Injection molded article with poly(arylene ether)-block copolymer composition
View Patent ↗An injection molded article, such as a washing machine top, exhibiting an improved balance of heat resistance, ductility, and absence of molding-related defects is formed from a poly(arylene ether)-block copolymer composition. The composition includes specific amounts of a poly(arylene ether) having particular molecular weight characteristics, a hydrogenated block copolymer, and an organophosphate ester flame retardant.
1. An injection molded article comprising a composition comprising:
about 79 to about 89 weight percent of a poly(arylene ether) having an intrinsic viscosity of 0.28 to 0.38 deciliter per gram, measured at 25° C. in chloroform; wherein the poly(arylene ether) consists of poly(2,6-dimethyl-1,4-phenylene ether) and comprises less than or equal to 6 weight percent, based on the weight of poly(arylene ether), of molecules having a molecular weight less than 5,000 atomic mass units and less than or equal to 30 weight percent, based on the weight of poly(arylene ether), of molecules having a molecular weight greater than 50,000 atomic mass units;
about 3 to about 8 weight percent of a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene; and
about 4 to about 15 weight percent of a flame retardant comprising an organophosphate ester;
wherein the composition comprises less than or equal to 0.5 weight percent of any polymer other than the poly(arylene ether) and the hydrogenated block copolymer; and
wherein all weight percents are based on the total weight of the composition unless a different weight basis is specified.
2. The injection molded article of claim 1 , wherein the poly(arylene ether) has a monomodal molecular weight distribution.
3. The injection molded article of claim 1 , wherein the hydrogenated block copolymer comprises a polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer having a weight average molecular weight of about 200,000 to about 400,000 atomic mass units.
4. The injection molded article of claim 3 , wherein the polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer has a polystyrene content of about 30 to about 35 weight percent.
5. The injection molded article of claim 1 , wherein the flame retardant consists of the organophosphate ester.
6. The injection molded article of claim 1 , wherein the composition comprises less than or equal to 0.1 weight percent of any polymer other than the poly(arylene ether) and the hydrogenated block copolymer.
7. The injection molded article of claim 1 ,
wherein the composition comprises about 81 to about 87 weight percent of the poly(arylene ether);
wherein the poly(arylene ether) has an intrinsic viscosity of 0.30 to 0.36 deciliter per gram, measured at 25° C. in chloroform;
wherein the composition comprises about 4 to about 7 weight percent of the hydrogenated block copolymer;
wherein the hydrogenated block copolymer comprises a polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer having a weight average molecular weight of about 200,000 to about 400,000 atomic mass units;
wherein the composition comprises about 5 to about 10 weight percent of the flame retardant; and
wherein the flame retardant comprises resorcinol bis(diphenyl phosphate), bisphenol A bis(diphenyl phosphate), or a mixture thereof.
8. The injection molded article of claim 1 , wherein the composition consists essentially of the poly(arylene ether), the hydrogenated block copolymer, the flame retardant, and, optionally, about 0.5 to about 5 weight percent of one or more additives selected from the group consisting of stabilizers, mold release agents, processing aids, drip retardants, nucleating agents, UV blockers, dyes, pigments, antioxidants, anti-static agents, blowing agents, mineral oil, metal deactivators, antiblocking agents, nanoclays, and electrically conductive agents.
9. The injection molded article of claim 1 , wherein a portion of the injection molded article comprises
a first dimension of at least 10 centimeters,
a second dimension of at least 10 centimeters, and
a third dimension of less than or equal to 1 centimeter.
10. The injection molded article of claim 1 , wherein the injection molded article is a washing machine top.
11. A composition comprising:
about 79 to about 89 weight percent of a poly(arylene ether) having an intrinsic viscosity of 0.28 to 0.38 deciliter per gram, measured at 25° C. in chloroform; wherein the poly(arylene ether) consists of poly(2,6-dimethyl-1,4-phenylene ether) and comprises less than or equal to 6 weight percent, based on the weight of poly(arylene ether), of molecules having a molecular weight less than 5,000 atomic mass units and less than or equal to 30 weight percent, based on the weight of poly(arylene ether), of molecules having a molecular weight greater than 50,000 atomic mass units;
about 3 to about 8 weight percent of a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene; and
about 4 to about 15 weight percent of a flame retardant comprising an organophosphate ester;
wherein the composition comprises less than or equal to 0.5 weight percent of any polymer other than the poly(arylene ether) and the hydrogenated block copolymer; and
wherein all weight percents are based on the total weight of the composition unless a different weight basis is specified.
12. The composition of claim 11 , wherein the poly(arylene ether) has a monomodal molecular weight distribution.
13. The composition of claim 11 , wherein the hydrogenated block copolymer comprises a polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer having a weight average molecular weight of about 200,000 to about 400,000 atomic mass units.
14. The composition of claim 13 , wherein the polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer has a polystyrene content of about 30 to about 35 weight percent.
15. The composition of claim 11 , wherein the flame retardant consists of the organophosphate ester.
16. The composition of claim 11 , wherein the composition comprises less than or equal to 0.1 weight percent of any polymer other than the poly(arylene ether) and the hydrogenated block copolymer.
17. The composition of claim 11 ,
wherein the composition comprises about 81 to about 87 weight percent of the poly(arylene ether);
wherein the poly(arylene ether) has an intrinsic viscosity of 0.30 to 0.36 deciliter per gram, measured at 25° C. in chloroform;
wherein the composition comprises about 4 to about 7 weight percent of the hydrogenated block copolymer;
wherein the hydrogenated block copolymer comprises a polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer having a weight average molecular weight of about 200,000 to about 400,000 atomic mass units;
wherein the composition comprises about 5 to about 10 weight percent of the flame retardant; and
wherein the flame retardant comprises resorcinol bis(diphenyl phosphate), bisphenol A bis(diphenyl phosphate), or a mixture thereof.
18. The composition of claim 11 , wherein the composition consists essentially of the poly(arylene ether), the hydrogenated block copolymer, the flame retardant, and, optionally, about 0.5 to about 5 weight percent of one or more additives selected from the group consisting of stabilizers, mold release agents, processing aids, drip retardants, nucleating agents, UV blockers, dyes, pigments, antioxidants, anti-static agents, blowing agents, mineral oil, metal deactivators, antiblocking agents, nanoclays, and electrically conductive agents.