Liquid crystal compound, polymerizable liquid crystal composition, optically anisotropic material, optical element and optical information writing/reading device
View Patent ↗A liquid crystal compound having a good durability against light, a polymerizable liquid crystal composition and an optically anisotropic material are provided. Further, an optical element having a good durability against light and an optical information writing/reading device employing such an element are provided. The liquid crystal compound is represented by a general formula CH 2 ═CR 1 —COO-(L) k -E 1 -E 2 -(E 3 ) m -R 2 . E 1 is preferably a trans-2,6-decahydronaphthalene group and E 2 is preferably a trans-1,4-cyclohexylene group. A phase difference plate 4 produced by employing the compound has a good durability against light, and accordingly, it is possible to achieve an optical head device employing a blue laser as a light source 1 and being suitable for large capacity writing/reading.
1. An optically anisotropic material which is obtained by photopolymerizing a polymerizable a liquid crystal compound represented by the following formula (1):
CH 2 ═CR 1 —COO-(L) k -E 1 -E 2 -(E 3 ) m -R 2 (1)
wherein R 1 is a hydrogen atom or a methyl group;
R 2 is a C 1-8 alkyl group or a fluorine atom, and when R 2 is an alkyl group, an etheric oxygen atom may be present in a carbon-carbon bond or at an end of the group to be bonded to a cyclic group, and a part or all of hydrogen atoms may be substituted by fluorine atoms;
K is 0 or 1;
L is —(CH 2 ) p COO—, —(CH 2 ) q OCO—, —(CH 2 ) r O— or —(CH 2 ) s —(wherein p, q, r and s are each independently an integer of from 1 to 8);
E 1 and E 2 are each independently a trans-1,4-cyclohexylene group or a trans -2,6-decahydronaphthalene group, and at least one of E 1 and E 2 is a trans-2,6-decahydronaphthalene group (wherein in the trans-1,4-cyclohexylene group and the trans -2,6-decahydronaphthalene group in E 1 and E 2 , hydrogen atoms bonded to carbon atoms in the groups may be each substituted by a fluorine atom or a methyl group);
E 3 is a trans-1,4-cyclohexylene group or a 1,4-phenylene group (wherein in the trans-1,4-cyclohexylene group and the 1,4-phenylene group in E 3 , hydrogen atoms bonded to carbon atoms in these groups may be each substituted by a fluorine atom or a methyl group); and
m is 0 or 1.
2. The optically anisotropic material according to claim 1 , wherein E 1 is a trans-2,6-decahydronaphthalene group, and
E 2 is a trans-1,4-cyclohexylene group.
3. The optically anisotropic material according to claim 2 , which is represented by the following formula (1A):
wherein R 1 is a hydrogen atom, and
R 2 is a C 2-6 linear alkyl group or a fluorine atom.
4. The optically anisotropic material according to claim 3 , wherein k is 1 and L is
—(CH 2 ) p COO— or (CH 2 ) q OCO—.
5. The optically anisotropic material according to claim 4 , wherein L is —(CH 2 ) p COO— wherein p is an integer of from 2 to 4.
6. The optically anisotropic material according to claim 3 , wherein k is 0.
7. An optical element having the optically anisotropic material as defined in claim 1 .
8. An optical information writing/reading device for recording an information in an optical recording medium and/or reading an information recorded in an optical recording medium, which has the optical element as defined in claim 7 .