Weatherable thermoplastic resin composition having excellent low gloss characteristic and method of preparing the same
The present invention provides a thermoplastic resin composition which comprises (A) a (meth)acrylic acid alkyl ester-based polymer forming a network-shaped disperse phase; and (B) an aromatic vinyl-cyanide vinyl based copolymer forming a continuous phase. The thermoplastic resin composition of the present invention can have an excellent low gloss characteristics while maintaining basic physical properties of a weather resistance, impact strength, thermal resistance, and delamination characteristics.
1. A weatherable thermoplastic resin composition comprising:
(A) a (meth)acrylic acid alkyl ester-based polymer forming a network-shaped disperse phase, wherein said (meth)acrylic acid alkyl ester-based polymer (A) is prepared by polymerizing a mixture comprising a (meth)acrylic acid alkyl ester, a (meth)acrylic acid glycidyl ester, and a compound having either two or more carboxyl groups or two or more hydroxyl groups; and
(B) an aromatic vinyl-cyanide vinyl based copolymer forming a continuous phase.
2. The weatherable thermoplastic resin composition of claim 1 , wherein said thermoplastic resin composition comprises about 5 to about 35% by weight of the (meth)acrylic acid alkyl ester-based polymer (A), and about 65 to about 95% by weight of the aromatic vinyl-cyanide vinyl based copolymer (B).
3. The weatherable thermoplastic resin composition of claim 1 , wherein said (meth)acrylic acid alkyl ester-based polymer (A) comprises about 60 to about 95% by weight of a (meth)acrylic acid alkyl ester; about 1 to about 20% by weight of a (meth)acrylic acid glycidyl ester; about 0 to about 20% by weight of an aromatic vinyl-based compound; and about 0 to about 10% by weight of a vinyl cyanide based compound.
4. The weatherable thermoplastic resin composition of claim 1 , wherein said (meth)acrylic acid alkyl ester-based polymer (A) includes a polymerized compound with either two or more carboxyl groups or two or more hydroxyl groups in an equivalent ratio of about 0.1 to about 3 with respect to the (meth)acrylic acid glycidyl ester.
5. The weatherable thermoplastic resin composition of claim 1 , wherein said (meth)acrylic acid alkyl ester comprises methyl methacrylate, ethyl methacrylate, propyl methacrylate, butyl methacrylate, pentyl methacrylate, hexyl methacrylate, heptyl methacrylate, octyl methacrylate, 2-ethyl hexyl methacrylate, methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, pentyl acrylate, hexyl acrylate, heptyl acrylate, octyl acrylate, 2-ethyl hexyl acrylate, or a combination thereof.
6. The weatherable thermoplastic resin composition of claim 1 , wherein said (meth)acrylate acid glycidyl ester compound comprises glycidyl acrylate, glycidyl (meth)acrylate, or a combination thereof.
7. The weatherable thermoplastic resin composition of claim 1 , wherein said compound having two or more carboxyl groups comprises a C2 to C10 alkanedioic acid, polyacid, or a combination thereof
8. The weatherable thermoplastic resin composition of claim 1 , wherein said compound having two or more hydroxyl groups comprises a C2 to C10 alkanediol, ethylene glycol, polyethylene glycol, propylene glycol, polypropylene glycol, polyol, or a combination thereof.
9. The weatherable thermoplastic resin composition of claim 1 , wherein said (meth)acrylic acid alkyl ester-based polymer (A) comprises a (meth)acrylic acid alkyl ester unit and a (meth)acrylic acid glycidyl ester unit as a main chain, and an epoxy group of the (meth)acrylic acid glycidyl ester unit is linked to the carboxyl groups or hydroxyl groups of the compound having either two or more carboxyl groups or two or more hydroxyl groups by ester bonds.
10. The weatherable thermoplastic resin composition of claim 1 , wherein said aromatic vinyl-cyanide vinyl based copolymer (B) is prepared by polymerizing about 60 to about 95% by weight of an aromatic vinyl-based compound, about 5 to about 40% by weight of a vinyl cyanide based compound, and about 0 to about 10% by weight of a (meth)acrylic acid alkyl ester.
11. The weatherable thermoplastic resin composition of claim 1 , wherein said aromatic vinyl-cyanide vinyl based copolymer (B) have a weight-average molecular weight of about 150,000 to about 300,000.
12. The weatherable thermoplastic resin composition of claim 10 , wherein said aromatic vinyl-based compound comprises styrene, a-methyl styrene, para-methyl styrene, or a combination thereof; and wherein said vinyl cyanide based compound comprises acrylonitrile, methacrylonitrile, ethacrylonitrile, or a combination thereof.
13. The weatherable thermoplastic resin composition of claim 1 , the thermoplastic resin has a gloss value of about 30 or less, which is measured using a 75 Degree Gloss Meter.