Polycarbonate resin composition having excellent wear resistance and electric conductivity and method of preparing the same
The present invention provides a polycarbonate resin composition comprising a polycarbonate (A), a styrene copolymer resin (B), carbon nano-tubes (C) and a carbon black (D).
1. A polycarbonate resin composition comprising:
a base resin comprising about 70 to about 95% by weight of a (A) polycarbonate and about 30 to about 55% by weight of a (B) styrene copolymer resin including about 60 to about 90% by weight of styrene based monomer and about 10 to about 40% by weight of unsaturated-nitrile based monomer,
(C) about 0.01 to about 5 parts by weight of carbon nano-tubes, and
(D) about 1 to about 20 parts by weight of carbon black,
wherein the amounts of carbon nano-tubes (C) and carbon black (D) are based on 100 parts by weight of the base resin, and
wherein the carbon nano-tubes and the carbon black form a three dimensional network structure.
2. The polycarbonate resin composition of claim 1 , wherein the carbon nano-tubes include single wall carbon nano-tubes, double wall carbon nano-tubes, multi wall carbon nano-tubes, cup-stacked carbon nano-fibers shaped in a hollow form with an interior with multiple layers of truncated cone graphenes stacked therein and combinations thereof.
3. The polycarbonate resin composition of claim 1 , wherein the carbon black is conductive globular carbon black having a particle size of about 1 to about 100 nm.
4. The polycarbonate resin composition of claim 3 , wherein the carbon black is conductive globular carbon black without gaps between globular shapes.
5. The polycarbonate resin composition of claim 1 , wherein pellets formed of the same by extruding and molding the polycarbonate resin composition at a 280° C. injection temperature have a surface resistance of E+5 or less measured according to ASTM D257.
6. The polycarbonate resin composition of claim 5 , wherein pellets formed of the same by extruding and molding the polycarbonate resin composition at a 280° C. injection temperature have an abrasion loss of about 30 mg or less measured under conditions of 3 Kgf pressure, 1000 rpm, and 200° C. for 4 and a half hours.
7. A polycarbonate resin composition comprising:
a base resin comprising about 70 to about 95% by weight of a (A) polycarbonate and about 30 to about 55% by weight of a (B) styrene copolymer resin including about 60 to about 90% by weight of styrene based monomer and about 10 to about 40% by weight of unsaturated-nitrile based monomer,
(C) about 0.01 to about 5 parts by weight of carbon nano-tubes, and
(D) about 1 to about 20 parts by weight of carbon black,
wherein the amounts of carbon nano-tubes (C) and carbon black (D) are based on 100 parts by weight of the base resin,
wherein the carbon nano-tubes and the carbon black form a three dimensional network structure, and
wherein the carbon black is conductive globular carbon black having a particle size of about 1 to about 100 nm.