Isoolefin-diolefin production process and apparatus therefore
View Patent ↗In an isoolefin-diolefin rubber production process (e.g. a butyl rubber production process), the cold rubber slurry produced in the reaction vessel is transported from the reaction vessel to the flash tank during which time the cold slurry may be expressed to separate at least part of the cold liquid reaction medium from the isoolefin-diolefin rubber. The separated cold liquid reaction medium is transported off stream, for example by a mechanical filter, where it can be recycled back into the reaction vessel and/or where it can be used to cool a feed stream or streams of the reaction components. The isoolefin-diolefin rubber and the residual liquid reaction medium are transported to a flash tank for further processing. The ability to separate and recycle cold liquid reaction medium makes the process more economical. In one aspect, the slurry may be transported from the reaction vessel to the flash tank by a self-cleaning fully intermeshing co-rotating twin screw extruder, which helps overcome the problem of plugging due to rubber sticking to the surfaces of the slurry transfer apparatus.
1. An apparatus for producing an isoolefin-diolefin rubber comprising:
(a) a reaction vessel comprising an impeller for preparing a slurry of an isoolefin-diolefin rubber in a liquid non-aqueous reaction medium at a temperature in a range of from −110° C. to −50° C., said reaction vessel having an outlet;
(b) an expression separator in fluid communication with the outlet of the reaction vessel for separating at least part of the liquid non-aqueous reaction medium in the liquid form from the rubber;
(c) a slurry processing vessel in fluid communication with the expression separator for receiving residual slurry; and,
(d) a conduit in fluid communication with the expression separator at one or more points between the reaction vessel and the slurry processing vessel for transporting the liquid non-aqueous reaction medium separated in liquid form from the rubber by the expression separator out of the expression separator and away from the reaction vessel.
2. The apparatus according to claim 1 , wherein the conduit further comprises a mechanical filter in fluid communication with the expression separator for further separating the at least part of the liquid reaction medium from the rubber.
3. The apparatus according to claim 2 , wherein the mechanical filter is a fully intermeshing counter-rotating twin screw extruder.
4. The apparatus according to claim 1 , wherein at least part of the separated liquid reaction medium is recycled into the reaction vessel.
5. The apparatus according to claim 1 , wherein the conduit further comprises a heat exchanger for receiving and cooling at least part of the liquid reaction medium.
6. The apparatus according to claim 1 , wherein the expression separator is a fully intermeshing co-rotating twin screw extruder.
7. The apparatus according to claim 1 , wherein the slurry processing vessel is a flash tank.
8. An apparatus for producing an isoolefin-diolefin rubber comprising:
(a) a reaction vessel comprising an impeller for preparing a slurry of an isoolefin-diolefin rubber in a liquid non-aqueous reaction medium at a temperature in a range of from −110° C. to −50° C. said reaction vessel having an outlet;
(b) a self-cleaning fully intermeshing twin screw conveyor in fluid communication with the outlet of the reaction vessel for transferring the rubber from the reaction vessel to a slurry processing vessel; and
(c) a conduit in fluid communication with the twin screw conveyor at one or more points between the reaction vessel and the slurry processing vessel for transporting the liquid non-aqueous reaction medium separated from the slurry away from the reaction vessel.
9. The apparatus according to claim 8 , wherein the conveyor is a self-cleaning fully intermeshing co-rotating twin screw extruder.
10. The apparatus according to claim 8 , wherein the slurry processing vessel is a flash tank.