Phosphor in polycrystalline ceramic structure and a light-emitting element comprisng same
View Patent ↗The invention relates to a phosphor in a polycrystalline ceramic structure and a light-emitting element provided with the same comprising a Light-Emitting Diode (LED) in which a composite structure of phosphor particles is embedded in a matrix, characterized in that the matrix is a ceramic composite structure comprising a polycrystalline ceramic alumina material, hereafter called luminescent ceramic matrix composite. This luminescent ceramic matrix composite can be made by the steps of converting a powder mixture of ceramic phosphor particles and alumina particles into a slurry, shaping the slurry into a compact, and applying a thermal treatment, optionally in combination with hot isostatic pressing into a polycrystalline phosphor-containing ceramic alumina composite structure. The luminescent ceramic matrix composite further allows a method of tuning the light-diffusing properties by changing at least one of the fractions of phosphor particles and second ceramic particles, the grain size of the particles of the ceramic composite structure, the difference in the refractive index of the particles of the ceramic composite structure, and the porosity in the polycrystalline phosphor-containing ceramic composite structure.
1. A method of producing a ceramic structure, the method comprising:
making a polycrystalline ceramic structure comprising a phosphor embedded in a ceramic matrix comprising non-luminescent polycrystalline alumina, wherein the phosphor comprises (Lu 1-x-y-a-b Y x Gd y ) 3 (Al 1-z Ga z ) 5 O 12 :Ce a Pr b wherein 0<x≦1; 0≦y<1; 0≦z≦0.1; 0≦a≦0.2; 0≦b ≦0.1; and a+b>0 , the ceramic matrix comprises 80 to 99.99 vol. % alumina and 0.01 to 20 vol. % phosphor, and making a polycrystalline ceramic structure comprises:
converting a powder of phosphor and alumina particles into a slurry,
shaping the slurry into a polycrystalline phosphor-containing ceramic alumina composite structure, and
applying a thermal treatment.
2. The method of producing a ceramic structure according to claim 1 , wherein the slurry is shaped into a polycrystalline phosphor-containing ceramic alumina composite structure by means of slip casting or injection molding so as to obtain a ceramic light-converting package, a collimating lens or collimating reflector, a coupling-out structure for light, or a heat-dissipating device.
3. The method of producing a ceramic structure of claim 1 further comprising tuning light-diffusing properties of the polycrystalline ceramic structure by selecting, prior to making the polycrystalline ceramic structure, the average particle size of the particles in the polycrystalline ceramic structure, wherein the average particle size of the particles in the polycrystalline ceramic structure is between 0.3 and 50 μm.
4. The method of producing a ceramic structure of claim 1 further comprising tuning light-diffusing properties of the polycrystalline ceramic structure by selecting, prior to making the polycrystalline ceramic structure, the porosity of the polycrystalline ceramic structure, wherein the porosity of the polycrystalline ceramic structure is no more than 1%.
5. The method of producing a ceramic structure of claim 1 wherein applying a thermal treatment is combined with hot isostatic pressing into the ceramic matrix.
6. A method of producing a light emitting element, the method comprising:
making a polycrystalline ceramic structure comprising a phosphor embedded in a ceramic matrix comprising non-luminescent polycrystalline alumina, wherein the phosphor comprises (Lu 1-x-y-a-b Y x Gd y ) 3 (Al l-z Ga z ) 5 O 12 :Ce a Pr b wherein 0<x≦1; 0≦y<1; 0≦z≦0.1; 0≦a≦0.2; 0≦b≦0.1; and a+b>0, the ceramic matrix comprises 80 to 99.99 vol. % alumina and 0.01 to 20 vol. % phosphor, and making a polycrystalline ceramic structure comprises:
converting a powder of phosphor and alumina particles into a slurry,
shaping the slurry into a polycrystalline phosphor-containing ceramic alumina composite structure, and
applying a thermal treatment; and
mounting the polycrystalline ceramic structure on a LED.