Stoichiometric lithium cobalt oxide and method for preparation of the same
View Patent ↗The present invention provides a LiCoO 2 -containing powder comprising LiCoO 2 having a stoichiometric composition via heat treatment of a lithium cobalt oxide and a lithium buffer material to make equilibrium of a lithium chemical potential there between; a lithium buffer material which acts as a Li acceptor or a Li donor to remove or supplement Li-excess or Li-deficiency, coexisting with a stoichiometric lithium metal oxide; and a method for preparing a LiCoO 2 -containing powder. Further, provided is an electrode comprising the above-mentioned LiCoO 2 -containing powder as an active material, and a rechargeable battery comprising the same electrode.
1. A LiCoO 2 -containing powder comprising:
a co-fired mixture containing a LiCoO 2 and a lithium buffer material,
wherein the lithium buffer material is a material of the Formula Li z MO 2 , wherein z is between 0.95 and 1.1; M is Ni 1-x-y Mn x Co y ; y is an amount of up to 0.5; and a ratio of (x/(1−x−y)) is in a range of 0.4 to 1.1,
wherein the LiCoO 2 has a stoichiometric composition having a Li:Co ratio of 1:1 via heat treatment of the LiCoO 2 and the lithium buffer material to make an equilibrium with respect to a lithium chemical potential there between,
wherein the lithium chemical potential of the LiCoO 2 is fixed, and the lithium chemical potential is higher than an equilibrium lithium chemical potential between the LiCoO 2 and a cobalt oxide and the lithium chemical potential is lower than an equilibrium lithium chemical potential between lithium cobalt oxide and Li 2 CO 3 .
2. The LiCoO 2 -containing powder according to claim 1 , wherein the lithium buffer material is a material that withdraws Li from Li 2 CO 3 , which is present in a Li-excess form of LiCoO 2 , or supplies Li to a cobalt oxide, which is present in a Li-deficient form of LiCoO 2 .
3. The LiCoO 2 -containing powder according to claim 1 , wherein the lithium buffer material is LiMn 1/3 Ni 1/3 CO 1/3 O 2 .
4. The LiCoO 2 -containing powder according to claim 1 , produced by a method comprising heat-treating at a heat treatment temperature which is lower than a temperature at which the LiCoO 2 and the lithium buffer material form a new compound.
5. The LiCoO 2 -containing powder according to claim 4 , wherein the heat treatment temperature is in the range of 400 to 1100° C.
6. The LiCoO 2 -containing powder according to claim 1 , wherein the content of lithium cobalt oxide is at least weight percent, based on the total weight of the LiCoO 2 -containing powder.
7. The LiCoO 2 -containing powder according to claim 1 , wherein the lithium cobalt oxide contacts the lithium buffer material.
8. The LiCoO 2 -containing powder according to claim 1 , further comprising a core-shell structure, wherein a core comprises the lithium cobalt oxide and a shell comprises the lithium buffer material.
9. The LiCoO 2 -containing powder according to claim 1 , which is prepared on the scale of at least 1 kg batch.
10. The LiCoO 2 -containing powder according to claim 1 , which is prepared on the scale of at least 20 kg batch.
11. A cathode active material for a rechargeable battery comprising the LiCoO 2 -containing powder according to claim.
12. An electrode comprising the powder of claim 1 .
13. A rechargeable battery comprising the electrode of claim 12 .
14. The LiCoO 2 -containing powder of claim 1 , wherein z is from 0.975 to 1.025.
15. A LiCoO 2 -containing powder comprising:
a co-fired mixture containing LiCoO 2 and a lithium buffer material,
wherein the LiCoO 2 -containing powder has a constant lithium chemical potential, wherein the LiCoO 2 coexists with the lithium buffer material under equilibrium conditions of lithium chemical potential there between and the LiCoO 2 has a stoichiometric composition having a Li:Co ratio of 1:1 via heat treatment, and the lithium chemical potential is higher than an equilibrium lithium chemical potential between LiCoO 2 and a cobalt oxide and the lithium chemical potential is lower than an equilibrium lithium chemical potential between LiCoO 2 and Li 2 CO 3 ,
wherein the lithium buffer material is a material of the Formula Li z MO 2 , wherein z is between 0.95 and 1.1; M is Ni 1-x-y Mn x Co y ; y is an amount of up to 0.5; and a ratio of (x/(1-x-y)) is in a range of 0.4 to 1.1.
16. The LiCoO 2 -containing powder of claim 15 , wherein z is from 0.975 to 1.025.
17. A method for preparing the LiCoO 2 -containing powder of claim 1 , comprising a step of providing a homogeneous mixture of LiCoO 2 and a lithium buffer material; and a step of heating the mixture to achieve equilibration of a lithium chemical potential.
18. The method according to claim 17 , wherein the homogeneous mixture has a core-shell structure that the lithium buffer material covers the surface of LiCoO 2 .
19. The method according to claim 17 , wherein the heat treatment temperature is lower than the temperature at which the reaction between the LiCoO 2 and the lithium buffer material takes place to form a new compound.
20. The method according to claim 17 , wherein the heat treatment temperature is in the range of 400 to 1100° C.