Cosmetic powder bead compositions
View Patent ↗Provided herein are beads comprising at least one structuring agent and least one powder, and a novel process for making same. In one aspect, the process includes solubilzing at least one structuring agent with a solvent in the presence of at least one powder under turbulent high shear mixing to form small, nonspherical nucleated seeds of about 3 mm or less in diameter, and thereafter allowing the nucleated seeds to accrete under laminar low shear mixing to obtain substantially spherical beads of a desired size.
1. A method of preparing powder beads, comprising:
solubilizing at least one structuring agent with a solvent in the presence of at least one powder under turbulent high shear mixing at a tip speed of greater than about 15 ft/s to form small, nonspherical nucleated seeds of about 3 mm or less in diameter, and
thereafter allowing the nucleated seeds to accrete under laminar low shear mixing at a tip speed of less than about 15 ft/s to obtain substantially spherical beads having a diameter of about 3 mm to about 30 mm.
2. The method of claim 1 , further comprising drying the beads.
3. The method of claim 1 , wherein the turbulent high shear mixing and/or laminar low shear mixing occurs in a vertical granulator.
4. The method of claim 1 , wherein said powder comprises at least one liquid binder.
5. The method of claim 4 , wherein the liquid binder is selected from the group consisting of glycerin, butylene glycol, and dipentaerythrityl hexa C 5 -C 9 acid esters.
6. The method of claim 5 , wherein the liquid binder comprises dipentaerythrityl hexa C 5 -C 9 acid esters.
7. The method of claim 6 , wherein the bead has an improved payoff ranging from about 1% to about 300% than extruded beads.
8. The method of claim 1 , wherein the structuring agent is a gum, a clay, or a synthetic structuring polymer.
9. The method of claim 8 , wherein the gum is an alginate, a hydroxyethyl cellulose, ahydroxyethylmethyl cellulose, a hydroxypropyl cellulose, a carboxymethyl cellulose, a carrageenan, a guar gum, a xanthan gum, a gum arabic, or combinations thereof.
10. The method of claim 8 , wherein the clay is a hectorite, a bentonite, a montmorillonite, kaolin, a fuller's earth, a diatomaceous earth, or combinations thereof.
11. The method of claim 8 , wherein the synthetic structuring polymer is a polyvinylpyrrolidone, an ethylene oxide block copolymer, a propylene oxide block copolymer, or a polycarboxylate.
12. The method of claim 1 , wherein the powder is a filler, a pigment, a powdered binder, a skin modifier, or combinations thereof.
13. The method of claim 12 , wherein the filler is talc, mica, sericite, corn starch, and combinations thereof.
14. The method of claim 12 , wherein the pigment is an inorganic pigment.
15. The method of claim 14 , wherein the inorganic pigment is an iron oxide, a ferric salt, a manganese salt, a chromium salt, a titanium oxide, or combinations thereof.
16. The method of claim 12 , wherein the powdered binder is selected from the group consisting of metal salts of fatty acids; waxes; polyethylene; methacrylates; lauroyl lysine; boron nitride; fatty alcohols; bismuth oxychloride, and combinations thereof.
17. The method of claim 16 , wherein the powdered binder is selected from the group consisting of zinc stearate, calcium stearate, aluminum stearate, lithium stearate, magnesium stearate, zinc myristate, aluminum myristate, magnesium myristate, microcrystalline wax, polyethylene wax; methyl methacrylate, polymethyl methacrylate, cetyl alcohol, stearyl alcohol, eicosanol, and combinations thereof.
18. The method of claim 12 , wherein the skin modifier is silica powder, nylon, or combinations thereof.
19. The method of claim 1 , wherein the bead has a weight to diameter ratio of less than about 0.034 g/mm.
20. A method of preparing powder beads, comprising:
solubilizing at least one structuring agent with at least one solvent, forming a solvent phase;
mixing at least one powder under turbulent tip speed greater than about 15 ft/s;
atomizing at least a portion of said solvent phase onto said powder;
mixing the solvent phase and said powder under turbulent flow to form nonspherical nucleated seeds of about 3 mm or less in diameter;
mixing the nucleated seeds under laminar tip speed less than about 15 ft/s to form substantially spherical beads having a diameter of about 3 mm to about 30 mm; and
drying said beads.
21. The method of claim 20 , wherein the portion of the solvent phase not atomized onto said powder is combined directly with the powder.
22. The method of claim 20 , wherein the turbulent high shear mixing and/or laminar low shear mixing occurs in a vertical granulator.
23. The method of claim 20 , wherein the nucleated seeds are nonspherical and have a diameter of about 1 mm to about 3 mm.
24. The method of claim 20 , wherein the structuring agent is a gum, a clay, or a synthetic structuring polymer.
25. The method of claim 24 , wherein the gum is an alginate, a hydroxyethyl cellulose, ahydroxyethylmethyl cellulose, a hydroxypropyl cellulose, a carboxymethyl cellulose, a carrageenan, a guar gum, a xanthan gum, a gum arabic, or combinations thereof.
26. The method of claim 24 , wherein the clay is a hectorite, a bentonite, a montmorillonite, kaolin, a fuller's earth, a diatomaceous earth, or combinations thereof.
27. The method of claim 24 , wherein the synthetic structuring polymer is a polyvinylpyrrolidone, an ethylene oxide block copolymer, a propylene oxide block copolymer, or a polycarboxylate.
28. The method of claim 20 , wherein the powder is a filler, a pigment, a powdered binder, a skin modifier, or combinations thereof.
29. The method of claim 28 , wherein the filler is talc, mica, sericite, corn starch, and combinations thereof.
30. The method of claim 28 , wherein the pigment is an inorganic pigment.
31. The method of claim 30 , wherein the inorganic pigment is an iron oxide, a ferric salt, a manganese salt, a chromium salt, a titanium oxide, or combinations thereof.
32. The method of claim 28 , wherein the powdered binder is selected from the group consisting of metal salts of fatty acids; waxes; polyethylene; methacrylates; lauroyl lysine; boron nitride; fatty alcohols; bismuth oxychloride, and combinations thereof.
33. The method of claim 32 , wherein the powdered binder is selected from the group consisting of zinc stearate, calcium stearate, aluminum stearate, lithium stearate, magnesium stearate, zinc myristate, aluminum myristate, magnesium myristate, microcrystalline wax, polyethylene wax; methyl methacrylate, polymethyl methacrylate, cetyl alcohol, stearyl alcohol, eicosanol, and combinations thereof.
34. The method of claim 28 , wherein the skin modifier is silica powder, nylon, or combinations thereof.
35. The method of claim 20 , wherein the bead has a weight to diameter ratio of less than about 0.034 g/mm.
36. The method of claim 20 , wherein the powder comprises at least one liquid binder.
37. The method of claim 36 , wherein the liquid binder is selected from the group consisting of glycerin, butylene glycol, and dipentaerythrityl hexa C 5 -C 9 acid esters.
38. The method of claim 37 , wherein the liquid binder comprises dipentaerythrityl hexa C 5 -C 9 acid esters.
39. The method of claim 38 , wherein the bead has an improved payoff ranging from about 1% to about 300% than extruded beads.