IP Library Granted Patent US 8,302,774
Granted Patent B2
US 8,302,774 · App. 12/968,356 · Granted Nov 6, 2012

Stabilized glycerin-in-oil emulsions

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Quick Facts
Patent No.
US 8,302,774
App. No.
12/968,356
Granted
Nov 6, 2012
Kind
B2
Abstract

Compositions and methods are disclosed for stabilizing glycerin-in-oil emulsions, which can be used to significantly reduce thermal instability or instability over time compared to traditional cosmetics or topical formulations. The compositions comprise one or more oil-soluble rheological modifiers and optionally one or more emulsifiers in a glycerin-in-oil emulsion.

Claims (44)

1. A stabilized glycerin-in-oil emulsion comprising:

(i) a continuous phase comprising one or more topically-acceptable oils,

(ii) a discontinuous phase comprising glycerin as the major component, and

(iii) a combination of trihydroxystearin and 12-hydroxystearic acid in an amount suitable to provide a viscosity for the emulsion at room temperature between about 2000 centipoise and about 3 million centipoise:

wherein a weight ratio of trihydroxystearin to 12-hydroxystearic acid is not greater than about 5/1; and

wherein said emulsion has improved stability compared to an otherwise identical emulsion not containing trihydroxystearin and/or 12-hydroxystearic add.

2. An emulsion according to claim 1 , wherein said emulsion further comprises one or more emulsifiers in a total range from about 0.5% to about 6.0% by weight.

3. An emulsion according to claim 2 , wherein said trihydroxystearin is present in a range from about 0.5% to about 2.5% by weight, and said 12-hydroxystearic acid is present in a range from about 0.2% to about 1.5% by weight.

4. An emulsion according to claim 3 , wherein said emulsion is stable as an emulsion after heating to about 49° C. for two days.

5. An emulsion according to claim 3 , wherein said emulsion is stable as an emulsion after heating to about 49° C. for one week.

6. An emulsion according to claim 3 , wherein said emulsion is stable as an emulsion after heating to about 60° C. for twelve hours.

7. An emulsion according to claim 3 , wherein said emulsion is stable as an emulsion after heating to about 60° C. for one week.

8. An emulsion according to claim 1 , wherein said emulsion is essentially anhydrous.

9. A cosmetic composition comprising

(i) a stabilized glycerin-in-oil emulsion comprising:

(a) a continuous phase comprising one or more topically-acceptable oils,

(b) a discontinuous phase comprising glycerin as the major component, and

(c) a combination of trihydroxystearin and 12-hydroxystearic acid in an amount suitable to provide a viscosity for the emulsion at room temperature between about 2000 centipoise and about 3 million centipoise, wherein a weight ratio of trihydroxystearin to 12-hydroxystearic acid is not greater than about 5/1; and

(ii) optionally one or more components distributed in either or both phases of said emulsion, said components selected from the group consisting of pigments, waxes, emollients, moisturizers, preservatives, flavorants, antioxidants, botanicals, and mixtures thereof;

wherein said emulsion has improved stability compared to an otherwise identical emulsion not containing trihydroxystearin and/or 12-hydroxystearic acid.

10. A cosmetic composition according to claim 9 , wherein said cosmetic composition is suitable for application to the lips.

11. A lip product comprising:

(A) a cosmetic composition suitable for application to the lips comprising

(i) a stabilized glycerin-in-oil emulsion comprising:

(a) a continuous phase comprising one or more topically-acceptable oils,

(b) a discontinuous phase comprising glycerin as the major component, and

(c) a combination of trihydroxystearin and 12-hydroxystearic acid in an amount suitable to provide a viscosity for the emulsion at room temperature between about 2000 centipoise and about 3 million centipoise such that the emulsion has a suitable consistency to be squeezed from a tube, wherein a weight ratio of trihydroxystearin to 12-hydroxystearic acid is not greater than about 5/1; and

(ii) optionally one or more components distributed in either or both phases of said emulsion, said components selected from the group consisting of pigments, waxes, emollients, moisturizers, preservatives, flavorants, antioxidants, botanicals, and mixtures thereof;

wherein said emulsion has improved stability compared to an otherwise identical emulsion not containing trihydroxystearin and/or 12-hydroxystearic acid; and

(B) a re-closeable container having a chamber at least partially charged with said cosmetic composition and a cap reversibly attached to said container for sealing the contents of the chamber when in a dosed position and for permitting said contents to be dispensed when in an open position.

12. A lip product according to claim 11 , wherein

(i) said one or more topically-acceptable oils are present in a range from about 40% to about 90% by weight of said cosmetic composition,

(ii) said glycerin is present in a range from about 5% to about 60% by weight of said cosmetic composition,

(iii) said trihydroxystearin is present in a range from about 0.5% to about 2.5% by weight of said cosmetic composition, and

(iv) said 12-hydroxystearic acid is present in a range from about 0.2% to about 1.5% by weight of said cosmetic composition;

wherein said cosmetic composition further comprises:

(v) one or more emulsifiers in a total range from about 0.5 to about 6.0% by weight of said cosmetic composition.

13. A lip product according to claim 11 , wherein said lip product is selected from the group consisting of lip cream, lip balm, lip gloss, medicated lip treatment, lip moisturizer, lip cosmetic, lip sunscreen, and lip flavorant.

14. A stabilized glycerin-in-oil emulsion comprising:

(i) a continuous phase comprising one or more topically-acceptable oils; and

(ii) a discontinuous phase comprising glycerin as the major component;

wherein the emulsion exhibits an elastic modulus (G′)≧0 that is essentially temperature independent at temperatures between about 25° C. to about 60° C.; and

wherein the emulsion comprises a weight ratio of trihydroxystearin to 12-hydroxystearic acid that is not greater than about 5/1.

15. An emulsion according to claim 14 , wherein the emulsion exhibits an elastic modulus (G′) that is essentially temperature independent at temperatures between about 20° C. to about 80° C.

Assignments (8)
RELEASE OF SECURITY INTEREST Recorded Jan 28, 2026
From: NATURA &CO LUXEMBOURG HOLDINGS S.À R.L., AS A SECURED PARTY; NATURA &CO UK HOLDINGS LIMITED, AS A SECURED PARTY
To: AVON PRODUCTS, INC.
Reel/Frame 074508/0281 →
RELEASE OF SECURITY INTEREST Recorded Dec 11, 2024
From: NATURA &CO HOLDING S.A.; NATURA COSMETICOS S.A.; NATURA &CO LUXEMBOURG HOLDINGS S.A R.L. - LUXEMBOURG; NATURA &CO UK HOLDINGS LIMITED - UK
To: AVON PRODUCTS, INC
Reel/Frame 069591/0494 →
PATENT SECURITY AGREEMENT Recorded Aug 16, 2024
From: AVON PRODUCTS, INC.
To: NATURA &CO HOLDING S.A.; NATURA &CO LUXEMBOURG HOLDINGS S.À R.L.; NATURA COSMÉTICOS S.A.; NATURA &CO UK HOLDINGS LIMITED
Reel/Frame 068659/0915 →
SECURITY INTEREST Recorded Apr 29, 2024
From: AVON PRODUCTS, INC.; MI HOLDINGS, INC.; AVON INTERNATIONAL OPERATIONS, INC.; AVON CAPITAL CORPORATION; AVON COSMETICS LIMITED; AVON BEAUTY LIMITED
To: NATURA &CO HOLDING S.A., AS SECURED PARTY; NATURA &CO LUXEMBOURG HOLDINGS S.À R.L., AS A SECURED PARTY; NATURA COSMÉTICOS S.A., AS A SECURED PARTY
Reel/Frame 067249/0491 →
SECURITY INTEREST Recorded Aug 11, 2023
From: AVON PRODUCTS, INC.
To: NATURA &CO LUXEMBOURG HOLDINGS S.À R.L., AS A SECURED PARTY; NATURA &CO UK HOLDINGS LIMITED, AS A SECURED PARTY
Reel/Frame 064566/0872 →
SECURITY INTEREST Recorded Nov 14, 2019
From: AVON PRODUCTS, INC.
To: CITIBANK, N.A., LONDON BRANCH
Reel/Frame 051032/0210 →
RELEASE OF SECURITY INTEREST IN PATENTS Recorded Aug 15, 2016
From: CITIBANK, N.A.
To: AVON PRODUCTS, INC.
Reel/Frame 039690/0331 →
SECURITY INTEREST Recorded Jun 12, 2015
From: AVON PRODUCTS, INC.
To: CITIBANK, N.A.
Reel/Frame 035899/0776 →