Crystalline resin sandwich films
View Patent ↗A resin composition that is storable at ambient temperatures. The resin composition forms a cured resin when exposed to a curing agent and heated to a curing temperature that is relatively close to ambient temperature. The resin composition includes a crystalline resin component that is sandwiched between two non-crystalline resin components to provide a zone that is rich in crystalline thermosetting resin. The crystalline thermosetting resin has a melting point that is above ambient temperature, but below the curing temperature. The viscosity of the resin component changes from a high viscosity state to a low viscosity state when the temperature is increased from ambient temperature to the curing temperature.
1. An uncured structure that is suitable for storage at ambient temperatures, said uncured structure comprising:
a) a resin composition wherein said resin composition forms a cured resin when exposed to a curing agent and heated to a curing temperature that is higher than said ambient temperature, said resin composition comprising:
a first non-crystalline component, said non-crystalline component including one or more non-crystalline thermosetting resins;
a second non-crystalline component, said non-crystalline component including one or more non-crystalline thermosetting resins; and
a crystalline component that comprises one or more crystalline thermosetting resins wherein said crystalline component is located between said first and second non-crystalline components to provide a zone that is rich in said one or more crystalline thermosetting resins and wherein said one or more crystalline thermosetting resins has a melting point that is above said ambient temperature and below said curing temperature and wherein the viscosity of said resin composition changes from a high viscosity state to a low viscosity state when the temperature of said resin composition is increased from said ambient temperature to said curing temperature; and
b) a curative component comprising a curing agent for said resin composition; and
c) a removable barrier located between said resin composition and said curing agent during storage of said uncured structure at said ambient temperatures.
2. An uncured structure according to claim 1 wherein said resin composition and said curing component are in the form of layers that are separated by said removable barrier.
3. An uncured structure according to claim 1 wherein said crystalline component comprises particles of one or more crystalline thermosetting resins.
4. An uncured structure according to claim 2 wherein said crystalline component is in the form of a film that comprises said one or more crystalline thermosetting resins.
5. An uncured structure according to claim 2 wherein said first and/or second non-crystalline components comprise a plurality of fibers.
6. An uncured structure according to claim 2 wherein said crystalline component comprises a plurality of fibers.
7. An uncured structure according to claim 5 wherein said crystalline component comprises a plurality of fibers.
8. An uncured structure according to claim 1 wherein said removable barrier comprises a polymeric film.
9. An uncured structure according to claim 2 wherein said removable barrier comprises a polymeric film.
10. A method for forming an uncured structure that is suitable for storage at ambient temperatures, said method comprising the steps of:
a) providing a resin composition wherein said resin composition forms a cured resin when exposed to a curing agent and heated to a curing temperature that is higher than said ambient temperature, said resin composition comprising:
a first non-crystalline component, said non-crystalline component including one or more non-crystalline thermosetting resins;
a second non-crystalline component, said non-crystalline component including one or more non-crystalline thermosetting resins; and
a crystalline component that comprises one or more crystalline thermosetting resins wherein said crystalline component is located between said first and second non-crystalline components to provide a zone that is rich in said one or more crystalline thermosetting resins and wherein said one or more crystalline thermosetting resins has a melting point that is above said ambient temperature and below said curing temperature and wherein the viscosity of said resin composition changes from a high viscosity state to a low viscosity state when the temperature of said resin composition is increased from said ambient temperature to said curing temperature;
b) providing a curative component comprising a curing agent for said resin composition; and
c) providing a removable barrier to separate said curative component from said resin composition during storage of said uncured structure at ambient temperatures.
11. A method for forming an uncured structure according to claim 10 wherein said resin composition and said curing component are provided in the form of layers that are separated by said removable barrier.
12. A method for forming an uncured structure according to claim 10 wherein said crystalline component comprises particles of one or more crystalline thermosetting resins.
13. A method for forming an uncured structure according to claim 11 wherein said crystalline component is in the form of a film that comprises said one or more crystalline thermosetting resins.
14. A method for forming an uncured structure according to claim 11 wherein said first and/or second non-crystalline components comprise a plurality of fibers.
15. A method for forming an uncured structure according to claim 11 wherein said crystalline component comprises a plurality of fibers.
16. A method for forming an uncured structure according to claim 14 wherein said crystalline component comprises a plurality of fibers.
17. A method for forming an uncured structure according to claim 10 wherein said removable barrier comprises a polymeric film.
18. A method for forming an uncured structure according to claim 11 wherein said removable barrier comprises a polymeric film.