Silicon titanium oxide coating, coated article including silicon titanium oxide coating, and method of making the same
View Patent ↗Certain example embodiments relate to a layer of or including Ti 1-x Si x O y and/or a method of making the same. In certain example embodiments, the Ti 1-x Si x O y -based layer may be substoichiometric with respect to oxygen. In certain example embodiments of this invention, the layer may include Ti 1-x Si x O y where x is from about 0.05 to 0.95 (more preferably from about 0.1 to 0.9, and even more preferably from about 0.2 to 0.8, and possibly from about 0.5 to 0.8) and y is from about 0.2 to 2 (more preferably from about 1 to 2, and even more preferably from about 1.5 to 2, and possibly from about 1.9 to 2). The layer may have an index of refraction of from about 1.6 to 1.9. The layer may also be used with a transparent conductive oxide in a transparent conductive coating.
1. A method for making a coated article, the method comprising:
sputter-depositing a first medium index layer comprising Ti 1-x Si x O y on a glass substrate, where x is from 0.05 to 0.95 and y is from 0.2 to 2, wherein said medium index layer comprising Ti 1-x Si x O y , is sputter-deposited by a target comprising Si and Ti, wherein the ratio of Si to Ti in the target is from 3:1 to 2:1,
forming a high index layer comprising an oxide of titanium over and contacting the medium index layer; and
forming a low index layer comprising an oxide of silicon over and contacting the high index layer,
wherein the medium index layer has an index of refraction of from 1.6 to 1.9, and a thickness of from about 30 to 70 nm,
wherein the high index layer has an index of refraction of from 2.0 to 2.4, and a thickness of from 75 to 125 nm, wherein the high index layer is significantly thicker than the medium index layer, and
wherein the low index layer has an index of refraction of from 1.4 to 1.6, and a thickness of from 65 to 115 nm, and wherein the high index layer is thicker than the low index layer.
2. The method of claim 1 , where x is from about 0.1 to 0.9, and y is from about 1 to 2.
3. The method of claim 1 , wherein x is from about 0.2 to 0.8, and y is from about 1.5 to 2.
4. The method of claim 1 , wherein the medium index layer has a thickness of from about 40 to 60 nm, the high index layer has a thickness of from about 80 to 110 nm, and the low index layer has a thickness of from about 70 to 110 nm.
5. The method of claim 1 , wherein the target material further comprises Al.
6. The method of claim 5 , wherein the medium index layer further comprises Al.
7. The method of claim 1 , wherein the target material further comprises one or more of Zr, V, Hf, Nb, Ce, Sb, Bi, Zn, Sn and Mg.
8. The method of claim 1 , wherein the ratio of Si to Ti is about 7:3.
9. The method of claim 8 , wherein the refractive index of the medium index layer is from about 1.75 to 1.8.
10. The method of claim 1 , where x is greater than about 0.5, and y is less than or equal to about 2; and wherein the high index layer consists essentially of titanium oxide and is over and contacting the layer comprising Ti 1-x Si x O y ; and wherein the low index layer consists essentially of silicon oxide over and is over and contacting the layer consisting essentially of titanium oxide; and wherein the three layers form an antireflective coating on the glass substrate.
11. The method of claim 1 , wherein the layer comprising Ti 1-x Si x O y is formed directly on and contacting the glass substrate.