Multiple layer polymer interlayers having a melt-fractured surface
View Patent ↗The present invention provides multiple layer interlayers having a soft inner polymer layer and relatively stiff outer layers that can be laminated without unacceptable optical distortion and used in various multiple layer glass panel type applications. Multiple layer interlayers of the present invention have surface topography that is formed by controlling the melt fracture that occurs at the exposed surface of the interlayer, or individual layers of the multiple layer interlayer, during formation of the interlayer. By precisely controlling the surface topography of the interlayer, lamination of the interlayer with a rigid substrate does not lead to unacceptable optical distortion caused by the transfer of the surface topography through outer, stiffer layers into softer, internal layers of the interlayer.
1. A method for producing a poly(vinyl butyral) interlayer comprising:
forming a first poly(vinyl butyral) melt, a second poly(vinyl butyral) melt, and a third poly(vinyl butyral) melt;
coextruding said first poly(vinyl butyral) melt, said second poly(vinyl butyral) melt, and said third poly(vinyl butyral) melt to form said interlayer comprising, in order, a first low plasticizer content poly(vinyl butyral) layer, a high plasticizer content poly(vinyl butyral) layer with 50 to 80 phr by weight plasticizer, and a second low plasticizer content poly(vinyl butyral), wherein the low plasticizer content poly(vinyl butyral) layers differ from the high plasticizer content poly(vinyl butyral) layer by at least 25 phr by weight in plasticizer content; and
controlling melt fracture during coextruding such that both surfaces of said interlayer have an R z of 20-50 microns and an R sm of less than 800 microns that is imparted by melt-fracture;
wherein the first low plasticizer content poly(vinyl butyral) layer has a tensile break stress that is at least 15 kilograms per square centimeter greater than the tensile break stress of said high plasticizer content poly(vinyl butyral) layer, and said second low plasticizer content poly(vinyl butyral) layer has a tensile break stress that is at least 15 kilograms per square centimeter greater than the tensile break stress of said high plasticizer content poly(vinyl butyral) layer.
2. The method of claim 1 , wherein both surfaces of said interlayer have an R sm value of less than 700 microns.
3. A method for producing a multiple layer glass panel comprising:
forming a first poly(vinyl butyral) melt, a second poly(vinyl butyral) melt, and a third poly(vinyl butyral) melt;
coextruding said first poly(vinyl butyral) melt, said second poly(vinyl butyral) melt, and said third poly(vinyl butyral) melt to form an interlayer comprising, in order, a first low plasticizer content poly(vinyl butyral) layer, a high plasticizer content poly(vinyl butyral) layer with 50 to 80 phr by weight plasticizer, and a second low plasticizer content poly(vinyl butyral), wherein the low plasticizer content poly(vinyl butyral) layers differ from the high plasticizer content poly(vinyl butyral) layer by at least 25 phr by weight in plasticizer content;
controlling melt fracture during coextruding such that both surfaces of said interlayer have an R z of 20-50 microns and an R sm of less than 800 microns that is imparted by melt-fracture; and
laminating said interlayer between two glass substrates to form said multiple layer glass panel;
wherein the first low plasticizer content poly(vinyl butyral) layer has a tensile break stress that is at least 15 kilograms per square centimeter greater than the tensile break stress of said high plasticizer content poly(vinyl butyral) layer, and said second low plasticizer content poly(vinyl butyral) layer has a tensile break stress that is at least 15 kilograms per square centimeter greater than the tensile break stress of said high plasticizer content poly(vinyl butyral) layer.
4. The method of claim 3 , wherein both surfaces of said interlayer have an R sm value of less than 700 microns.