Wire and methodology for cutting materials with wire
View Patent ↗Wire for cutting feedstock and a method for cutting feedstock with the wire. The wire may include an iron based alloy comprising at least 35 at % iron, nickel and/or cobalt in the range of about 7 to 50 at %, at least one non-metal or metalloid selected from the group consisting of boron, carbon, silicon, phosphorus, and/or nitrogen present in the range of about 1 to 35 at %, and one metal selected from the group consisting of copper, titanium, molybdenum, aluminum, and/or chromium present in the range of about 0 to 25 at %, wherein the wire has an aspect ratio of greater than one and exhibits metallic and/or crystalline phases of less than 500 nm in size.
1. A method of cutting feedstock, comprising:
providing a wire comprising an iron based alloy comprising iron present in the range of 40 at % to 68 at %, nickel present in the range of 13 at % to 17 at %, cobalt present in the range of 1 at % to 21 at %, boron present in the range of 12 at % to 19 at %, optionally carbon present in the range of 1 at % to 6 at %, optionally silicon present in the range of 0.1 at % to 4.0 at %, and one or more metals selected from the group consisting of titanium, molybdenum, aluminum, and/or chromium present in the range of 0 to 20 at %, wherein said wire has an aspect ratio of greater than one and exhibits metallic and/or crystalline phases of less than 500 nm in size; and
cutting said feedstock with said wire.
2. The method of claim 1 , further comprising supplying an abrasive slurry and contacting said abrasive slurry with said feedstock with said wire.
3. The method of claim 2 , wherein said abrasive slurry comprises particles exhibiting a Mohs hardness of 9 or greater.
4. The method of claim 1 , wherein said wire is coated or impregnated with particles exhibiting a Mohs hardness of 9 or greater.
5. The method of claim 4 , wherein said particles are in the range of 10 μm to 120 μm in size.
6. The method of claim 4 , wherein said wire is coated with an overstrike comprising one or more of the following materials nickel, copper, silver and gold.
7. The method of claim 1 , wherein said wire has a width in the range of 0.8 mm to 2 mm and a thickness in the range of 15 μm to 150 μm.
8. The method of claim 1 , wherein said wire exhibits a tensile elongation of 1% or greater, when measured at a strain rate of 0.001 s −1 .
9. The method of claim 1 , wherein said wire exhibits a tensile elongation of 1% to 7%, when measured at a strain rate of 0.001 s −1 .
10. The method of claim 1 , wherein said wire exhibits an ultimate tensile strength in the range of 0.5 GPa to 4.5 GPa, when measured at a strain rate of 0.001 s −1 .
11. The method of claim 1 , wherein said alloy exhibits a tensile elongation of 1% to 7% and an ultimate tensile strength in the range of 0.5 GPa to 4.5 GPa, when measured at a strain rate of 0.001 s −1 .
12. The method of claim 1 , wherein said wire includes metallic glass phases.
13. The method of claim 1 , wherein said wire exhibits at least one or more glass to crystalline transformation peaks from 350 to 650° C., when measured by DSC or DTA at a rate of 10° C./min.
14. The method of claim 1 , wherein said wire exhibits at least one or more glass to crystalline transformation peaks with exothermic energies from −8.9 to −173.9 J/g, when measured by DSC or DTA at a heating rate of 10° C./min.
15. The method of claim 1 , wherein said wire exhibits a tensile elongation of 1% to 7%, when measured at a strain rate of 0.001 s −1 ; an ultimate tensile strength in the range of 0.5 GPa to 4.5 GPa, when measured at a strain rate of 0.001 s −1 ; at least one or more glass to crystalline transformation peaks from 350 to 650° C., when measured by DSC or DTA at a heating rate of 10° C./min; at least one or more glass to crystalline transformation peaks with exothermic energies from −8.9 to −173.9 J/g, when measured by DSC or DTA at a heating rate of 10° C./min.
16. The method of claim 1 , wherein said iron based alloy comprises iron present in the range of 43 to 68 at %; nickel present in the range of 15 at % to 17 at %, cobalt present in the range of 2 to 21 at %; boron present in the range of 12 to 19 at %; optionally carbon present in the range of 1 to 6 at %; and optionally silicon present in the range of 0.1 to 4 at %, wherein said iron based alloy is chromium free.
17. The method of claim 16 , wherein said iron based alloy exhibits a tensile elongation of 1.5% 6.8%, when measured at a strain rate of 0.001 s −1 ; an ultimate tensile strength in the range of 1.0 GPa to 3.7 GPa, when measured at a strain rate of 0.001 s −1 ; and at least one or more glass to crystalline transformation peaks from 403 to 618° C., when measured by DSC or DTA at a heating rate of 10° C./min.
18. The method of claim 1 , wherein said iron based alloy comprises iron present in the range of 40 at % to 65 at %; nickel present in the range of 13 at % to 17 at %; cobalt present in the range of 2 at % to 12 at %, boron present in the range of 12 at % to 17 at %, silicon present in the range of 0.1 at % to 4 at %, and chromium present in the range of 1 at % to 20 at %, wherein said iron based alloy is free of carbon.
19. The method of claim 18 , wherein said iron based alloy exhibits a tensile elongation of 2.7% to 4.8%, when measured at a strain rate of 0.001 s −1 ; an ultimate tensile strength in the range of 2.7 GPa to 4.7 GPa, when measured at a strain rate of 0.001 s −1 ; and at least one or more glass to crystalline transformation peaks from 416 to 556° C., when measured by DSC or DTA at a heating rate of 10° C./min.
20. The method of claim 1 , wherein said feedstock is a silicon ingot.
21. A wire for cutting feedstock, comprising:
an iron based alloy comprising iron present in the range of 40 at % to 68 at %, nickel present in the range of 13 at % to 17 at %, cobalt present in the range of 1 at % to 21 at %, boron present in the range of 12 at % to 19 at %, optionally carbon present in the range of 1 at % to 6 at %, optionally silicon present in the range of 0.1 at % to 4.0 at %, and one or more metals selected from the group consisting of titanium, molybdenum, aluminum, and/or chromium present in the range of about 0 to 20 at %, wherein said wire has an aspect ratio of greater than one and metallic and/or crystalline phases of less than 500 nm in size.
22. The wire of claim 21 , wherein said wire is impregnated with particles having a Mohs hardness of greater than 9.
23. The wire of claim 21 , further comprising a coating at least partially provided on the surface of said wire.
24. The wire of claim 21 , wherein said wire exhibits a tensile elongation of 1% to 7%, when measured at a strain rate of 0.001 s −1 ; an ultimate tensile strength in the range of 0.5 GPa to 4.5 GPa, when measured at a strain rate of 0.001 s −1 ; at least one or more glass to crystalline transformation peaks from 350 to 650° C., when measured by DSC or DTA at a heating rate of 10° C./min; at least one or more glass to crystalline transformation peaks with exothermic energies from −8.9 to −173.9 J/g, when measured by DSC or DTA at a heating rate of 10° C./min.
25. The wire of claim 21 , wherein said iron based alloy comprises iron present in the range of 43 to 68 at %; nickel present in the range of 15 at % to 17 at %, cobalt present in the range of 2 to 21 at %; boron present in the range of 12 to 19 at %; optionally carbon present in the range of 1 to 6 at %; and optionally silicon present in the range of 0.1 to 4 at %, wherein said iron based alloy is chromium free.
26. The wire of claim 25 , wherein said iron based alloy exhibits a tensile elongation of 1.5% 6.8%, when measured at a strain rate of 0.001 s −1 ; an ultimate tensile strength in the range of 1.0 GPa to 3.7 GPa, when measured at a strain rate of 0.001 s −1 ; and at least one or more glass to crystalline transformation peaks from 403 to 618° C., when measured by DSC or DTA at a heating rate of 10° C./min.
27. The wire of claim 21 , wherein said iron based alloy comprises iron present in the range of 40 at % to 65 at %; nickel present in the range of 13 at % to 17 at %; cobalt present in the range of 2 at % to 12 at %, boron present in the range of 12 at % to 17 at %, silicon present in the range of 0.1 at % to 4 at %, and chromium present in the range of 1 at % to 20 at %, wherein said iron based alloy is carbon free.
28. The method of claim 27 , wherein said iron based alloy exhibits a tensile elongation of 2.7% to 4.8%, when measured at a strain rate of 0.001 s −1 ; an ultimate tensile strength in the range of 2.7 GPa to 4.7 GPa, when measured at a strain rate of 0.001 s −1 ; and at least one or more glass to crystalline transformation peaks from 416 to 556° C., when measured by DSC or DTA at a heating rate of 10° C./min.
29. The wire of claim 21 , wherein said wire has a width in the range of 0.8 mm to 2 mm and a thickness in the range of 15 μm to 150 μm.
30. The wire of claim 21 , wherein said wire exhibits a tensile elongation of 1% or greater, when measured at a strain rate of 0.001 s −1 .
31. The wire of claim 21 , wherein said wire exhibits a tensile elongation of 1% to 7%, when measured at a strain rate of 0.001 s −1 .
32. The wire of claim 21 , wherein said wire exhibits an ultimate tensile strength in the range of 0.5 GPa to 4.5 GPa, when measured at a strain rate of 0.001 s −1 .
33. The wire of claim 21 , wherein said wire exhibits a tensile elongation of 1% to 7% and an ultimate tensile strength in the range of 0.5 GPa to 4.5 GPa, when measured at a strain rate of 0.001 s −1 .
34. The wire of claim 21 , wherein said wire includes metallic glass phases.
35. The wire of claim 21 , wherein said wire exhibits at least one or more glass to crystalline transformation peaks from 350 to 650° C., when measured by DSC or DTA at a heating rate of 10° C./min.
36. The wire of claim 21 , wherein said wire exhibits at least one or more glass to crystalline transformation peaks with exothermic energies from −8.9 to −173.9 J/g, when measured by DSC or DTA at a heating rate of 10° C./min.