Carbon nanofiber, method for production thereof, method for production of carbon fiber composite material using carbon nanofiber, and carbon fiber composite material
View Patent ↗A method of producing a carbon fiber composite material includes a first step and a second step. The first step includes oxidizing first carbon nanofibers produced by a vapor growth method to obtain second carbon nanofibers having an oxidized surface. The second step includes mixing the second carbon nanofibers into an elastomer, and uniformly dispersing the carbon nanofibers in the elastomer by applying a shear force to obtain the carbon fiber composite material. The second carbon nanofibers obtained by the first step have a surface oxygen concentration measured by X-ray photoelectron spectroscopy (XPS) of 2.6 to 4.6 atm %.
1. A method of producing a carbon fiber composite material comprising:
providing first carbon nanofibers produced by a vapor growth method;
oxidizing the first carbon nanofibers and reducing the mass of the first carbon nanofibers by 2 to 20% to obtain second carbon nanofibers having an oxidized surface, the second carbon nanofibers having a surface oxygen concentration measured by X-ray photoelectron spectroscopy (XPS) of 2.6 to 4.6 atm %; and
mixing the second carbon nanofibers into an elastomer, and uniformly dispersing the second carbon nanofibers in the elastomer by applying a shear force to obtain a carbon fiber composite material.
2. The method of producing a carbon fiber composite material according to claim 1 , wherein the surface oxygen concentration of the second carbon nanofibers measured by X-ray photoelectron spectroscopy (XPS) is higher than that of the first carbon nanofibers by 0.5 to 2.6 atm %.
3. The method of producing a carbon fiber composite material according to claim 1 , wherein the surface oxygen concentration of the second carbon nanofibers measured by X-ray photoelectron spectroscopy (XPS) is higher than that of the first carbon nanofibers by 20 to 120%.
4. The method of producing a carbon fiber composite material according to claim 1 , wherein the oxidizing step includes heating the first carbon nanofibers at 600 to 800° C. in an oxygen-containing atmosphere.
5. A method of producing a carbon fiber composite material comprising:
providing first carbon nanofibers produced by a vapor growth method;
oxidizing the first carbon nanofibers and reducing the mass of the first carbon nanofibers by 2 to 20% to obtain second carbon nanofibers having an oxidized surface, the second carbon nanofibers having a surface oxygen concentration measured by X-ray photoelectron spectroscopy (XPS) of 2.6 to 4.6 atm % and the second carbon nanofibers having a ratio (D/G) of a peak intensity D at around 1300 cm −1 to a peak intensity G at around 1600 cm −1 measured by Raman scattering spectroscopy of 0.12 to 0.22; and
mixing the second carbon nanofibers into an elastomer, and uniformly dispersing the second carbon nanofibers in the elastomer by applying a shear force to obtain a carbon fiber composite material.
6. A method of producing a carbon fiber composite material comprising:
providing first carbon nanofibers produced by a vapor growth method;
oxidizing the first carbon nanofibers to obtain second carbon nanofibers having an oxidized surface, the second carbon an having a surface oxygen concentration measured by X-ray photoelectron spectroscopy (XPS) of 2.6 to 4.6 atm % and the second carbon nanofibers having a specific surface area by nitrogen adsorption of 34 to 58 m 2 /g; and
mixing the second carbon nanofibers into an elastomer, and uniformly dispersing the second carbon nanofibers in the elastomer by applying a shear force to obtain a carbon fiber composite material.
7. The method of producing a carbon fiber composite material according to claim 1 , wherein the first carbon nanofibers have an average diameter of 4 to 250 nm.