Oil absorbing material and processes of recycling absorbent articles to produce the same
View Patent ↗An oil absorbing material is generally provided. The oil absorbing material can includes sorbent particles having an average aspect ratio of about 5 to about 500 and a mean average particle diameter of about 10 μm to about 1 millimeter. The oil absorbing material comprises polypropylene, polyethylene, inorganic filler particles, and absorbent core material. In one embodiment, the sorbent particles can have an average specific surface area of about 0.25 to about 5.0 m 2 /g and can have a bulk density that is about 0.01 g/cm 3 to about 0.8 g/cm 3 . Processes of making the oil absorbing material are also provided via a solid-state shear pulverization recycling process transforming absorbent article waste into the oil absorbing material. The process can include pulverizing the absorbent article waste to form sorbent particles while cooling the absorbent article waste in an amount sufficient to maintain the absorbent article waste in a solid state.
1. A process for transforming absorbent article waste into an oil absorbing material, the process comprising:
downsizing absorbent article waste to form sorbent particles, wherein the absorbent article waste comprises thermoplastic polyolefin material, inorganic filler particles, and absorbent core material, wherein downsizing is achieved at a temperature sufficient to maintain the thermoplastic polyolefin material in a solid state, wherein the sorbent particles have an average aspect ratio of about 5 to about 500 and a mean average particle diameter of about 10 μm to about 1 millimeter.
2. The process as in claim 1 , further comprising: shredding the absorbent article waste into waste shreddings prior to downsizing.
3. The process as in claim 2 , wherein the waste shreddings have a size of about 0.25 cm to about 3 cm in the maximum width dimension and about 0.5 cm to about 2 cm in the maximum thickness dimension.
4. The process as in claim 1 , wherein the absorbent article waste comprises article tailings.
5. The process as in claim 4 , wherein the absorbent article waste comprises about 45% to about 85% by weight thermoplastic polyolefin material, about 1% to about 10% by weight of an inorganic filler material, and about 1% to about 25% of absorbent core material.
6. The process as in claim 5 , wherein the absorbent article waste comprises about 40% to about 70% by weight polypropylene, about 5% to about 15% by weight polyethylene, about 1% to about 10% by weight of an inorganic filler material, and about 1% to about 25% of absorbent core material.
7. The process as in claim 5 , wherein the absorbent core material comprises cellulosic material and superabsorbent material such that the oil absorbing material comprises about 1% to about 17% by weight of the super absorbent material and about 0.5% to about 10% by weight cellulosic material.
8. The process as in claim 1 , wherein the absorbent article waste comprises diapers.
9. The process as in claim 8 , wherein the absorbent article waste comprises about 20% to about 45% by weight thermoplastic polyolefin material, about 1% to about 5% by weight inorganic filler particles, and about 25% to about 65% by weight absorbent core material.
10. The process as in claim 9 , wherein the absorbent article waste comprises about 20% to about 35% by weight polypropylene, about 3% to about 8% by weight polyethylene, about 1% to about 5% by weight inorganic filler particles, and about 25% to about 65% by weight absorbent core material.
11. The process as in claim 9 , wherein the absorbent core material comprises cellulosic material and superabsorbent material such that the oil absorbing material comprises about 15% to about 35% by weight of the super absorbent material and about 10% to about 30% by weight cellulosic material.
12. The process as in claim 1 , wherein the absorbent article waste is downsized by a twin-screw extruder.
13. The process as in claim 12 , wherein the twin-screw extruder is housed within an extruder barrel, wherein the extruder barrel is cooled during downsizing.