Process for conversion of paraffinic feedstock
View Patent ↗The invention provides a process for converting a paraffinic feedstock comprising at least 50 wt % of compounds boiling above 370° C., a paraffin content of at least 60 wt %, an aromatics content below 1 wt %, a naphthenic content below 2 wt %, a nitrogen content below 0.1 wt %, and a sulphur content below 0.1 wt %, comprising: (a) reacting the feedstock with hydrogen at a temperature between 175 and 400° C. and a pressure between 20 and 100 bar using a catalyst comprising 0.005 to 5.0 wt % of a Group VIII noble metal on a carrier comprising 0.1-15 wt % zeolite beta and at least 40 wt % amorphous silica-alumina (b) withdrawing the effluent (c) subjecting the effluent to a fractionation step to form a heavy fraction, an intermediate fraction, and a light fraction; and (d) providing at least part of the heavy fraction to the reaction zone.
1. A process for the conversion of a paraffinic feedstock that comprises at least 50 wt % of compounds boiling above 370° C. wherein the weight ratio of compounds boiling above 540° C. and compounds boiling between 370 and 540° C. in the feedstock is at least 0.3:1 and which has a paraffin content of at least 60 wt %, an aromatics content of below 1 wt %, a naphthenic content below 2 wt %, a nitrogen content of below 0.1 wt %, and a sulphur content of below 0.1 wt %, which process comprises the steps of:
providing the feedstock to a reaction zone where it is contacted with hydrogen at a temperature in the range of 175 to 400° C. and a pressure in the range of 20 to 100 bar in the presence of a catalyst comprising 0.005 to 5.0 wt % of a Group VIII noble metal on a carrier, the carrier comprising 0.1-15 wt % of a zeolite beta and at least 40 wt % of an amorphous silica-alumina, calculated on the weight of the catalyst, said zeolite beta having a silica:alumina molar ratio of at least 50, and said amorphous silica-alumina having an alumina content, calculated as Al 2 O 3 , of 5-70 wt %;
withdrawing the effluent from the reaction zone through an outlet;
subjecting the effluent from the reaction zone to a fractionation step to form at least a heavy fraction, an intermediate fraction with a boiling range of 370-540° C., and a light fraction; and
providing at least part of the heavy fraction to the inlet of the reaction zone.
2. A process according to claim 1 , wherein the intermediate fraction is provided to a dewaxing zone.
3. A process according to claim 1 wherein the feedstock comprises at least 60 wt % compounds boiling above 370° C.
4. A process according to claim 1 wherein the Group VIII noble metal on the catalyst is selected from the group consisting of platinum, palladium, and mixtures thereof.
5. A process according to claim 1 wherein the zeolite beta in the catalyst is present in an amount of at least 0.5 wt % and in an amount of at most 10 wt %.
6. A process according to claim 1 wherein the zeolite beta in the catalyst has a silica:alumina molar ratio of at least 75 and at most 500, calculated as SiO 2 and Al 2 O 3 .
7. A process according to claim 2 wherein at least part of the intermediate fraction is provided to a catalytic dewaxing zone where it is contacted with a dewaxing catalyst and hydrogen.
8. A process according to claim 7 wherein the dewaxing catalyst comprises a molecular sieve in combination with a metal having a hydrogenation function.