Method for forming a protective coating containing aluminium and zirconium on a metal part
View Patent ↗A method for forming a protective coating containing aluminum and zirconium on the surface of a metal part. The part is put into contact with a cement made of aluminum alloy, at a treatment temperature, with an atmosphere containing an active gas which reacts with the cement to form a gaseous aluminum halide, which decomposes in contact with the part depositing metallic aluminum thereon, the active gas containing ZrOCl 2 that decomposes in contact with the part depositing Zr metal thereon, and being formed by vaporizing granules of ZrOCl 2 that are solid at ambient temperature. The part, the cement, and ZrOCl 2 granules are then progressively heated together in a chamber from ambient temperature to the treatment temperature with a plateau at 400° C.±200° C.
1. A method for forming a protective coating containing aluminium and zirconium on a surface of a metal part, the method comprising:
placing the part, a cement made of aluminium alloy, and granules of ZrOCl 2 in a chamber;
applying a treatment temperature to the chamber to form an atmosphere comprising an active gas which reacts with the cement to form a gaseous aluminium halide, which decomposes in contact with the part depositing metallic aluminium thereon, the active gas comprising ZrOCl 2 that decomposes in contact with the part depositing Zr metal thereon, and being formed by vaporizing the granules of ZrOCl 2 that are solid at ambient temperature,
wherein during the treatment, the part, the cement, and the ZrOCl 2 granules are progressively heated together, in the chamber, from ambient temperature to a temperature with a plateau at 400° C.±200° C., the heating plateau lasting 5 to 30 minutes during which the vaporized granules of ZrOCl 2 are distributed in the atmosphere, and
wherein a concentration of Zr deposited on the metal part is controlled by adjustment of a quantity of the ZrOCl 2 relative to the donor cement placed in the deposition chamber, adjustment of the atmosphere of the chamber, and at least one parameter selected from the group consisting of adjustment of the temperature of the plateau and adjustment of a rate of heating the chamber from the plateau to the aluminization treatment temperature.
2. The method according to claim 1 , wherein the plateau is at a temperature of 500° C.±100° C.
3. The method according to claim 1 , wherein heating is carried out progressively at a temperature rise rate of between 4° C. and 20° C. per minute.
4. The method according to claim 2 , wherein heating is carried out progressively at a temperature rise rate of between 4° C. and 20° C. per minute.
5. The method according to claim 1 , wherein the active gas additionally contains at least one ammonium halide.
6. The method according to claim 5 , wherein the ratio of ZrOCl 2 to ammonium halide is greater than 1/1 and is less than 20/1.
7. The method according to claim 1 , wherein the part contains at least nickel which combines with aluminium to form an intermetallic compound NiAl in the coating in which aluminium is partially substituted by zirconium.
8. The method according to claim 7 , wherein the part is a superalloy based on nickel or cobalt.
9. The method according to claim 1 , wherein the active gas contains at least one halogen.
10. The method according to claim 1 , wherein the aluminium alloy contains chromium.
11. The method according to claim 1 , wherein the atmosphere is formed, apart from the active gas, of an inert or reducing gas.
12. The method according to claim 11 , wherein the inert gas is argon and the reducing gas is hydrogen.
13. The method according to claim 1 , wherein the treatment temperature lies between 950 and 1200° C. or is approximately 1080° C.
14. The method according to claim 1 , wherein the concentration of Zr is less than 1200 ppm.