Perpendicular magnetic recording medium and process for manufacture thereof
View Patent ↗An object of the present invention is to provide a perpendicular magnetic recording medium in which each space between crystal grains of a first magnetic recording layer is so designed as to allow the layer to also have a function as a continuous layer, and a method of manufacturing a perpendicular magnetic recording medium. In a perpendicular magnetic recording medium 100 according to the present invention, a first magnetic recording layer 122 a and a second magnetic recording layer 122 b are ferromagnetic layers each having a granular structure in which a grain boundary part made of a non-magnetic substance is formed between crystal grains each grown in a column shape and, in the first magnetic recording layer 122 a , an intergranular distance defined by an average of shortest distances between grain boundary parts each between a crystal grain and its adjacent crystal grain is equal to or shorter than 1 nm.
1. A perpendicular magnetic recording medium comprising:
a base;
a recording layer consisting of a first magnetic recording layer 3 nm or more and less than 5 nm thick and a second magnetic recording layer 7 nm or more and less than 15 nm thick, in this order on the base, and
a continuous layer that comprises a material whose composition differs from that of a material that comprises the second magnetic recording layer and magnetically continues in a direction of a base surface is provided on a side of the second magnetic recording layer away from the base,
wherein
the first magnetic recording layer and the second magnetic recording layer are ferromagnetic layers of a granular structure in which grain boundary parts made of a non-magnetic substance are each formed between crystal grains each grown in a columnar shape, and
a first intergranular distance defined by an average of shortest distances between each of the crystal grains and its adjacent crystal grain in the first magnetic recording layer is shorter than a second intergranular distance defined by an average of shortest distances between grain boundary parts each between each of the crystal grains and its adjacent crystal grain in the second magnetic recording layer,
wherein A>B when an average particle diameter of the crystal grains in the first magnetic recording layer is taken as A nm and an average particle diameter of the crystal grains in the second magnetic recording layer is taken as B nm,
wherein a ratio between the average particle diameter of the crystal grains in the first magnetic recording layer and the average particle diameter of the crystal grains in the second magnetic recording layer is 1<A/B<1.2,
wherein the non-magnetic substance included in the first magnetic recording layer includes one or a plurality of oxides selected from the group of SiO 2 , TiO 2 , Cr 2 O 3 , Ta 2 O 5 , Nb 2 O 5 , B 2 O 3 , and ZrO 2 , and
wherein the non-magnetic substance included in the second magnetic recording layer includes one or a plurality of oxides selected from the group of SiO 2 , TiO 2 , Cr 2 O 3 , Ta 2 O 5 , Nb 2 O 5 , B 2 O 3 , and ZrO 2 .
2. The perpendicular magnetic recording medium according to claim 1 , wherein a total thickness of the first magnetic recording layer and the second magnetic recording layer is equal to or smaller than 15 nm.
3. The perpendicular magnetic recording medium according to claim 1 , wherein the film thickness of the first magnetic recording layer is approximately 0.2 to approximately 2 times larger than a film thickness of the continuous layer.
4. The perpendicular magnetic recording medium according to claim 1 , wherein the film thickness of the second magnetic recording layer is approximately 0.7 to approximately 2 times larger than a film thickness of the continuous layer.