IP Library Granted Patent US 8,703,689
Granted Patent B2
US 8,703,689 · App. 12/981,220 · Granted Apr 22, 2014

Hypochlorite composition with enhanced fabric and equipment safety benefits

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Quick Facts
Patent No.
US 8,703,689
App. No.
12/981,220
Granted
Apr 22, 2014
Kind
B2
Abstract

The present invention provides an aqueous bleaching composition comprising from about 1.0% to 10.0% by weight of alkali metal hypochlorite, from about 0.05% to 5.0% by weight of alkali metal hydroxide to provide the composition with a pH in the range of from about 9 to 14; from about 0.02% to 5.0% by weight of a metal silicate or mixtures of metal silicates; from about 0.0001% to 0.2% by weight of a metal periodate; and water. The compositions reliably protect the fabric against yellowing and weakening while providing protection to stainless steel metal parts of the washing machine and metal garment decors such as buckles, buttons, etc.

Claims (36)

1. A method of reducing damage to metal parts of a washing machine during a laundry cycle using a hypochlorite-containing bleach, the method comprising the step of

adding to said laundry cycle an aqueous liquid bleaching composition consisting essentially of:

i. from about 1.0% to 10.0% by weight of alkali metal hypochlorite,

ii. from about 0.05% to 5.0% by weight of alkali metal hydroxide to provide the composition with a pH in the range of from about 9 to 14;

iii. from about 0.02% to 5.0% by weight of an alkali metal silicate or mixtures of alkali metal silicates;

iv. from about 0.0001% to 0.1% by weight of an alkali metal periodate;

v. water, and

vi. optionally a fragrance wherein the fragrance either is added directly to the composition or is added as an emulsified solution wherein the emulsified solution optionally contains a surfactant that is compatible with hypochlorite,

wherein the presence of said bleaching composition during said laundry cycle does not cause damage to metal parts of the washing machine with which it comes into contact.

2. The method of claim 1 , comprising the further step of washing the fabrics with a detergent.

3. The method of claim 2 , wherein said detergent is present in said washing machine during said contacting step.

4. The method of claim 2 wherein said bleaching composition is rinsed from said fabrics prior to the step of washing the fabrics with a detergent solution.

5. The method of claim 1 , wherein the fabrics are contacted with the bleaching composition for a period of from about 3 to 60 minutes.

6. The method of claim 5 , wherein the fabrics are contacted with the bleaching composition for a period of from about 5 to 30 minutes.

7. The method of claim 1 , comprising the further step of diluting the bleaching composition in water.

8. The method of claim 7 wherein said bleaching composition is diluted in the range of from about 0.5 g/l to 140 g/l.

9. The method of claim 7 wherein said bleaching composition is diluted in the range of from about 1 g/l to 50 g/l.

10. The method of claim 7 wherein said bleaching composition is diluted in the range of from about 5 g/l to 25 g/l.

11. The method of claim 1 wherein the contacting step is conducted at a temperature of 40° C.

12. The method of claim 1 wherein the contacting step is conducted at room temperature.

13. The method of claim 1 wherein said fabrics have metal accessories attached thereto, which metal accessories are not damaged by contact with said bleaching composition during said contacting step.

14. A method of bleaching one or more fabrics having one or more metal accessories attached thereto while protecting said metal accessories from bleach damage, the method comprising the step of

contacting the fabrics and the metal accessories attached thereto with an aqueous liquid bleaching composition consisting essentially of:

i. from about 1.0% to 10.0% by weight of alkali metal hypochlorite,

ii. from about 0.05% to 5.0% by weight of alkali metal hydroxide to provide the composition with a pH in the range of from about 9 to 14;

iii. from about 0.02% to 5.0% by weight of an alkali a metal silicate or mixtures of alkali metal silicates;

iv. from about 0.0001% to 0.1% by weight of an alkali a metal periodate;

v. water, and

vi. optionally a fragrance wherein the fragrance either is added directly to the composition or is added as an emulsified solution wherein the emulsified solution optionally contains a surfactant that is compatible with hypochlorite,

wherein said bleaching composition does not cause damage to said metal accessories with which it comes into contact.

15. The method of claim 14 , further comprising the step of diluting the bleaching composition in water.

16. The method of claim 15 wherein said bleaching composition is diluted in the range of from about 0.5 g/l to 140 g/l.

17. The method of claim 15 wherein said bleaching composition is diluted in the range of from about 1 g/l to 50 g/l.

18. The method of claim 15 wherein said bleaching composition is diluted in the range of from about 5 g/l to 25 g/l.

19. The method of claim 14 wherein the contacting step is conducted at a temperature of 40° C.

20. The method of claim 14 wherein the contacting step is conducted at room temperature.

Assignments (25)
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Dec 12, 2025
From: AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; BIO-LAB, INC.; CYGNUS CORPORATION; KIK INTERNATIONAL LLC; HI-LEX LLC; HOMECARE LABS, INC.; JAMES AUSTIN COMPANY; KIK CUSTOM PRODUCTS INC.; NC BRANDS L.P.; SOLSKYN PERSONAL CARE LLC
To: KIK LUX FINCO SARL
Reel/Frame 073924/0557 →
RELEASE AND TERMINATION OF INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Jul 10, 2024
From: BARCLAYS BANK PLC
To: APG, INC.; HI-LEX LLC; KIK INTERNATIONAL, LLC; KIK NEW JERSEY, LLC; BIO-LAB, INC.; HOMECARE LABS, INC.; MARIETTA CORPORATION; KIK CUSTOM PRODUCTS INC.; KIK CUSTOM PRODUCTS INC.
Reel/Frame 068259/0638 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Jul 10, 2024
From: AQUA CLEAR INDUSTRIES, LLC; BIO-LAB, INC.; KIK INTERNATIONAL LLC; KIK CUSTOM PRODUCTS INC.; NC BRANDS L.P.
To: BARCLAYS BANK PLC
Reel/Frame 068259/0725 →
RELEASE/TERMINATION OF INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Jul 8, 2024
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: BIO-LAB, INC.; KIK CUSTOM PRODUCTS INC.; NC BRANDS, L.P.; PRESTONE PRODUCTS CORPORATION
Reel/Frame 068220/0306 →
RELEASE AND TERMINATION OF INTELLECTUAL PROPERTY SECURITY INTEREST Recorded Jul 8, 2024
From: BARCLAYS BANK PLC
To: AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; BIO-LAB, INC.; HI-LEX LLC; HOMECARE LABS, INC.; KIK CUSTOM PRODUCTS, INC.; KIK INTERNATIONAL, LLC; PRESTONE PRODUCTS CORPORATION; SOLSKYN PERSONAL CARE LLC; SUNBELT POOL PRODUCTS, LLC; JAMES AUSTIN COMPANY; NC BRANDS L.P.; CYGNUS CORPORATION
Reel/Frame 068220/0455 →
SECURITY INTEREST Recorded Jul 8, 2024
From: AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; BIO-LAB, INC.; CYGNUS CORPORATION; KIK CUSTOM PRODUCTS INC.; KIK INTERNATIONAL LLC; HI-LEX LLC; HOMECARE LABS, INC.; JAMES AUSTIN COMPANY; NC BRANDS L.P.; SOLSKYN PERSONAL CARE LLC
To: JEFFERIES FINANCE LLC
Reel/Frame 067928/0718 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Jul 8, 2024
From: AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; BIO-LAB, INC; CYGNUS CORPORATION; KIK CUSTOM PRODUCTS INC.; KIK INTERNATIONAL LLC; HI-LEX LLC; HOMECARE LABS, INC.; JAMES AUSTIN COMPANY; NC BRANDS L.P.; SOLSKYN PERSONAL CARE LLC
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 068220/0368 →
RELEASE OF SECURITY INTEREST Recorded May 18, 2022
From: TCW ASSET MANAGEMENT COMPANY LLC
To: MARIETTA CORPORATION; AEROSOLS DANVILLE INC.
Reel/Frame 059942/0312 →
SECURITY AGREEMENT Recorded Dec 27, 2021
From: AQUA CLEAR INDUSTRIES, LLC; ASEPIS, INC.; BIO-LAB, INC.; HI-LEX LLC; HOMECARE LABS, INC.; KIK CUSTOM PRODUCTS INC.; KIK INTERNATIONAL LLC; PRESTONE PRODUCTS CORPORATION; SOLSKYN PERSONAL CARE LLC; SUNBELT POOL PRODUCTS, LLC; JAMES AUSTIN COMPANY; CYGNUS CORPORATION; NC BRANDS L.P.
To: BARCLAYS BANK PLC
Reel/Frame 058592/0835 →
RELEASE OF INTELLECTUAL PROPERTY SECURITY INTEREST Recorded Jul 29, 2021
From: BARCLAYS BANK PLC, AS COLLATERAL AGENT
To: BIO-LAB, INC.; HI-LEX LLC; HOMECARE LABS, INC.; JAMES AUSTIN COMPANY; KIK INTERNATIONAL LLC; NC BRANDS L.P.; PRESTONE PRODUCTS CORPORATION; SOLSKYN PERSONAL CARE LLC; SUNBELT POOL PRODUCTS, LLC
Reel/Frame 057650/0125 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (NOTES) Recorded Dec 22, 2020
From: BIO-LAB, INC.; KIK CUSTOM PRODUCTS INC.; KIK INTERNATIONAL LLC; PRESTONE PRODUCTS CORPORATION; SOLSKYN PERSONAL CARE LLC; JAMES AUSTIN COMPANY; CYGNUS CORPORATION; NC BRANDS L.P.; AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; HI-LEX LLC; HOMECARE LABS, INC.; SUNBELT POOL PRODUCTS, LLC
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
Reel/Frame 055327/0754 →
SECURITY INTEREST Recorded Aug 22, 2020
From: MARIETTA CORPORATION; AEROSOLS DANVILLE INC. (F/K/A KIK CUSTOM PRODUCTS, INC.)
To: BANK OF AMERICA
Reel/Frame 053569/0001 →
SECURITY INTEREST Recorded Aug 20, 2020
From: AEROSOLS DANVILLE, INC.; MARIETTA CORPORATION
To: TCW ASSET MANAGEMENT COMPANY LLC
Reel/Frame 053549/0096 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (2019) Recorded Jan 28, 2019
From: APG, INC.; AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; BIO-LAB, INC.; HI-LEX LLC; HOMECARE LABS, INC.; KIK CUSTOM PRODUCTS INC.; KIK CUSTOM PRODUCTS, INC; KIK INTERNATIONAL LLC; MARIETTA CORPORATION; PRESTONE PRODUCTS CORPORATION; SOLSKYN PERSONAL CARE LLC; SUNBELT POOL PRODUCTS, LLC; JAMES AUSTIN COMPANY; CBI LABORATORIES, INC.; CYGNUS CORPORATION; NC BRANDS L.P.
To: BARCLAYS BANK PLC, AS AGENT
Reel/Frame 048180/0101 →
RELEASE OF SECURITY INTEREST Recorded Sep 14, 2016
From: BARCLAYS BANK PLC
To: APG, INC.; AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; BIO-LAB, INC.; CYGNUS CORPORATION; HI-LEX LLC; HOMECARE LABS, INC.; KIK CUSTOM PRODUCTS INC.; KIK CUSTOM PRODUCTS, INC; KIK INTERNATIONAL LLC; MARIETTA CORPORATION; SOLSKYN PERSONAL CARE LLC; KIK NEW JERSEY, LLC; PRESTONE PRODUCTS CORPORATION
Reel/Frame 040031/0793 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Apr 5, 2016
From: APG, INC.; AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; BIO-LAB, INC.; CYGNUS CORPORATION; HI-LEX LLC; HOMECARE LABS, INC.; KIK CUSTOM PRODUCTS, INC. (TEXAS); KIK CUSTOM PRODUCTS INC. (DELAWARE); KIK INTERNATIONAL LLC; MARIETTA CORPORATION; PRESTONE PRODUCTS CORPORATION; SOLSKYN PERSONAL CARE LLC; KIK NEW JERSEY, LLC
To: BARCLAYS BANK PLC, AS COLLATERAL AGENT
Reel/Frame 038354/0938 →
RELEASE OF SECURITY INTEREST Recorded Aug 26, 2015
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
To: KIK CUSTOM PRODUCTS, INC.
Reel/Frame 036428/0130 →
SECURITY INTEREST Recorded Aug 26, 2015
From: APG, INC.; BIO-LAB, INC.; KIK CUSTOM PRODUCTS, INC; KIK CUSTOM PRODUCTS INC.; KIK INTERNATIONAL LLC; HI-LEX LLC; HOMECARE LABS, INC.; MARIETTA CORPORATION; AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; CYGNUS CORPORATION; KIK NEW JERSEY, LLC
To: BARCLAYS BANK PLC, AS COLLATERAL AGENT
Reel/Frame 036427/0038 →
SECURITY INTEREST Recorded Aug 26, 2015
From: APG, INC.; BIO-LAB, INC.; KIK CUSTOM PRODUCTS, INC; KIK CUSTOM PRODUCTS INC.; KIK INTERNATIONAL LLC; HI-LEX LLC; HOMECARE LABS, INC.; MARIETTA CORPORATION; AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; CYGNUS CORPORATION; KIK HOLDCO COMPANY INC.; KIK NEW JERSEY, LLC
To: BARCLAYS BANK PLC, AS ADMINISTRATIVE AGENT
Reel/Frame 036427/0334 →
RELEASE OF SECURITY INTEREST Recorded Aug 26, 2015
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
To: KIK CUSTOM PRODUCTS, INC.
Reel/Frame 036428/0271 →
RELEASE OF SECURITY INTEREST Recorded Aug 26, 2015
From: UBS AG, STAMFORD BRANCH, AS COLLATERAL AGENT
To: KIK CUSTOM PRODUCTS, INC.
Reel/Frame 036428/0477 →
SECURITY AGREEMENT Recorded Jun 4, 2013
From: KIK CUSTOM PRODUCTS, INC. A TEXAS CORPORATION
To: CREDIT SUISSE AG, AS SECOND LIEN COLLATERAL AGENT
Reel/Frame 030546/0031 →
SECURITY AGREEMENT Recorded Jun 3, 2013
From: KIK CUSTOM PRODUCTS, INC., A TEXAS CORPORATION
To: CREDIT SUISSE AG, AS FIRST LIEN COLLATERAL AGENT
Reel/Frame 030537/0701 →
SECURITY AGREEMENT Recorded May 29, 2013
From: KIK CUSTOM PRODUCTS, INC.
To: UBS AG, STAMFORD BRANCH, AS AGENT
Reel/Frame 030501/0732 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 31, 2010
From: MERCADO, HEDELIZA MALONZO
To: KIK CUSTOM PRODUCTS INC.
Reel/Frame 025570/0159 →