Low emission polymer composition
View Patent ↗The present invention relates to a polymer composition comprising a polyolefin base resin comprising (A) a propylene homopolymer with a MWD of 1.5 to 5.0, and (B) an ethylene copolymer with one or more comonomers selected from alphaolefins with 4 to 12 carbon atoms, having a density of not greater than 920 kg/m 3 wherein the polyolefin base resin has a weight ratio of propylene homopolymer (A) to ethylene copolymer (B) from 95:5 to 60:40, the use of such a polymer composition for the manufacture of an injection molded article, an article produced from such a polymer composition, an article with a grained surface structure produced from such a polymer composition showing having a scratch resistance, determined as the difference of the luminance ΔL at a load of 10 N, of not more than 1 and a gloss at an angle of 60° of not more than 2.8%, and the use of a polymer composition for the production of such an article.
1. A polymer composition comprising a polyolefin base resin comprising
(A) a propylene homopolymer with a MWD of 1.5 to 5.0, and
(B) an ethylene copolymer with one or more comonomers selected from alpha-olefins with 4 to 12 carbon atoms, having a density of not greater than 920 kg/m 3 ,
wherein the polyolefin base resin has a weight ratio of propylene homopolymer (A) to ethylene copolymer (B) from 95:5 to 60:40,
component (A) has an amount of xylene cold solubles (XS) of not more than 2.0 wt %, and
the polyolefin composition has a content of volatiles of less than 45 micrograms Carbon equivalents/g, measured according to VDA 277.
2. The polymer composition according to claim 1 wherein component (A) has a MFR (2.16 kg, 230° C.) of 2 to 200 g/10 min, measured according to ISO 1133.
3. The polymer composition according to claim 1 wherein component (A) has a melting point as determined by differential scanning calorimetry (DSC) of not more than 160° C.
4. The polymer composition according to claim 1 wherein component (B) has a MWD of 1.5 to 5.0 and a weight average molecular weight Mw of 40 to 160 kg/mol, measured by GPC according to ISO 16014-1, and -4.
5. The polymer composition according to claim 1 wherein component (B) has a MFR (2.16 kg, 190° C.) of at least 5.0 g/10 min, measured according to ISO 1133.
6. The polymer composition according to claim 1 wherein component (B) has a comonomer content of 5 to 40 wt % based on the total component (B) and the comonomers of component (B) are selected from a group consisting of 1-butene, 1-hexene, 4-methyl-1-pentene and 1-octene.
7. The polymer composition according to claim 1 wherein component (B) has been polymerized in the presence of a single-site catalyst.
8. The polymer composition according to claim 1 wherein the polyolefin base resin further comprises an ethylene homopolymer (C) having a density of at least 940 kg/m 3 in an amount of from greater than zero to 15 wt % based on the total polyolefin base resin.
9. The polymer composition according to claim 1 wherein the composition further comprises at least one filler material (D) in an amount of from greater than zero to 20 wt %.
10. The polymer composition according to claim 9 wherein component (D) is an inorganic filler material and is selected from talc, wollastonite, CaCO 3 , BaSO 4 and mica.
11. The polymer composition according to claim 1 wherein the polyolefin composition has an amount of volatile organic compounds of less than 100 micrograms toluene equivalents/g and an amount of fogging of less than 100 micrograms hexadecane equivalents/g, measured according to VDA 278.
12. An article produced from a polymer composition according to claim 1 .
13. An article with a grained surface structure, having a scratch resistance ΔL of not more than 1 , determined as the difference of the luminance of the unscratched from the scratched areas in a cross hatch test with the scratches being applied using a cylindrical metal pen with a ball shaped end having a radius of 0.5 mm±0.01 at a force of 10 N and the distance of the scratches being 2 mm, and a gloss at an angle of 60° of not more than 2.8%, determined according to DIN 67530, comprising a polymer composition according to claim 1 .
14. The polymer composition according to claim 1 , wherein component (A) has been polymerized in the presence of a single-site catalyst.
15. The polymer composition of claim 1 , wherein component (A) has a MWD of 2.0 to 4.0.
16. The polymer composition of claim 1 , wherein component (A) has a MWD of 2.2 to 3.5.
17. The polymer composition of claim 1 , wherein component (A) comprises a mixture of different propylene homopolymers.
18. The polymer composition of claim 1 , wherein component (B) comprises a mixture of different ethylene copolymers.
19. The polymer composition of claim 1 , wherein component (B) has a MWD of 2.2 to 3.5.