Gadolinium oxide-doped zirconium oxide overcoat and/or method of making the same
View Patent ↗Certain example embodiments relate to a coated article including at least one infrared (IR) reflecting layer in a low-E coating. In certain examples, at least one layer of the coating is of or includes zirconium oxide (e.g., ZrO 2 ) doped with gadolinium and/or gadolinium oxide (e.g., Gd 2 O 3 or other suitable stoichiometry). Providing a layer including Gd-doped zirconium oxide as the uppermost or overcoat layer of the coated article (e.g., over a silicon nitride based layer) advantageously results in improved durability, and chemical and heat stability in certain example embodiments. Coated articles herein may be used in the context of insulating glass (IG) window units, vehicle windows, or in other suitable applications such as monolithic window applications, laminated windows, and/or the like.
1. A coated article, comprising:
a substrate supporting a multi-layer coating on a major surface thereof, the coating comprising a low-E coating and a layer comprising gadolinium (Gd)-doped zirconium oxide over the low-E coating,
wherein the low-E coating comprises, moving away from the substrate:
a first dielectric layer,
an IR reflecting layer comprising silver, and
a second dielectric layer, and
wherein the layer comprising Gd-doped zirconium oxide includes from about 1 to 20% Gd.
2. The coated article of claim 1 , wherein the layer comprising Gd-doped zirconium oxide is an outermost layer of the coating.
3. The coated article of claim 1 , wherein the coated article is heat-treated.
4. The coated article of claim 1 , wherein the layer comprising Gd-doped zirconium oxide comprises from about 5 to 17% Gd.
5. The coated article of claim 1 , wherein the layer comprising Gd-doped zirconium oxide comprises from about 5 to 15% Gd.
6. The coated article of claim 1 , wherein the coated article is heat treated together with the coating, and the coating has a net compressive residual stress following heat treatment.
7. The coated article of claim 6 , wherein the coating has a reduced tensile stress compared to a coating lacking Gd in the layer comprising Gd-doped zirconium oxide.
8. The coated article of claim 1 , wherein the layer comprising Gd-doped zirconium oxide has a thickness of from about 1 to 15 nm.
9. The coated article of claim 1 , wherein the layer comprising Gd-doped zirconium oxide has a thickness of from about 2.5 to 10 nm.
10. The coated article of claim 1 , wherein the layer comprising Gd-doped zirconium oxide has a thickness of from about 3 to 7 nm.
11. A coated article, comprising:
a functional coating provided on a major surface of a glass substrate;
an overcoat layer provided over the functional coating and/or as the outermost layer of the functional coating, wherein the overcoat layer comprises gadolinium (Gd)-doped zirconium oxide.
12. The coated article of claim 11 , wherein the coated article is heat treated.
13. The coated article of claim 11 , wherein the overcoat layer has a thickness of from about 1 to 15 nm.
14. The coated article of claim 11 , wherein the overcoat layer comprises from about 1 to 20% Gd.
15. The coated article of claim 14 , wherein the functional coating comprises at least one IR reflecting layer including nickel and/or a nickel alloy.
16. The coated article of claim 14 , wherein the coated article is heat treated together with the coating, and the coating has a net compressive residual stress following heat treatment.
17. The coated article of claim 16 , wherein the coating has a reduced tensile stress compared to a coating lacking Gd in the layer comprising Gd-doped zirconium oxide.
18. A method of making a coated article including a coating supported by a glass substrate, the method comprising:
disposing a first dielectric layer, directly or indirectly, on the glass substrate;
disposing an IR reflecting layer over the first dielectric layer;
disposing a second dielectric layer over the IR reflecting layer;
sputter-depositing an overcoat layer comprising gadolinium (Gd)-doped zirconium oxide over the second dielectric layer, the overcoat layer being the outermost layer of the coating; and
heat-treating the glass substrate with the coating thereon,
wherein the overcoat layer comprises from about 1 to 20% Gd.
19. The method of claim 18 , wherein after heat treating, the coating has a net compressive residual stress.
20. The method of claim 19 , wherein after heat treating, the coating has a reduced tensile stress compared to a coating lacking Gd in the overcoat layer.
21. The method of claim 20 , wherein the overcoat layer is sputter-deposited from a metallic target.
22. The method of claim 21 , wherein the layer comprising gadolinium (Gd)-doped zirconium oxide is sputter-deposited from a metallic target in the presence of oxygen.
23. The method of claim 22 , wherein an amount of oxygen present during deposition is (in mL O 2 per kW Zr target power) from about 1 to 6 mL/kW.
24. The method of claim 23 , wherein the amount of oxygen present during deposition is (in mL O 2 per kW Zr target power) from about 2 to 4.2 mL/kW.
25. The method of claim 22 , wherein the overcoat layer goes through fewer phase changes during the heat treating compared to an overcoat layer lacking Gd.
26. A method of making a coated article including a coating supported by a glass substrate, the method comprising:
providing the glass substrate;
disposing a functional layer, directly or indirectly, on the glass substrate, the functional layer being an IR reflecting layer; and
sputter-depositing an overcoat layer comprising gadolinium (Gd)-doped zirconium oxide over the second dielectric layer, the overcoat layer being the outermost layer of the coating and comprising from about 1 to 20% Gd; and
wherein the glass substrate is heat treatable with the coating thereon, wherein the coating has a net compressive residual stress and a reduced tensile stress compared to a coating lacking Gd in the overcoat layer.
27. The coated article of claim 1 , wherein the layer comprising Gd-doped zirconium oxide directly contacts the low-E coating.