Ferromagnetic amorphous alloy ribbon with reduced surface defects and application thereof
View Patent ↗A ferromagnetic amorphous alloy ribbon, a method of fabricating a ribbon and a wound transformer core are provided. The ribbon includes an alloy of Fe a Si b B c C d where 80.5≦a≦83 at. %, 0.5≦b≦6 at. %, 12≦c≦16.5 at. %, 0.01≦d≦1 at. % with a+b+c+d=100, and is cast from a molten state of the alloy, having a-surface tension of greater than or equal to 1.1 N/mi,. A defect length along a direction of the ribbon's length is between 5 mm and 200 mm, a defect depth less than 0.4 ×t μm and a defect occurrence frequency less than 0.05 ×w times within 1.5 m of ribbon length, where t is the ribbon thickness and w is the ribbon width in mm. The ribbon has a saturation magnetic induction exceeding 1.60 T and a magnetic core loss of less than 0.14 W/kg when measured at 60 Hz and at 1.3 T induction level in an annealed straight strip form, and a core magnetic loss of less than 0.3 W/kg and an exciting power of less than 0.4 VA/kg in an annealed wound transformer core form and is suitable for use in transformer cores, rotational machines, electrical chokes, magnetic sensors and pulse power devices.
1. A ferromagnetic amorphous alloy ribbon comprising:
an alloy having a composition represented by Fe a Si b B c C d where 80.5≦a≦83 at. %, 0.5≦b≦6 at. %, 12≦c≦16.5 at. %, 0.01≦d≦1 at. % with a+b+c+d=100 and incidental impurities;
the ribbon having been cast from a molten state of the alloy, with a molten alloy surface tension of greater than or equal to 1.1 N/m,
the ribbon having a ribbon length, a ribbon thickness, a ribbon width, and a ribbon surface facing a casting atmosphere side,
the ribbon having ribbon surface defects on the ribbon surface facing the casting atmosphere side,
the ribbon surface defects being measured in terms of a defect length, a defect depth, and defect occurrence frequency,
the defect length along a direction of the ribbon's length being between 5 mm and 200 mm, the defect depth being less than 0.4 33 t μm and the defect occurrence frequency being greater than zero and less than 0.05 ×w times per 1.5 m of ribbon length, where t is the ribbon thickness and w is the ribbon width in mm, and
the ribbon having a saturation magnetic induction exceeding 1.60 T and exhibiting a magnetic core loss of less than 0.14 W/kg when measured at 60 Hz and at a 1.3 T induction level in an annealed straight strip form, and a core magnetic loss of less than 0.3 W/kg and an exciting power of less than 0.4 VA/kg when measured at 60 Hz and at a 1.3 T induction level in an annealed wound transformer core form.
2. The ferromagnetic amorphous alloy ribbon of claim 1 , wherein the Si content b and the B content c are related to the Fe content a and the C content d according to relations of b≧166.5×(100−d)/100−2a and c≦a−66.5 ×(100−d)/100.
3. The ferromagnetic amorphous alloy ribbon of claim 1 , further comprising a content of Cu being between 0.005 wt. % and 0.20 wt. %.
4. The ferromagnetic amorphous alloy ribbon of claim 1 , further comprising a content of Mn being between 0.05 wt. % and 0.30 wt. %, and a content of Cr being between 0.01 wt. % and 0.2 wt. %.
5. The ferromagnetic amorphous alloy ribbon of claim 1 , wherein up to 20 at. % of Fe is optionally replaced by Co, and up to 10 at. % Fe is optionally replaced by Ni.
6. The ferromagnetic amorphous alloy ribbon of claim 1 , wherein the ribbon has been cast from a molten state of the alloy at temperatures between 1,250° C. and 1,400° C.
7. The ferromagnetic amorphous alloy ribbon of claim 1 , wherein the ribbon has been cast in an environmental atmosphere containing less than 5 vol. % oxygen gas at the molten alloy-ribbon interface.
8. The ferromagnetic amorphous alloy ribbon of claim 1 , wherein the ribbon comprises a portion 100 mm in width and 1.5 m in length, the portion having a defect occurrence count of less than 5.
9. A wound transformer core, comprising:
a ferromagnetic amorphous alloy ribbon, the ribbon being annealed in magnetic fields applied along the direction of the ribbon's length, and the core exhibiting magnetic core loss of less than 0.3 W/kg and exciting power of less than 0.4 VA/kg when measured at 60 Hz and 1.3 T induction, the ribbon being cast and configured to control a defect in the ribbon from an alloy having a chemical composition represented by Fe a Si b B c C d where 81≦a<82.5 at. %, 2.5<b<4.5 at. %, 12≦c≦16 at. %, 0.01≦d≦1 at. % with a+b+c+d=100 and satisfying the relations of b≧166.5×(100−d)/100−2a and c≦a−66.5×(100−d)/100,
the ribbon haying been cast from a molten state of the alloy, with a molten alloy surface tension of greater than or equal to 1.1 N/m,
the alloy having a trace element selected from at least one of Cu, Mn, and Cr,
the Cu content is at 0.005-0.20 wt. %, the Mn content is at 0.05-0.30 wt. % and the Cr content is at 0.01-0.2 wt. %,
the alloy having less than 20 at. % Fe optionally replaced by Co, and less than 10 at. % Fe optionally replaced by Ni,
the ribbon haying ribbon surface defects on the ribbon surface facing the casting atmosphere side,
the ribbon surface defects being measured in terms of a defect length, a defect depth, and defect occurrence frequency, and
the ribbon having surface defects that are controlled during formation on a surface of the ribbon, the defect length along a direction of the ribbon's length being between 5 mm and 200 mm, the defect depth being less than 0.4 ×t μm, the defect occurrence frequency being greater than zero and less than 0.05 ×w times per 1.5 m of ribbon length, where t is the ribbon thickness and w is the ribbon width in mm, by controlling a molten metal surface tension during a casting of the ribbon from a molten state of the alloy.
10. The wound transformer core of claim 9 , where the ribbon has been annealed in magnetic fields applied along the direction of the ribbon's length, and the core exhibiting magnetic core loss of less than 0.25 W/kg and exciting power of less than 0.35 VA/kg when measured at 60 Hz and 1.3 induction.
11. The wound transformer core of claim 10 , wherein the ribbon has been annealed in a temperature range between 300° C. and 335° C.
12. The wound transformer core of claim 10 , being operated up to an induction level of 1.5 T at room temperature.
13. The wound transformer core of claim 9 , having a toroidal shape or semi-toroidal shape.
14. The wound transformer core of claim 9 , having step-lap joints.
15. The wound transformer core of claim 9 , having over-lap joints.
16. A method of fabricating a ferromagnetic amorphous alloy ribbon, the method comprising:
selecting an alloy having a composition represented by Fe a Si b B c C d where 80.5≦a≦83 at. %, 0.5≦b≦6 at. %, 12≦c≦16.5 at. %, 0.01≦d≦1 at. % with a+b+c+d=100 and incidental impurities;
casting the ribbon from a molten state of the alloy in an environmental atmosphere containing less than 5 vol. % oxygen gas at the molten alloy-ribbon interface, the casting performed with a molten alloy surface tension greater than or equal to 1.1 N/m; and
obtaining the ribbon having a ribbon length, a ribbon thickness, and a ribbon width,
wherein the ribbon has ribbon surface defects that are controlled during formation by controlling a surface tension of the alloy in a molten state during the casting and are measured in terms of a defect length, a defect depth, and defect occurrence frequency,
wherein the defect length along a direction of the ribbon's length is between 5 mm and 200 mm, the defect depth is less than 0.4 ×t μm and the defect occurrence frequency is greater than zero and less than 0.05 ×w times per 1.5 m of ribbon length, where t is the ribbon thickness and w is the ribbon width in mm, and
wherein the ribbon has a saturation magnetic induction exceeding 1.60 T and exhibiting a magnetic core loss of less than 0.14 W/kg when measured at 60 Hz and at a 1.3 T induction level in an annealed straight strip form, and a core magnetic loss of less than 0.3 W/kg and an exciting power of less than 0.4 VA/kg when measured at 60 Hz and at a 1.3 T induction level in an annealed wound transformer core form.
17. The method of claim 16 , wherein the Si content b and the B content c are related to the Fe content a and the C content d according to relations of b ≧166.5×(100−d)/100−2a and c≦a−66.5 ×(100−d)/100.
18. The method of claim 16 , wherein the alloy further comprises a content of Cu being between 0.005 wt. % and 0.20 wt. %.
19. The method of claim 16 , wherein the alloy further comprises a content of Mn being at 0.05-0.30 wt. % and a content of Cr being at 0.01-0.2 wt. %.
20. The method of claim 16 , wherein up to 20 at. % of Fe is optionally replaced by Co, and up to 10 at. % Fe is optionally replaced by Ni.
21. The method of claim 16 , wherein the ribbon is cast from a molten state of the alloy at temperatures between 1,250° C. and 1,400° C.
22. The method of claim 16 , wherein the ribbon obtained comprises a portion 100 mm in width and 1.5 m in length, the portion having a defect occurrence count of less than 5.