Energy ray-curable ink composition
View Patent ↗The present invention provides an energy ray-curable ink composition excellent in the continuous discharge property, and excellent in curability and adherability. The present invention relates to an energy ray-curable ink composition which contains a coloring agent, contains only a monofunctional monomer having an acrylic equivalent of 300 or less, and having one ethylenic double bond in one molecule, and a polyfunctional monomer having an acrylic equivalent of 150 or less, and having two or more ethylenic double bonds in one molecule as a polymerizable compound, contains an α-aminoalkylphenone compound and a thioxanthone compound as a photopolymerization initiator, and contains a silicone compound having a polydimethylsiloxane structure as a surface conditioner.
1. An energy ray-curable ink composition comprising a coloring agent, a polymerizable compound, a photopolymerization initiator and a surface conditioner,
wherein the polymerizable compound consists only of a monofunctional monomer having an acrylic equivalent of 300 or less, and having one ethylenic double bond in one molecule, and a polyfunctional monomer having an acrylic equivalent of 150 or less, and having two or more ethylenic double bonds in one molecule,
the photopolymerization initiator contains an α-aminoalkylphenone compound and a thioxanthone compound,
the surface conditioner contains a silicone compound having a polydimethylsiloxane structure,
the ink composition contains 10 to 20% by mass of the monofunctional monomer, 10 to 75% by mass of the polyfunctional monomer, 2 to 20% by mass of the α-aminoalkylphenone compound, 0.1 to 10% by mass of the thioxanthone compound, and 2.5% by mass or less of the silicone compound in the total amount of the ink composition, and
a mass ratio of the content of the monofunctional monomer and the content of the polyfunctional monomer (polyfunctional monomer/monofunctional monomer) is 3 to 8.
2. The energy ray-curable ink composition according to claim 1 , wherein the polymerizable compound contains a polyfunctional monomer having an acrylic equivalent of 150 or less, and having three or more ethylenic double bonds in one molecule, as the polyfunctional monomer, and
the content of the polyfunctional monomer having an acrylic equivalent of 150 or less, and having three or more ethylenic double bonds in one molecule is 10 to 50% by mass in the total amount of the ink composition.
3. The energy ray-curable ink composition according to claim 1 , wherein the polymerizable compound contains a polyfunctional monomer having an acrylic equivalent of 150 or less, and having two ethylenic double bonds in one molecule, and a polyfunctional monomer having an acrylic equivalent of 150 or less, and having three or more ethylenic double bonds in one molecule, as the polyfunctinal monomer, and
the content of the polyfunctional monomer having an acrylic equivalent of 150 or less, and having two ethylenic double bonds in one molecule is 10 to 60% by mass, and the content of the polyfunctional monomer having an acrylic equivalent of 150 or less, and having three or more ethylenic double bonds in one molecule is 10 to 50% by mass, and the total content of these polyfunctional monomers is 20 to 75% by mass, in the total amount of the ink composition.