Method of manufacturing perpendicular magnetic recording medium and perpendicular magnetic recording medium
View Patent ↗An object of the present invention is to provide a method of manufacturing a perpendicular magnetic recording medium ( 100 ) in which both of a coercive force Hc and reliability can be achieved at a higher level even with heating at the time of forming a medium protective layer ( 126 ) and to provide the perpendicular magnetic recording medium ( 100 ). Thus, in a typical structure of the present invention, in the method of manufacturing the perpendicular magnetic recording medium ( 100 ) including at least a magnetic recording layer ( 122 b ), which is a ferromagnetic layer of a granular structure in which a non-magnetic grain boundary part is formed between crystal grains each grown in a columnar shape, and a medium protective layer ( 126 ) with carbon hydride as a main component in this order on a disk base ( 110 ), the method includes a magnetic recording layer forming step of forming the magnetic recording layer ( 122 b ) so that the grain boundary part contains oxides of a plurality of types and a medium protective layer forming step of forming the medium protective layer ( 126 ) in a state where the disk base ( 110 ) having the magnetic recording layer ( 122 b ) formed thereon is heated at 160 to 200 degrees Celsius.
1. A perpendicular magnetic recording medium comprising:
a base;
at least a magnetic recording layer, which is a ferromagnetic layer of a granular structure in which a non-magnetic grain boundary part is formed between crystal grains each grown in a columnar shape;
a medium protective layer with carbon hydride as a main component in this order on said base; and
a lower magnetic recording layer below the magnetic recording layer,
wherein the grain boundary part of the magnetic recording layer contains SiO 2 and TiO 2 , the medium protective layer is formed in a state where the base having the magnetic recording layer formed thereon is heated at 160 to 200 degrees Celsius, the magnetic recording layer has a coercive force Hc equal to or larger than 5000 (Oe), the lower magnetic recording layer is a ferromagnetic layer of a granular structure in which a non-magnetic grain boundary part is formed between crystal grains each grown in a columnar shape, and the grain boundary part of the lower magnetic recording layer contains SiO 2 and CrO 2 .
2. The perpendicular magnetic recording medium according to claim 1 , wherein
a peak ratio Dh/Gh when a D peak Dh appearing near 1350 cm −1 of a spectrum obtained by excluding fluorescence from a Raman spectrum at a wave number of 900 cm −1 to a wave number of 1800 cm −1 obtained by pumping the medium protective layer with argon ion laser light having a wavelength of 514.5 nm and a G peak Gh appearing near 1520 cm −1 thereof are subjected to waveform separation with a Gaussian function is 0.75 to 0.95.