High activity catalyst component for olefin polymerization and method of using the same

1. A catalyst system for use in a polymerization of an olefin comprising:

a) a solid catalyst component comprising:

(i) a titanium halide;

(ii) a magnesium halide;

(iii) a first internal electron donor compound comprising at least one ether group and at least one ketone group; and

(iv) a second electron donor compound having a 1,8-naphthyl diester structure;

b) an organoaluminum compound; and

c) an external electron donor compound.

2. The catalyst system of claim 1 , wherein the first internal electron donor has a structure:

wherein R 1 , R 2 , R 3 , and R 4 , independently, represent a substituted or unsubstituted hydrocarbon group.

3. The catalyst system of claim 2 , wherein R 1 , C 1 , and R 2 are taken together to form a 5- or 6-membered hydrocarbon ring or a fluorenyl structure.

4. The catalyst system of claim 2 , wherein R 3 is linear or branched C 1 -C 12 alkyl or C 4 -C 8 alkylphenyl; and O—R 4 is C 1 -C 6 alkoxy.

5. The catalyst system of claim 2 , wherein R 1 —C 1 —R 2 are taken together to form fluorene, cyclopentane, cyclopentadiene, cyclohexane, cyclohexadiene, or a C 5 -C 15 linear or branched alkyl group.

6. The catalyst system of claim 1 , wherein the first internal electron donor is selected from the group consisting of 9-(alkylcarbonyl)-9-alkoxymethylfluorene, 9-(methylcarbonyl)-9-methoxymethylfluorene, 9-(methylcarbonyl)-9-ethoxymethylfluorene, 9-(methylcarbonyl)-9-propoxymethylfluorene, 9-(methylcarbonyl)-9-butoxymethylfluorene, 9-(methylcarbonyl)-9-pentoxymethylfluorene, 9-(ethylcarbonyl)-9-methoxymethylfluorene, 9-(ethylcarbonyl)-9-ethoxymethylfluorene, 9-(ethylcarbonyl)-9-propoxymethylfluorene, 9-(ethylcarbonyl)-9-butoxymethylfluorene, 9-(ethylcarbonyl)-9-pentoxymethylfluorene, 9-(propylcarbonyl)-9-methoxymethylfluorene, 9-(propylcarbonyl)-9-ethoxymethylfluorene, 9-(propylcarbonyl)-9-propoxymethylfluorene, 9-(propylcarbonyl)-9-butoxymethylfluorene, 9-(propylcarbonyl)-9-pentoxymethylfluorene, 9-(butylcarbonyl)-9-methoxymethylfluorene, 9-(butylcarbonyl)-9-ethoxymethylfluorene, 9-(butylcarbonyl)-9-propoxymethylfluorene, 9-(butylcarbonyl)-9-butoxymethylfluorene, 9-(butylcarbonyl)-9-pentoxymethylfluorene, 9-(isobutylcarbonyl)-9-methoxymethylfluorene, 9-(isobutylcarbonyl)-9-ethoxymethylfluorene, 9-(isobutylcarbonyl)-9-propoxymethylfluorene, 9-(isobutylcarbonyl)-9-butoxymethylfluorene, 9-(isobutylcarbonyl)-9-pentoxymethylfluorene, 9-(pentylcarbonyl)-9-methoxymethylfluorene, 9-(pentylcarbonyl)-9-ethoxymethylfluorene, 9-(pentylcarbonyl)-9-propoxymethylfluorene, 9-(pentylcarbonyl)-9-butoxymethylfluorene, 9-(pentylcarbonyl)-9-pentoxymethylfluorene, 9-(hexylcarbonyl)-9-methoxymethylfluorene, 9-(hexylcarbonyl)-9-ethoxymethylfluorene, 9-(hexylcarbonyl)-9-propoxymethylfluorene, 9-(hexylcarbonyl)-9-butoxymethylfluorene, 9-(hexylcarbonyl)-9-pentoxymethylfluorene, 9-(octylcarbonyl)-9-methoxymethylfluorene, 9-(octylcarbonyl)-9-ethoxymethylfluorene, 9-(octylcarbonyl)-9-propoxymethylfluorene, 9-(octylcarbonyl)-9-butoxymethylfluorene, 9-(octylcarbonyl)-9-pentoxymethylfluorene; 9-(i-octylcarbonyl)-9-methoxymethylfluorene, 9-(i-octylcarbonyl)-9-ethoxymethylfluorene, 9-(i-octylcarbonyl)-9-propoxymethylfluorene, 9-(i-octylcarbonyl)-9-butoxymethylfluorene, 9-(i-octylcarbonyl)-9-pentoxymethylfluorene, 9-(nonylcarbonyl)-9-methoxymethylfluorene, 9-(nonylcarbonyl)-9-ethoxymethylfluorene, 9-(nonylcarbonyl)-9-propoxymethylfluorene, 9-(nonylcarbonyl)-9-butoxymethylfluorene, 9-(nonylcarbonyl)-9-pentoxymethylfluorene; 9-(i-nonylcarbonyl)-9-methoxymethylfluorene, 9-(i-nonylcarbonyl)-9-ethoxymethylfluorene, 9-(i-nonylcarbonyl)-9-propoxymethylfluorene, 9-(i-nonylcarbonyl)-9-butoxymethylfluorene, 9-(i-nonylcarbonyl)-9-pentoxymethylfluorene, 9-(2-ethyl-hexylcarbonyl)-9-methoxymethylfluorene, 9-(2-ethyl-hexylcarbonyl)-9-ethoxymethylfluorene, 9-(2-ethyl-hexylcarbonyl)-9-propoxymethylfluorene, 9-(2-ethyl-hexylcarbonyl)-9-butoxymethylfluorene, 9-(2-ethyl-hexylcarbonyl)-9-pentoxymethylfluorene, 9-(phenylketone)-9-methoxymethylfluorene, 9-(phenylketone)-9-ethoxymethylfluorene, 9-(phenylketone)-9-propoxymethylfluorene, 9-(phenylketone)-9-butoxymethylfluorene, 9-(phenylketone)-9-pentoxymethylfluorene, 9-(4-methylphenylketone)-9-methoxymethylfluorene, 9-(3-methylphenylketone)-9-methoxymethylfluorene, 9-(2-methylphenylketone)-9-methoxymethylfluorene, 1-(ethylcarbonyl)-1-methoxymethylcyclopentane, 1-(propylcarbonyl)-1-methoxymethylcyclopentane, 1-(i-propylcarbonyl)-1-methoxymethylcyclopentane, 1-(butylcarbonyl)-1-methoxymethylcyclopentane, 1-(i-butylcarbonyl)-1-methoxymethylcyclopentane, 1-(pentylcarbonyl)-1-methoxymethylcyclopentane, 1-(1-pentylcarbonyl)-1-methoxymethylcyclopentane, 1-(neopentylcarbonyl)-1-methoxymethylcyclopentane, 1-(hexylcarbonyl)-1-methoxymethylcyclopentane, 1-(2-ethylhexylcarbonyl)-1-methoxymethylcyclopentane, 1-(octylcarbonyl)-1-methoxymethylcyclopentane, 1-(i-octylcarbonyl)-1-methoxymethylcyclopentane, 1-(nonylcarbonyl)-1-methoxymethylcyclopentane, 1-(i-nonylcarbonyl)-1-methoxymethylcyclopentane, 1-(ethylcarbonyl)-1-methoxymethyl-2-methylcyclopentane, 1-(propylcarbonyl)-1-methoxymethyl-2-methylcyclopentane, 1-(i-propylcarbonyl)-1-methoxymethyl-2-methyl-cyclopentane, 1-(butylcarbonyl)-1-methoxymethyl-2-methylcyclopentane, 1-(i-butylcarbonyl)-1-methoxymethyl-2-methylcyclopentane, 1-(pentylcarbonyl)-1-methoxymethyl-2-methylcyclopentane, 1-(i-pentylcarbonyl)-1-methoxymethyl-2-methylcyclopentane, 1-(neopentylcarbonyl)-1-methoxymethyl-2-methylcyclopentane, 1-(hexylcarbonyl)-1-methoxymethyl-2-methylcyclopentane, 1-(2-ethylhexylcarbonyl)-1-methoxymethyl-2-methyl cyclopentane, 1-(octylcarbonyl)-1-methoxymethyl-2-methyl cyclopentane, 1-(i-octylcarbonyl)-1-methoxymethyl-2-methyl cyclopentane, 1-(nonylcarbonyl)-1-methoxymethyl-2-methyl cyclopentane, 1-(1-nonylcarbonyl)-1-methoxymethyl-2-methylcyclopentane, 1-(ethylcarbonyl)-1-methoxymethyl-2,5-dimethylcyclopentane, 1-(propylcarbonyl)-1-methoxymethyl-2,5-dimethylcyclopentane, 1-(i-propylcarbonyl)-1-methoxymethyl-2,5-dimethyl-cyclopentane, 1-(butylcarbonyl)-1-methoxymethyl-2,5-di-cyclopentane, 1-(i-butylcarbonyl)-1-methoxymethyl-2,5-dimethylcyclopentane, 1-(pentylcarbonyl)-1-methoxymethyl-2,5-dimethylcyclopentane, 1-(i-pentylcarbonyl)-1-methoxymethyl-2,5-dimethylcyclopentane, 1-(neopentylcarbonyl)-1-methoxymethyl-2,5-dimethylcyclopentane, 1-(hexylcarbonyl)-1-methoxymethyl-2,5-dimethylcyclopentane, 1-(2-ethylhexylcarbonyl)-1-methoxymethyl-2,5-dimethyl cyclopentane, 1-(octylcarbonyl)-1-methoxymethyl-2,5-dimethyl cyclopentane, 1-(i-octylcarbonyl)-1-methoxymethyl-2,5-dimethyl cyclopentane, 1-(nonylcarbonyl)-1-methoxymethyl-2,5-dimethyl cyclopentane, 1-(i-nonylcarbonyl)-1-methoxymethyl-2,5-dimethyl cyclopentane, 1-(ethylcarbonyl)-1-methoxymethyl-2,4-cyclopentadiene, 1-(propylcarbonyl)-1-methoxymethyl-2,4-cyclopentadiene, 1-(i-propylcarbonyl)-1-methoxymethyl-2,4-cyclopentadiene, 1-(butylcarbonyl)-1-methoxymethyl-2,4-cyclopentadiene, 1-(i-butylcarbonyl)-1-methoxymethyl-2,4-cyclopentadiene, 1-(pentylcarbonyl)-1-methoxymethyl-2,4-cyclopentadiene, 1-(i-pentylcarbonyl)-1-methoxymethyl-2,4-cyclopentadiene, 1-(neopentylcarbonyl)-1-methoxymethyl-2,4-cyclopentadiene, 1-(hexylcarbonyl)-1-methoxymethyl-2,4-cyclopentadiene, 1-(2-ethylhexylcarbonyl)-1-methoxymethyl-2,4-cyclopentadiene, 1-(octylcarbonyl)-1-methoxymethyl-2,4-cyclopentadiene, 1-(i-octylcarbonyl)-1-methoxymethyl-2,4-cyclopentadiene, 1-(nonylcarbonyl)-1-methoxymethyl-2,4-cyclopentadiene, 1-(i-nonylcarbonyl)-1-methoxymethyl-2,4-cyclopentadiene, 1-(ethylcarbonyl)-1-methoxymethyl-2-methyl-2,4-cyclopentadiene, 1-(propylcarbonyl)-1-methoxymethyl-2-methyl-2,4-cyclopentadiene, 1-(i-propylcarbonyl)-1-methoxymethyl-2-methyl-2,4-cyclopentadiene, 1-(butylcarbonyl)-1-methoxymethyl-2-methyl-2,4-cyclopentadiene, 1-(i-butylcarbonyl)-1-methoxymethyl-2-methyl-2,4-cyclopentadiene, 1-(pentylcarbonyl)-1-methoxymethyl-2-methyl-2,4-cyclopentadiene, 1-(i-pentylcarbonyl)-1-methoxymethyl-2-methyl-2,4-cyclopentadiene, 1-(neopentylcarbonyl)-1-methoxymethyl-2-methyl-2,4-cyclopentadiene, 1-(hexylcarbonyl)-1-methoxymethyl-2-methyl-2,4-cyclopentadiene, 1-(2-ethylhexylcarbonyl)-1-methoxymethyl-2-methyl-2,4-cyclopentadiene, 1-(octylcarbonyl)-1-methoxymethyl-2-methyl-2,4-cyclopentadiene, 1-(i-octylcarbonyl)-1-methoxymethyl-2-methyl-2,4-cyclopentadiene, 1-(nonylcarbonyl)-1-methoxymethyl-2-methyl-2,4-cyclopentadiene, 1-(i-nonylcarbonyl)-1-methoxymethyl-2-methyl-2,4-cyclopentadiene, 1-(ethylcarbonyl)-1-methoxymethyl-2,5-dimethyl-2,4-cyclopentadiene, 1-(propylcarbonyl)-1-methoxymethyl-2,5-dimethyl-2,4-cyclopentadiene, 1-(i-propylcarbonyl)-1-methoxymethyl-2,5-dimethyl-2,4-cyclopentadiene, 1-(butylcarbonyl)-1-methoxymethyl-2,5-dimethyl-2,4-cyclopentadiene, 1-(i-butylcarbonyl)-1-methoxymethyl-2,5-dimethyl-2,4-cyclopentadiene, 1-(pentylcarbonyl)-1-methoxymethyl-2,5-dimethyl-2,4-cyclopentadiene, 1-(i-pentylcarbonyl)-1-methoxymethyl-2,5-dimethyl-2,4-cyclopentadiene, 1-(neopentylcarbonyl)-1-methoxymethyl-2,5-dimethyl-2,4-cyclopentadiene, 1-(hexylcarbonyl)-1-methoxymethyl-2,5-dimethyl-2,4-cyclopentadiene, 1-(2-ethylhexylcarbonyl)-1-methoxymethyl-2,5-dimethyl-2,4-cyclopentadiene, 1-(octylcarbonyl)-1-methoxymethyl-2,5-dimethyl-2,4-cyclopentadiene, 1-(i-octylcarbonyl)-1-methoxymethyl-2,5-dimethyl-2,4-cyclopentadiene, 1-(nonylcarbonyl)-1-methoxymethyl-2,5-dimethyl-2,4-cyclopentadiene, 1-(i-nonylcarbonyl)-1-methoxymethyl-2,5-dimethyl-2,4-cyclopentadiene, 1-(ethylcarbonyl)-1-methoxymethylcyclohexane, 1-(propylcarbonyl)-1-methoxymethylcyclohexane, 1-(i-propylcarbonyl)-1-methoxymethylcyclohexane, 1-(butylcarbonyl)-1-methoxymethylcyclohexyl, 1-(i-butylcarbonyl)-1-methoxymethylcyclohexane, 1-(pentylcarbonyl)-1-methoxymethylcyclohexane, 1-(i-pentylcarbonyl)-1-methoxymethylcyclohexane, 1-(neopentylcarbonyl)-1-methoxymethylcyclohexane, 1-(hexylcarbonyl)-1-methoxymethylcyclohexane, 1-(2-ethylhexylcarbonyl)-1-methoxymethylcyclohexane, 1-(octylcarbonyl)-1-methoxymethylcyclohexane, 1-(i-octylcarbonyl)-1-methoxymethylcyclohexane, 1-(i-nonylcarbonyl)-1-methoxymethylcyclohexane, 1-(ethylcarbonyl)-1-methoxymethyl-2-methylcyclohexane, 1-(propylcarbonyl)-1-methoxymethyl-2-methylcyclohexane, 1-(i-propanecarbonyl)-1-methoxymethyl-2-methylcyclohexane, 1-(butylcarbonyl)-1-methoxymethyl-2-methylcyclohexane, 1-(i-butylcarbonyl)-1-methoxymethyl-2-methylcyclohexane, 1-(pentylcarbonyl)-1-methoxymethyl-2-methylcyclohexane, 1-(i-pentylcarbonyl)-1-methoxymethyl-2-methylcyclohexane, 1-(neopentylcarbonyl)-1-methoxymethyl-2-methylcyclohexane, 1-(hexylcarbonyl)-1-methoxymethyl-2-methylcyclohexane, 1-(2-ethylhexylcarbonyl)-1-methoxymethyl-2-methylcyclohexane, 1-(octylcarbonyl)-1-methoxymethyl-2-methylcyclohexane, 1-(i-octylcarbonyl)-1-methoxymethyl-2-methylcyclohexane, 1-(i-nonylcarbonyl)-1-methoxymethyl-2-methyl cyclohexane, 1-(ethylcarbonyl)-1-methoxymethyl-2,6-dimethylcyclohexane, 1-(propylcarbonyl)-1-methoxymethyl-2,6-dimethylcyclohexane, 1-(i-propylcarbonyl)-1-methoxymethyl-2,6-dimethyl-cyclohexane, 1-(butylcarbonyl)-1-methoxymethyl-2,6-dimethyl-cyclohexane, 1-(i-butylcarbonyl)-1-methoxymethyl-2,6-dimethylcyclohexane, 1-(pentylcarbonyl)-1-methoxymethyl-2,6-dimethylcyclohexane, 1-(i-pentylcarbonyl)-1-methoxymethyl-2,6-dimethylcyclohexane, 1-(neopentylcarbonyl)-1-methoxymethyl-2,6-dimethylcyclohexane, 1-(hexylcarbonyl)-1-methoxymethyl-2,6-dimethylcyclohexane, 1-(2-ethylhexylcarbonyl)-1-methoxymethyl-2,6-dimethyl cyclohexane, 1-(octylcarbonyl)-1-methoxymethyl-2,6-dimethyl cyclohexane, 1-(i-octylcarbonyl)-1-methoxymethyl-2,6-dimethyl cyclohexane, 1-(i-nonylcarbonyl)-1-methoxymethyl-2,6-dimethyl cyclohexane, 2,5-dimethyl-3-ethylcarbonyl-3′-methoxymethylpentane, 2,5-dimethyl-3-propylcarbonyl-3′-methoxymethylpentane, 2,5-dimethyl-3-propylcarbonyl-3′-methoxymethylpentane, 2,5-dimethyl-3-butylcarbonyl-3′-methoxymethylpentane, 2,5-dimethyl-3-i-butylcarbonyl-1-methoxymethylcyclohexyl, 1-(ethylcarbonyl)-1-methoxymethyl-2,5-cyclohexadiene, 1-(propylcarbonyl)-1-methoxymethyl-2,5-cyclohexadiene, 1-(i-propylcarbonyl)-1-methoxymethyl-2,5-cyclohexadiene, 1-(butylcarbonyl)-1-methoxymethylcyclohexyl, 1-(i-butylcarbonyl)-1-methoxymethyl-2,5-cyclohexadiene, 1-(pentylcarbonyl)-1-methoxymethyl-2,5-cyclohexadiene, 1-(i-pentylcarbonyl)-1-methoxymethyl-2,5-cyclohexadiene, 1-(neopentylcarbonyl)-1-methoxymethyl-2,5-cyclohexadiene, 1-(hexylcarbonyl)-1-methoxymethyl-2,5-cyclohexadiene, 1-(2-ethylhexylcarbonyl)-1-methoxymethyl-2,5-cyclohexadiene, 1-(octylcarbonyl)-1-methoxymethyl-2,5-cyclohexadiene, 1-(i-octylcarbonyl)-1-methoxymethyl-2,5-cyclohexadiene, 1-(i-nonylcarbonyl)-1-methoxymethyl-2,5-cyclohexadiene, 1-(ethylcarbonyl)-1-methoxymethyl-2-methyl-2,5-cyclohexadiene, 1-(propylcarbonyl)-1-methoxymethyl-2-methyl-2,5-cyclohexadiene, 1-(i-propanecarbonyl)-1-methoxymethyl-2-methyl-2,5-cyclohexadiene, 1-(butylcarbonyl)-1-methoxymethyl-2-methyl-2,5-cyclohexadiene, 1-(i-butylcarbonyl)-1-methoxymethyl-2-methyl-2,5-cyclohexadiene, 1-(pentylcarbonyl)-1-methoxymethyl-2-methyl-2,5-cyclohexadiene, 1-(i-pentylcarbonyl)-1-methoxymethyl-2-methyl-2,5-cyclohexadiene, 1-(neopentylcarbonyl)-1-methoxymethyl-2-methyl-2,5-cyclohexadiene, 1-(hexylcarbonyl)-1-methoxymethyl-2-methyl-2,5-cyclohexadiene, 1-(2-ethylhexylcarbonyl)-1-methoxymethyl-2-methyl-2,5-cyclohexadiene, 1-(octylcarbonyl)-1-methoxymethyl-2-methyl-2,5-cyclohexadiene, 1-(i-octylcarbonyl)-1-methoxymethyl-2-methyl-2,5-cyclohexadiene, 1-(i-nonylcarbonyl)-1-methoxymethyl-2-methyl-2,5-cyclohexadiene, 1-(ethylcarbonyl)-1-methoxymethyl-2,6-dimethyl-2,5-cyclohexadiene, 1-(propylcarbonyl)-1-methoxymethyl-2,6-dimethyl-2,5-cyclohexadiene, 1-(i-propylcarbonyl)-1-methoxymethyl-2,6-dimethyl-2,5-cyclohexadiene, 1-(butylcarbonyl)-1-methoxymethyl-2,6-dimethyl-2,5-cyclohexadiene, 1-(i-butylcarbonyl)-1-methoxymethyl-2,6-dimethyl-2,5-cyclohexadiene, 1-(pentylcarbonyl)-1-methoxymethyl-2,6-dimethyl-2,5-cyclohexadiene, 1-(i-pentylcarbonyl)-1-methoxymethyl-2,6-dimethyl-2,5-cyclohexadiene, 1-(neopentylcarbonyl)-1-methoxymethyl-2,6-dimethyl-2,5-cyclohexadiene, 1-(hexylcarbonyl)-1-methoxymethyl-2,6-dimethyl-2,5-cyclohexadiene, 1-(2-ethylhexylcarbonyl)-1-methoxymethyl-2,6-dimethyl-2,5-cyclohexadiene, 1-(octylcarbonyl)-1-methoxymethyl-2,6-dimethyl-2,5-cyclohexadiene, 1-(i-octylcarbonyl)-1-methoxymethyl-2,6-dimethyl-2,5-cyclohexadiene, 1-(i-nonylcarbonyl)-1-methoxymethyl-2,6-dimethyl-2,5-cyclohexadiene, 2,5-dimethyl-3-ethylcarbonyl-3′-methoxymethylpentane, 2,5-dimethyl-3-propylcarbonyl-3′-methoxymethylpentane, 2,5-dimethyl-3-i-propylcarbonyl-3′-methoxymethylpentane, 2,5-dimethyl-3-butylcarbonyl-3′-methoxymethylpentane, 2,5-dimethyl-3-i-butylcarbonyl-1-methoxymethylcyclohexyl, 4-isopropyl-4-(methoxymethyl)-7-methyloctan-3-one, 5-isopropyl-5-(methoxymethyl)-2,8-dimethylnonan-4-one, 5-isopropyl-5-(methoxymethyl)-8-methylnonan-4-one, 6-isopropyl-6-(methoxymethyl)-9-methyldecan-5-one, 5-isopropyl-5-(methoxymethyl)-2-methylundecan-6-one, 5-isopropyl-5-(methoxymethyl)-2-methyldodecan-6-one, 5-isopropyl-5-(methoxymethyl)-2-methyltridecan-6-one, 4-isopentyl-4-(methoxymethyl)-7-methyloctan-3-one, 5-isopentyl-5-(methoxymethyl)-8-methylnonan-4-one, 6-isopentyl-6-(methoxymethyl)-9-methyldecan-5-one, 5-isopentyl-5-(methoxymethyl)-2-methylundecan-6-one, 5-isopentyl-5-(methoxymethyl)-2-methyldodecan-6-one, 5-isopentyl-5-(methoxymethyl)-2-methyltridecan-6-one, 4-isobutyl-4-(methoxymethyl)-6-methylheptan-3-one, 5-isobutyl-5-(methoxymethyl)-7-methyloctan-4-one, 4-isobutyl-4-(methoxymethyl)-2-methylnonan-5-one, 4-isobutyl-4-(methoxymethyl)-2-methyldecan-5-one, and 4-isobutyl-4-(methoxymethyl)-2-methylundecan-5-one, and mixtures thereof.

7. The catalyst system of claim 1 , wherein the second internal electron donor has a structure:

wherein R 5 through R 10 , independently, are hydrogen, halogen, C 1 -C 6 linear or branched alkyl, C 6 -C 10 cycloalkyl, phenyl, C 1 -C 3 alkylenearyl, arylene C 1 -C 6 alkyl; and R 11 and R 12 , independently, are C 1 -C 20 linear or branched alkyl, C 5 -C 10 cycloalkyl, C 5 -C 10 cycloalkenyl, C 5 -C 10 cycloalkadienyl, phenyl, C 1 -C 3 alkylenearyl, or arylene C 1 -C 6 alkyl.

8. The catalyst system of claim 1 , wherein the second internal electron donor is selected from the group consisting of a naphthalene-1,8-diyl dicycloalkanecarboxylate derivative, a naphthalene-1,8-diyl dicycloalkenecarboxylate derivative, an 8-(cycloalkanecarbonyloxy)naphthalene-1-yl benzoate derivative, an 8-(cycloalkenecarbonyloxy)naphthalene-1-yl benzoate derivative, a 1,8-naphthyl diaryloate derivatives, and mixtures thereof.

9. The catalyst system of claim 1 , wherein the second internal electron donor is selected from the group consisting of naphthalene-1,8-diyl dicyclohexanecarboxylate, naphthalene-1,8-diyl di-2-methylcyclohexanecarboxylate, naphthalene-1,8-diyl di-3-methylcyclohexanecarboxylate, and naphthalene-1,8-diyl di-4-methylcyclohexanecarboxylate, naphthalene-1,8-diyl dicyclohex-1-enecarboxylate, naphthalene-1,8-diyl dicyclohex-2-enecarboxylate, naphthalene-1,8-diyl dicyclohex-3-enecarboxylate, 8-(cyclohexanecarbonyloxy)naphthalene-1-yl benzoate, 8-(2-methylcyclohexanecarbonyloxy)naphthalene-1-yl benzoate, 8-(3-methylcyclohexanecarbonyloxy)naphthalene-1-yl benzoate, 8-(4-methylcyclohexanecarbonyloxy)naphthalene-1-yl benzoate, 8-(2-methylcyclohexanecarbonyloxy)naphthalene-1-yl 2-methylbenzoate, 8-(3-methylcyclohexanecarbonyloxy)naphthalene-1-yl 2-methylbenzoate, 8-(4-methylcyclohexanecarbonyloxy)naphthalene-1-yl 2-methylbenzoate, 8-(2-methylcyclohexanecarbonyloxy)naphthalene-1-yl 3-methylbenzoate, 8-(3-methylcyclohexanecarbonyloxy)naphthalene-1-yl 3-methylbenzoate, 8-(4-methylcyclohexanecarbonyloxy)naphthalene-1-yl 3-methylbenzoate, 8-(2-methylcyclohexanecarbonyloxy)naphthalene-1-yl 4-methylbenzoate, 8-(3-methylcyclohexanecarbonyloxy)naphthalene-1-yl 4-methylbenzoate, and 8-(4-methylcyclohexanecarbonyloxy)naphthalene-1-yl 4-methylbenzoate, 8-(cyclohex-1-enecarbonyloxy)naphthalene-1-yl benzoate, 8-(cyclohex-2-enecarbonyloxy)naphthalene-1-yl benzoate, 8-(cyclohex-3-enecarbonyloxy)naphthalene-1-yl benzoate, 8-(cyclohex-1-enecarbonyloxy)naphthalene-1-yl 2-methylbenzoate, 8-(cyclohex-2-enecarbonyloxy)naphthalene-1-yl 2-methylbenzoate, 8-(cyclohex-3-enecarbonyloxy)naphthalene-1-yl 2-methylbenzoate, 8-(cyclohex-1-enecarbonyloxy)naphthalene-1-yl 3-methylbenzoate, 8-(cyclohex-2-enecarbonyloxy)naphthalene-1-yl 3-methylbenzoate, 8-(cyclohex-3-enecarbonyloxy)naphthalene-1-yl 3-methylbenzoate, 8-(cyclohex-1-enecarbonyloxy)naphthalene-1-yl 4-methylbenzoate, 8-(cyclohex-2-enecarbonyloxy)naphthalene-1-yl 4-methylbenzoate, 8-(cyclohex-3-enecarbonyloxy)naphthalene-1-yl 4-methylbenzoate, 8-(2-methylcyclohex-1-enecarbonyloxy)naphthalene-1-yl benzoate, 8-(2-methylcyclohex-2-enecarbonyloxy)naphthalene-1-yl benzoate, 8-(2-methylcyclohex-3-enecarbonyloxy)naphthalene-1-yl benzoate, 8-(2-methylcyclohex-1-enecarbonyloxy)naphthalene-1-yl 2-methylbenzoate, 8-(2-methylcyclohex-2-enecarbonyloxy)naphthalene-1-yl 2-methylbenzoate, 8-(2-methylcyclohex-3-enecarbonyloxy)naphthalene-1-yl 2-methylbenzoate, 8-(2-methylcyclohex-1-enecarbonyloxy)naphthalene-1-yl 3-methylbenzoate, 8-(2-methylcyclohex-2-enecarbonyloxy)naphthalene-1-yl 3-methylbenzoate, 8-(2-methylcyclohex-3-enecarbonyloxy)naphthalene-1-yl 3-methylbenzoate, 8-(2-methylcyclohex-1-enecarbonyloxy)naphthalene-1-yl 4-methylbenzoate, 8-(2-methylcyclohex-2-enecarbonyloxy)naphthalene-1-yl 4-methylbenzoate, 8-(2-methylcyclohex-3-enecarbonyloxy)naphthalene-1-yl 4-methylbenzoate, 8-(3-methylcyclohex-1-enecarbonyloxy)naphthalene-1-yl benzoate, 8-(3-methylcyclohex-2-enecarbonyloxy)naphthalene-1-yl benzoate, 8-(3-methylcyclohex-3-enecarbonyloxy)naphthalene-1-yl benzoate, 8-(3-methylcyclohex-1-enecarbonyloxy)naphthalene-1-yl 2-methylbenzoate, 8-(3-methylcyclohex-2-enecarbonyloxy)naphthalene-1-yl 2-methylbenzoate, 8-(3-methylcyclohex-3-enecarbonyloxy)naphthalene-1-yl 2-methylbenzoate, 8-(3-methylcyclohex-1-enecarbonyloxy)naphthalene-1-yl 3-methylbenzoate, 8-(3-methylcyclohex-2-enecarbonyloxy)naphthalene-1-yl 3-methylbenzoate, 8-(3-methylcyclohex-3-enecarbonyloxy)naphthalene-1-yl 3-methylbenzoate, 8-(3-methylcyclohex-1-enecarbonyloxy)naphthalene-1-yl 4-methylbenzoate, 8-(3-methylcyclohex-2-enecarbonyloxy)naphthalene-1-yl 4-methylbenzoate, 8-(3-methylcyclohex-3-enecarbonyloxy)naphthalene-1-yl 4-methylbenzoate, 8-(4-methylcyclohex-1-enecarbonyloxy)naphthalene-1-yl benzoate, 8-(4-methylcyclohex-2-enecarbonyloxy)naphthalene-1-yl benzoate, 8-(4-methylcyclohex-3-enecarbonyloxy)naphthalene-1-yl benzoate, 8-(4-methylcyclohex-1-enecarbonyloxy)naphthalene-1-yl 2-methylbenzoate, 8-(4-methylcyclohex-2-enecarbonyloxy)naphthalene-1-yl 2-methylbenzoate, 8-(4-methylcyclohex-3-enecarbonyloxy)naphthalene-1-yl 2-methylbenzoate, 8-(4-methylcyclohex-1-enecarbonyloxy)naphthalene-1-yl 3-methylbenzoate, 8-(4-methylcyclohex-2-enecarbonyloxy)naphthalene-1-yl 3-methylbenzoate, 8-(4-methylcyclohex-3-enecarbonyloxy)naphthalene-1-yl 3-methylbenzoate, 8-(4-methylcyclohex-1-enecarbonyloxy)naphthalene-1-yl 4-methylbenzoate, 8-(4-methylcyclohex-2-enecarbonyloxy)naphthalene-1-yl 4-methylbenzoate, 8-(4-methylcyclohex-3-enecarbonyloxy)naphthalene-1-yl 4-methylbenzoate, and mixtures thereof.

10. The catalyst system of claim 7 , wherein the second internal electron donor has a structure:

wherein R 13 through R 22 , independently, are hydrogen, halogen, C 1 -C 6 linear or branched alkyl, C 5 -C 10 cycloalkyl, C 1 -C 6 linear or branched alkoxyl, aryl, C 7 -C 10 arylalkyl, C 1 -C 6 alkylenearyl, or arylene C 1 -C 6 alkyl.

11. The catalyst system of claim 10 , wherein the second internal electron donor is selected from the group consisting of a 1,8-naphthyl di(alkylbenzoate), a 1,8-naphthyl di(dialkylbenzoate), a 1,8-naphthyl di(trialkylbenzoate), a 1,8-naphthyl di(arylbenzoate), a 1,8-naphthyl di(halobenzoate), a 1,8-napthyl di(dihalobenzoate), a 1,8-naphthyl di(alkylhalobenzoate), and mixtures thereof.

12. The catalyst system of claim 10 , wherein the second internal electron donor is selected from the group consisting of 1,8-naphthyl dibenzoate; 1,8-naphthyl di-4-methylbenzoate; 1,8-naphthyl di-3-methylbenzoate; 1,8-naphthyl di-2-methylbenzoate; 1,8-naphthyl di-4-ethylbenzoate; 1,8-naphthyl di-4-n-propylbenzoate; 1,8-naphthyl di-4-isopropylbenzoate; 1,8-naphthyl di-4-n-butylbenzoate; 1,8-naphthyl di-4-isobutylbenzoate; 1,8-naphthyl di-4-t-butylbenzoate; 1,8-naphthyl di-4-phenylbenzoate; 1,8-naphthyl di-4-fluorobenzoate; 1,8-naphthyl di-3-fluorobenzoate; 1,8-naphthyl di-2-fluorobenzoate; 1,8-naphthyl di-4-chlorobenzoate; 1,8-naphthyl di-3-chlorobenzoate; 1,8-naphthyl di-2-chlorobenzoate; 1,8-naphthyl di-4-bromobenzoate; 1,8-naphthyl di-3-bromobenzoate; 1,8-naphthyl di-2-bromobenzoate; 1,8-naphthyl di-4-cyclohexylbenzoate; 1,8-naphthyl di-2,3-dimethylbenzoate; 1,8-naphthyl di-2,4-dimethylbenzoate; 1,8-naphthyl di-2,5-dimethylbenzoate; 1,8-naphthyl di-2,6-dimethylbenzoate; 1,8-naphthyl di-3,4-dimethylbenzoate; 1,8-naphthyl di-3,5-dimethylbenzoate; 1,8-naphthyl di-2,3-dichlorobenzoate; 1,8-naphthyl di-2,4-dichlorobenzoate; 1,8-naphthyl di-2,5-dichlorobenzoate; 1,8-naphthyl di-2,6-dichlorobenzoate; 1,8-naphthyl di-3,4-dichlorobenzoate; 1,8-naphthyl di-3,5-dichlorobenzoate; 1,8-naphthyl di-3,5-di-t-butylbenzoate; and mixtures thereof.

13. The catalyst system of claim 1 , wherein the solid catalyst component further comprises one or more additional internal electron donor compound.

14. The catalyst system of claim 1 , wherein the first internal electron donor compound and the second internal electron donor compound are supported on a magnesium halide crystal lattice.

15. The catalyst system of claim 1 , wherein the titanium halide is TiCl 4 or TiCl 3 .

16. The catalyst system of claim 1 , wherein the titanium halide has a general formula TiX n (OR) 4-n , wherein R is a hydrocarbon radical having 1 to about 20 carbon atoms, X is a halogen, and n is from 1 to 4.

17. The catalyst system of claim 1 , wherein the external electron donor compound comprises an alkyl benzoate, an organosilicon compound, or both.

18. The catalyst system of claim 1 , wherein the organoaluminum compound is an alkyl-aluminum compound.

19. The catalyst system of claim 18 , wherein the organoaluminum compound is a trialkyl aluminum compound.

20. The catalyst system of claim 19 , wherein the trialkyl aluminum compound is selected from the group consisting of triethylaluminum, triisobutylaluminum, tri-n-octylaluminum, and mixtures thereof.

21. A solid catalyst component for a polymerization of an olefin comprising

(i) a titanium halide;

(ii) a magnesium halide;

(iii) a first internal electron donor compound comprising at least one ether group and at least one ketone group; and

(iv) a second electron donor compound having a 1,8-naphthyl diester structure.

22. A process for polymerizing or copolymerizing an olefin comprising

(i) providing a catalyst system of claim 1 ;

(ii) polymerizing or copolymerizing the olefin in a presence of the catalyst system to form a polymer or a copolymer; and

(iii) recovering the polymer or the copolymer.

23. The process of claim 22 , wherein the olefin is selected from the group consisting of ethylene, propylene, 1-butylene, 4-methyl-1-pentente, 1-hexene, 1-octene, and mixtures thereof.