phase and composed of at least 15 one vinylaromatic monomer, and
b2) at least one block B2 forming a soft phase and composed of at least one vinylaromatic monomer and of at least one diene;
C at least one triblock copolymer C composed of
c1) a first block C1 composed of at least one vinylaromatic monomer,
c2) a second block C2, composed of at least one diene, and
c3) a third block C3 composed of at least one methyl methacrylate monomer or comprising at least 50% by weight of methyl methacrylate; and
D optionally, at least one styrene polymer selected from glass-clear polystyrene and impact-resistant polystyrene.
2. The composition according to claim 1 comprising:
A from 30 to 85% by weight of the copolymer A;
B from 5 to 69.9% by weight of the block copolymer B; and
C from 0.1 to 45% by weight of the copolymer C;
D from 0 to 50% by weight of component D,
where the entirety of components A, B, C, and, optionally, D gives 100% by weight.
3. The composition according to claim 1 , wherein the copolymer A comprises:
a1) from 60 to 90% by weight of at least one alkylated styrene as component A1,
a2) from 10 to 40% by weight of acrylonitrile as component A2,
a3) from 0 to 30% by weight of at least one further monomer as component A3, where the entirety of components A1, A2, and A3 gives 100% by weight.
4. The composition according to claim 1 , wherein the monomer constitution of the block copolymer B is from 15 to 65% by weight of diene, and from 35 to 85% by weight of vinylaromatic monomer, where the entirety of diene and vinylaromatic monomer gives 100% by weight.
5. The composition according to claim 1 , wherein the block copolymer B is composed of at least two blocks B1 forming a hard phase and of at least one block B2 situated between these and forming a soft phase.
6. The composition according to claim 1 , wherein, in the block copolymer B, the relative proportion of 1,2-linkages of the diene units of the block B2 (polydiene) forming the soft phase, based on the entirety of 1,2- and 1,4-cis/trans linkages, is ≦20%.
7. The composition according to claim 1 , wherein, in the block copolymer B, the block B1 is composed of styrene and the block B2 is composed of butadiene and styrene.
8. The composition according to claim 1 , wherein the triblock copolymer C is composed of
c1) from 10 to 88% by weight of the first block C1,
c2) from 2 to 80% by weight of the second block C2, and
c3) from 10 to 88% by weight of the third block C3,
where the entirety of components C1, C2, and C3 gives 100% by weight.
9. The composition according to claim 1 , wherein the triblock copolymer C is composed of a first block C1 composed of at least one vinylaromatic monomer selected from styrene and α-methylstyrene, of a second block C2 composed of at least one diene selected from butadiene and isoprene, and of a third block C3 composed of at least 60% by weight of PMMA.
10. The composition according to claim 1 , wherein component D is glass-clear polystyrene.
11. The composition according to claim 1 , wherein rubbery styrene block copolymers are comprised as additional component E.
12. A process for the preparation of compositions according to claim 1 , which comprises mixing components A, B, C, optionally D, and, optionally, E, and, optionally further additives.
13. A molding, a foil, a fiber, or a foam comprising a composition according to any of claim 1 .
14. Packaging for electronic components, packaging for applications in chemical engineering, household products, bathroom items, housings, tubes, profiles, medical items or medical devices, and toys comprising the composition according to claim 1 .