Tire Having a Ply Border Liner With Low Hysteresis
The invention relates to a tyre comprising at least one border rubber for one end of a reinforcing element or ply, having a composition based on at least one diene elastomer, a reinforcing filler and a vulcanisation system, characterized in that the composition also includes graphite, in such a way that: the reinforcing filler content is equal to (A−X) phr and the graphite content is between X/6 and 2X/3 phr; A being a number between 20 and 120; X being a number between 4 and 48; and X and A satisfying the following relationship: X<0.4A.
1 . A tire comprising at least one border rubber for one end of a reinforcing element or ply, the border rubber having a composition based on at least one diene elastomer, a reinforcing filler and a vulcanization system, wherein the composition further comprises graphite, in such a way that:
the reinforcing filler content is equal to (A−X) phr and the graphite content is between X/6 and 2×/3 phr;
A being a number between 20 and 120;
X being a number between 4 and 48; and
X and A satisfying the following relationship: X<0.4A.
2 . The tire according to claim 1 , wherein the composition of the border rubber includes graphite with a content between 2 and 30 phr.
3 . The tire according to claim 1 , wherein the composition of the border rubber includes graphite with a content between 3 and 20 phr.
4 . The tire according to claim 1 , wherein the graphite content is equal to X/2.
5 . The tire according to claim 1 , wherein the graphite content is equal to X/6.
6 . The tire according to claim 1 , wherein the diene elastomer is selected from the group consisting of polybutadienes, natural rubber, synthetic polyisoprenes, butadiene copolymers, isoprene copolymers and blends of these elastomers.
7 . The tire according to claim 1 , wherein the diene elastomer is an isoprene elastomer.
8 . The tire according to claim 7 , wherein the diene elastomer comprises more than 40 phr natural rubber and/or synthetic polyisoprene.
9 . The tire according to claim 1 , wherein the graphite is in lamellar form.
10 . The tire according to claim 1 , wherein the graphite is a natural graphite.
11 . The tire according to claim 1 , wherein the graphite is an expandable natural graphite.
12 . The tire according to claim 1 , wherein the graphite is an expanded graphite.
13 . The tire according to claim 1 , wherein the graphite is a synthetic graphite.
14 . The tire according to claim 1 , wherein the graphite comprises a blend of natural graphite and/or expandable natural graphite and/or expanded graphite and/or synthetic graphite.
15 . The tire according to claim 1 , wherein the reinforcing filler comprises carbon black.
16 . The tire according to claim 15 , wherein the reinforcing filler comprises predominantly carbon black.
17 . The tire according to claim 16 , wherein the reinforcing black filler is formed from carbon black.
18 . The tire according to claim 1 , wherein the reinforcing filler comprises an inorganic filler.
19 . The tire according to claim 18 , wherein the inorganic filler is silica.
20 . A process for producing a border rubber for one end of a reinforcing element or ply of a tire, having a composition based on at least one diene elastomer, a reinforcing filler and a vulcanization system, wherein the composition further comprises graphite, in such a way that:
the reinforcing filler content is equal to (A−X) phr and the graphite content is between X/6 and 2×/3 phr;
A being a number between 20 and 120;
X being a number between 4 and 48; and
X and A satisfying the following relationship: X<0.4A,
said process comprising the following steps:
incorporating into a diene elastomer at least one reinforcing filler, by thermomechanically mixing all the ingredients, one or more times, until a maximum temperature of between 110° C. and 190° C. is reached;
cooling the mixture down to a temperature below 100° C.;
then incorporating a vulcanization system; and
mixing everything until a maximum temperature below 110° C. is reached.
21 . The tire according to claim 7 , wherein the isoprene elastomer comprises a synthetic or natural rubber.