Polyalphaolefins and processes for forming polyalphaolefins
View Patent ↗The invention is directed to polyalphaolefins (PAOs) and processes for forming PAOs. In one embodiment, the invention is to a process for forming a PAO comprising polymerizing C 8 -C 12 α-olefin monomers in the presence of hydrogen, a C 8 -C 12 saturated hydrocarbon, e.g., a C 8 -C 12 saturated straight-chain hydrocarbon, and a catalyst system in a reaction vessel, wherein the C 8 -C 12 saturated straight-chain hydrocarbon has about the same number of carbon atoms as the C 8 -C 12 α-olefin monomers. The C 8 -C 12 saturated straight-chain hydrocarbon optionally is derived from a crude PAO product formed by the process of the invention. The invention is also directed to reaction systems for performing the processes of the invention, to processes for controlling PAO viscosity based on residence time, and to the removal of spent catalyst using a solid adsorbent particles.
1. A liquid polyalphaolefin having a kinematic viscosity at 100° C. of less than 500 cSt formed from α-olefin monomer polymerization feedstock comprising a C 8 -C 12 α-olefin monomer in an amount greater than or equal to 50 weight percent, based on total monomer contained in the feedstock, wherein the polyalphaolefin comprises from 0.5 to 5 mole % of mm triads, from 37 to 59.5 mole % of mr triads and from 40 to 58 mole % of rr triads.
2. The polyalphaolefin of claim 1 , wherein the polyalphaolefin is formed in the presence of a bridged metallocene catalyst and hydrogen.
3. The polyalphaolefin of claim 1 , wherein about 75 weight percent to about 99 weight percent of the α-olefin monomer polymerization feedstock is C 8 -C 12 α-olefin.
4. The polyalphaolefin of claim 1 , wherein the C 8 -C 12 α-olefin monomer is 1-decene.
5. The polyalphaolefin of claim 2 , wherein the bridged metallocene catalyst is diphenylmethylene (cyclopentadienyl-9-fluorenyl) zirconium dichloride.
6. The polyalphaolefin of claim 2 , wherein the monomer is polymerized in the presence of an alkylaluminoxane co-catalyst.
7. The polyalphaolefin of claim 1 , which is a homopolymer of 1-decene.
8. The polyalphaolefin of claim 3 , wherein about 1 weight percent to about 25 weight percent of the α-olefin monomer polymerization feedstock is selected from ethylene, propylene, 2-methylpropene, 1-butene, 3-methyl-1-butene, 1-pentene, 4-methyl-1-pentene, 1-hexene, 1-heptene, 1-tridecene, 1-tetradecene, 1-pentadecene, 1-hexadecene, 1-heptadecene, 1-octadecene and 1-nonadecene.
9. The polyalphaolefin of claim 8 , wherein about 80 weight percent to about 90weight percent of the α-olefin monomer polymerization feedstock is a C 8 -C 12 α-olefin and about 10 weight percent to about 20 weight percent of the α-olefin monomer polymerization feedstock is selected from ethylene, propylene, 2-methylpropene, 1-butene, 3-methyl-1-butene, 1-pentene, 4-methyl-1-pentene, 1-hexene, 1-heptene, 1-tridecene, 1-tetradecene, 1-pentadecene, 1-hexadecene, 1-heptadecene, 1-octadecene and 1-nonadecene.
10. The polyalphaolefin of claim 3 , wherein about 75 weight percent to about 99 weight percent of the α-olefin monomer polymerization feedstock is decene.
11. The polyalphaolefin of claim 10 , wherein about 75 weight percent to about 99 weight percent of the α-olefin monomer polymerization feedstock is decene and about 1 weight percent to about 25 weight percent of the α-olefin monomer polymerization feedstock is selected from ethylene, propylene, 2-methylpropene, 1-butene, 3-methyl-1-butene, 1-pentene, 4-methyl-1-pentene, 1-hexene, 1-heptene, 1-heptene, 1-octene, 1-nonene, 1-undecene, 1-dodecene, 1-tridecene, 1-tetradecene, 1-pentadecene, 1-hexadecene, 1-heptadecene, 1-octadecene and 1-nonadecene.
12. The polyalphaolefin of claim 11 , wherein about 75 weight percent to about 99 weight percent of the α-olefin monomer polymerization feedstock is decene and about 1 weight percent to about 25 weight percent of the α-olefin monomer polymerization feedstock is selected from 1-octene, 1-nonene, 1-undecene and 1-dodecene.
13. The polyalphaolefin of claim 11 , wherein about 75 weight percent to about 99 weight percent of the α-olefin monomer polymerization feedstock is decene and about 1 weight percent to about 25 weight percent of the α-olefin monomer polymerization feedstock is selected from ethylene, propylene, 2-methylpropene, 1-butene, 3-methyl-1-butene, 1-pentene, 4-methyl-1-pentene, 1-hexene and 1-heptene.
14. The polyalphaolefin of claim 1 , wherein the polyalphaolefin has a weight average molecular weight of from about 500 to about 80,000.
15. The polyalphaolefin of claim 14 , wherein the polyalphaolefin has a weight average molecular weight of from 750 to about 60,000.
16. The polyalphaolefin of claim 1 , wherein the polyalphaolefin has a T g of below about −20° C.
17. The polyalphaolefin of claim 1 , wherein the polyalphaolefin has a kinematic viscosity at 100° C. from 50 to 500 centistokes.
18. The polyalphaolefin of claim 1 , wherein the polyalphaolefin has a kinematic viscosity at 100° C. from 50 to 150 centistokes.