Printable monolayer polyvinylidene chloride structures
View Patent ↗The present invention includes a polymer composition of at least one vinylidene chloride/alkyl acrylate polymer having from about 3.4 to about 6.7 percent mole percent of mer units derived from at least one alkyl acrylate monomer polymerized with the vinylidene chloride and comprising a plasticizer and having at least one of the following compositional characteristics (1) and (2): (1) at least one low molecular weight vinyl chloride polymer having a molecular weight of at most about 70,000 Daltons in an amount sufficient to increase affinity for at least one ink; and (2) at least one methacrylic polymer in an amount sufficient to increase the affinity for at least one ink. Surfaces comprising such a composition and articles having such surfaces are surprisingly printable and are aspects of the invention as is printing thereon.
1. A polymer surface preparable from a polymer composition of at least one vinylidene chloride/alkyl acrylate polymer having from about 3.4 to about 6.7 mole percent of mer units derived from at least one alkyl acrylate monomer polymerized with the vinylidene chloride; and comprising a plasticizer and at least one low molecular weight vinyl chloride polymer having a molecular weight of at most about 70,000 Daltons in an amount of from about 0.5 to about 3 weight percent based on total polymer composition, which is sufficient to increase affinity for at least one ink.
2. The polymer surface of claim 1 which has more affinity for or adhesion to at least one ink than does a film, article or surface of the same composition except without the vinyl chloride polymer.
3. The polymer surface of claim 1 wherein the alkyl acrylate is methyl acrylate.
4. The polymer surface of claim 1 wherein the composition comprises at least one epoxy plasticizer and at least one ester plasticizer and the ester plasticizer or combination thereof is selected from dibutyl sebacate, acetyl tributyl citrate (ATBC), other citrate esters, other polymeric or high molecular weight ester oils, and combinations thereof.
5. The polymer surface of claim 4 having printing thereon.
6. The polymer surface of claim 1 wherein the amount of total plasticizer is from about 4 to about 9 weight percent based on polymer composition including from about 0.5 to about 3.5 weight percent based on weight of polymer composition of an epoxy plasticizer or combination of epoxy plasticizers.
7. The polymer surface of claim 6 having printing thereon.
8. The polymer surface of claim 1 wherein the low molecular weight vinyl chloride polymer is present in an amount of from about 0.75 to about 2.7 weight percent based on total polymer composition.
9. The polymer surface of claim 1 further comprising at least one methacrylic polymer, wherein the methacrylic polymer has a molecular weight of about 100,000 to about 400,000 and is a copolymer of methyl methacrylate and at least one of: an alkyl acrylate, different methacrylic monomer, styrenic monomer or a combination thereof in an amount of from about 50 to about 70 weight percent of the methacrylic polymer.
10. The polymer surface of claim 1 wherein the vinyl chloride polymer has a molecular weight of from about 15,000 to about 50,000 Daltons and a comonomer selected from vinyl acetate, alkyl acrylate, alkyl methacrylate, ethylene, styrenic monomer, acrylic acid, methacrylic acid, maleic acid, and a combination thereof.
11. The polymer surface of claim 1 having printing thereon.
12. An article comprising the surface of claim 1 as at least a portion of its surface.
13. The article claim of 12 which comprises at least one monolayer film or sheet, multilayer film, sheet or laminate, a molded or fabricated article, or a coated article.
14. A process of printing comprising applying ink to a surface of claim 1 .