Epoxy resin composition, resin sheet, prepreg, multilayer printed wiring board and semiconductor device
An object of the present invention is to provide an epoxy resin composition that provides, when used for an insulation layer of a multilayer printed wiring board, a multilayer printed wiring board which is excellent in plating adhesion, heat resistance and moisture resistance reliability and capable of forming fine wiring. Another object of the present invention is to provide a resin sheet, a prepreg, a method for producing a multilayer printed wiring board, a multilayer printed wiring board and a semiconductor device. These objects are achieved by an epoxy resin composition comprising (A) an epoxy resin, (B) a phenoxy resin having a specific bisphenol acetophenone structure and (C) a curing agent, wherein the content of the phenoxy resin (B) is 10 to 30% by weight of the total solid content of the resin composition.
1. An epoxy resin composition comprising:
(A) an epoxy resin, (B) a phenoxy resin having a bisphenol acetophenone structure represented by the following formula (1) and a weight average molecular weight of 1.0×10 4 or more, and (C) a curing agent, wherein the content of the phenoxy resin (B) is 10 to 30% by weight of the total solid content of the resin composition:
wherein R 1 may be the same or different and are each a group selected from a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, or halogen; R 2 is a group selected from a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, or halogen; R 3 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms; and m is an integer of 0 to 5.
2. The epoxy resin composition according to claim 1 , further comprising (D) an inorganic filler.
3. The epoxy resin composition according to claim 2 , wherein the inorganic filler (D) has a particle diameter of 0.2 μm to 5 μm.
4. The epoxy resin composition according to claim 2 , wherein the inorganic filler (D) comprises silica and/or aluminum hydroxide.
5. The epoxy resin composition according to claim 2 , wherein, in the total solid content of the resin composition, the content of the epoxy resin (A) is 5 to 60% by weight, the content of the phenoxy resin (B) is 10 to 30% by weight, the content of the curing agent (C) is 0.01 to 15% by weight, and the content of the inorganic filler (D) is 10 to 75% by weight.
6. The epoxy resin composition according to claim 1 , further comprising (E) a cyanate resin and/or prepolymer thereof.
7. The epoxy resin composition according to claim 1 , wherein the epoxy resin (A) is a novolac-type epoxy resin having a condensed ring aromatic hydrocarbon structure.
8. The epoxy resin composition according to claim 1 , further comprising (D) an inorganic filler and (E) a cyanate resin and/or prepolymer thereof, wherein the epoxy resin (A) is (A1) a novolac-type epoxy resin having a condensed ring aromatic hydrocarbon structure.
9. The epoxy resin composition according to claim 8 , wherein, in the total solid content of the resin composition, the content of the novolac-type epoxy resin (A1) having a condensed ring aromatic hydrocarbon structure is 10 to 60% by weight; the content of the phenoxy resin (B) is 10 to 30% by weight, the content of the curing agent (C) is 0.01 to 5% by weight; the content of the inorganic filler (D) is 10 to 70% by weight; and the content of the cyanate resin and/or prepolymer thereof (E) is 5 to 60% by weight.
10. The epoxy resin composition according to claim 1 , comprising an imidazole compound as the curing agent (C).
11. The epoxy resin composition according to claim 1 , further comprising a poly(meth)acrylic acid ester having a weight average molecular weight of 1.0×10 3 to 1.0×10 5 .
12. The epoxy resin composition according to claim 1 , wherein the phenoxy resin (B) having a bisphenol acetophenone structure represented by the above formula (1) further has a biphenyl structure.
13. The epoxy resin composition according to claim 1 , wherein the phenoxy resin (B) having a bisphenol acetophenone structure represented by the above formula (1) has a glass transition temperature of 120° C. or more.
14. The epoxy resin composition according to any of claim 1 , wherein, in the total solid content of the resin composition, the content of the epoxy resin (A) is 5 to 80% by weight, the content of the phenoxy resin (B) is 10 to 30% by weight, and the content of the curing agent (C) is 0.01 to 25% by weight.
15. A resin sheet comprising a substrate and a resin layer comprising the epoxy resin composition defined in claim 1 , wherein the resin layer is formed on the substrate.
16. A method for producing a multilayer printed wiring board comprising the steps of successively laminating the resin sheets defined in claim 15 on a surface of an inner layer circuit board, on which an inner layer circuit pattern is formed, and forming a conductor circuit layer by a semi-additive process.
17. A multilayer printed wiring board formed by laminating the resin sheets defined in claim 15 one or both surfaces of an inner layer circuit board and hot-pressing the same.
18. A semiconductor device formed by mounting a semiconductor element on the multilayer printed wiring board defined in claim 17 .
19. A prepreg comprising a glass fiber substrate and the epoxy resin composition defined in claim 1 , wherein the glass fiber substrate is impregnated with the epoxy resin composition.
20. A multilayer printed wiring board formed by laminating the prepregs defined in claim 19 on one or both surfaces of an inner layer circuit board and hot-pressing the same.