Organic electroluminescence device and display unit
View Patent ↗An organic electroluminescence device having high light emitting efficiency and improved reliability is provided. The organic electroluminescence device includes: an anode containing at least aluminum (Al); a cathode; and an organic layer between the anode and the cathode, the organic layer including a light emitting layer. The organic layer has a hole injection layer composed of a sulfonic acid derivative between the anode and the light emitting layer.
1. An organic electroluminescence device comprising:
an anode containing at least aluminum;
a cathode; and
an organic layer between the anode and the cathode, the organic layer including a light emitting layer;
wherein,
the organic layer has a hole injection layer between the anode and the light emitting layer, and
the hole injection layer comprises a sulfonic acid derivative with at least a compound expressed in Formula 1:
where B1 represents a trivalent group containing a benzene ring, a naphthalene ring, an anthracene ring, a phenanthrene ring, or a heterocycle, and each of R1 and R2 represent a carboxyl group or a hydroxyl group.
2. The organic electroluminescence device according to claim 1 , wherein the sulfonic acid derivative contains a compound having a structure expressed in Formula 3, and a polymer compound having a structure expressed in Formula 4, Formulae 3 and 4 being:
where (a) Z2 represents an oxygen atom, a sulfur atom, or —NH—, (b) B3 represents a (n 2 +2) valence group containing a naphthalene ring or an anthracene ring, (c) R4 represents a hydrocarbon group, a group containing a 1,3,5-triazine ring, a group having the structure indicated in Formula 5, a group having the structure indicated in Formula 6, or a derivative of the foregoing groups, (d) b is an integer that is 1 or greater, and (e) n 2 is an integer that is from 1 to 4, both inclusive
where i represents an integer that is 1 or greater,
Formulas 5 and 6 being
and
where each of Z3 and Z4 represent an oxygen atom, a sulfur atom, a sulfinyl group (—S(═O)—), a sulfonyl group (—S(═O) 2 —), or a group containing any of a nitrogen atom, a silicon atom, a phosphorus atom, or a P(═O) group.
3. The organic electroluminescence device according to claim 1 , wherein the hole injection layer is formed by a coating method.
4. The organic electroluminescence device according to claim 1 , wherein a thickness of the hole injection layer is from 5 nm to 50 nm, both inclusive.
5. The organic electroluminescence device according to claim 1 , wherein the anode has light reflectance and the cathode has light transmittance, and light emitted from the light emitting layer is emitted from the cathode side.
6. The organic electroluminescence device according to claim 4 , wherein the anode contains aluminum as a main component and an element having a lower work function than that of aluminum as an accessory component.
7. A display unit comprising:
an organic electroluminescence device including (a) an anode containing at least aluminum, (b) a cathode, and (c) an organic layer between the anode and the cathode,
wherein,
the organic layer includes a light emitting layer,
the organic layer includes a hole injection layer between the anode and the light emitting layer, and
the hole injection layer comprises a sulfonic acid derivative with a compound expressed in Formula 1:
where B1 represents a trivalent group containing a benzene ring, a naphthalene ring, an anthracene ring, a phenanthrene ring, or a heterocycle, and each of R1 and R2 represent a carboxyl group or a hydroxyl group.
8. The display unit according to claim 7 , wherein the sulfonic acid derivative contains a compound having a structure expressed in Formula 3, and a polymer compound having a structure expressed in Formula 4, Formulas 3 through 4 being:
where (a) Z2 represents an oxygen atom, a sulfur atom, or —NH—, (b) B3 represents a (n 2 +2) valence group containing a naphthalene ring or an anthracene ring, (c) R4 represents a hydrocarbon group, a group containing a 1,3,5-triazine ring, a group having the structure indicated in Formula 5, a group having the structure indicated in Formula 6, or a derivative of the foregoing groups, (d) b is an integer that is 1 or greater, (e) n 2 is an integer that is from 1 to 4, both inclusive,
where i is an integer that is 1 or greater, Formulas 5 and 6 being:
and
where each Z3 and Z4 represent an oxygen atom, a sulfur atom, a sulfinyl group (—S(═O)—), a sulfonyl group (—S(═O) 2 —), or a group containing any of a nitrogen atom, a silicon atom, a phosphorus atom, or a P(═O) group.
9. The display unit according to claim 7 , wherein the hole injection layer is formed by a coating method.
10. The display unit according to claim 7 , wherein a thickness of the hole injection layer is from 5 nm to 50 nm, both inclusive.
11. The display unit according to claim 7 , wherein the anode has light reflectance and the cathode has light transmittance, and light emitted from the light emitting layer is emitted from the cathode side.
12. The display unit according to claim 7 , wherein the anode contains aluminum as a main component and an element having a lower work function than that of aluminum as an accessory component.